SAFETY DATA SHEET ZOJIRUSHI CITRIC ACID CLEANER Section 1. Chemical product and company identification Product name Recommended use and restrictions ZOJIRUSHI CITRIC ACID CLEANER Delimer Use only for the purpose on the product label. Product dilution information 1 oz/5 L or.757 oz/gal or 3 g/5 L or 6 g/l Supplier's information Code Date of issue Section 2. Hazards identification GHS Classification GHS label elements SSDC Division Kay Chemical Company 45 Corporate Dr., #1 Grapevine, TX 7651 1-866-999-7484 912272-6 2 Aug 213 EMERGENCY HEALTH INFORMATION 1-866-897-861 Outside US and Canada 1-952-852-4656 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Not classified. Signal word Symbol Warning No signal word. Hazard statements Precautionary statements Prevention Response Storage Disposal Other hazards Causes serious eye irritation. Wear eye or face protection. Do not mix with bleach or other chlorinated products - will cause chlorine gas. Wash hands thoroughly after handling. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical attention. No other specific measures identified. See section 13 for waste disposal information. None known. Wash thoroughly after handling. Get medical attention if symptoms appear. No other specific measures identified. See section 13 for waste disposal information. None known. Page 1/6
Section 3. Composition/information on ingredients Substance/mixture Hazardous ingredients Mixture Concentration Range (%) CAS number CITRIC ACID >5 77-92-9 Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in quantities requiring reporting, in accordance with local regulations. Section 4. First aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Skin contact No known effect after skin contact. Rinse with water for a few minutes. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. Protection of firstaiders Notes to physician See toxicological information (section 11) Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Specific fire-fighting methods Special protective equipment for fire-fighters No known effect after eye contact. Rinse with water for a few minutes. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Section 5. Fire-fighting measures Personal precautions Environmental precautions Methods for cleaning up Use water spray, fog or foam. No specific fire or explosion hazard. Section 6. Accidental release measures Decomposition products may include the following materials carbon dioxide carbon monoxide Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Collect spillage. Use a water rinse for final cleanup. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Page 2/6
Section 6. Accidental release measures Section 7. Handling and storage Handling Storage Control parameters Appropriate engineering controls Personal protection Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Avoid contact with eyes, skin and clothing. Do Wash thoroughly after handling. not mix with bleach or other chlorinated products - will cause chlorine gas. Wash thoroughly after handling. Keep out of reach of children. Keep container Keep out of reach of children. tightly closed. Store between the following temperatures and 5 C Section 8. Exposure controls/personal protection Ingredient name None. Physical state Color Melting point Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wear eye protection. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. Exposure limits Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties White Odor ph Odorless Not applicable Flash point > 1 C Product does not support combustion. Explosion limits (solid, gas) Boiling point Evaporation rate (butyl acetate = 1) Solid Liquid. Clear [Light] Odorless 2.5 > 1 C Page 3/6
Section 9. Physical and chemical properties Vapor pressure Vapor density Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Odor threshold Viscosity Stability Possibility of hazardous reactions Hazardous decomposition products 1.44 to 1.64 (Water = 1) Easily soluble in the following materials cold water. Section 1. Stability and reactivity Conditions to avoid Materials to avoid Route of exposure Ingestion Acute toxicity Eye contact Skin contact Inhalation Ingestion Toxicity data Section 11. Toxicological information The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Reactive or incompatible with the following materials alkalis. Do not mix with bleach or other chlorinated products - will cause chlorine gas. Slightly reactive or incompatible with the following materials metals. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin contact, Eye contact, Ingestion Symptoms Eye contact Adverse symptoms may include the following pain or irritation watering redness Skin contact Inhalation Causes serious eye irritation. Product/ingredient name citric acid LD5 Dermal Rat >2 mg/kg LD5 Oral Rat 117 mg/kg Page 4/6
Section 11. Toxicological information Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Other adverse effects Section 12. Ecological information Ecotoxicity Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure citric acid Acute LC5 >1 mg/l Fish 96 hours Disposal methods Section 13. Disposal considerations Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification Not intended for transport. Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 No listed substance No listed substance Page 5/6
Section 16. Other information Hazardous Material Information System (U.S.A.) Health 2 Health Physical hazards Physical hazards National Fire Protection Association (U.S.A.) Health 2 Instability/Reactivity Health Instability/Reactivity Special Special Date of issue Prepared by 2 Aug 213 Regulatory Affairs 1-8-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 6/6