Revised edition: 14.03.2018 1. 1. 1. Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Fuchsin 1. 2. Article No.: 94110 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Use as laboratory reagent 1. 3. Uses advised against: Details of the Supplier of the (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H315 Cat.: 2 H319 Cat.: 2 H335 Cat.: 3 H351 Cat.: 2 Classification according to Directive No. 67/548/EC or No. 1999/45/EC R45 Skin irritation, hazard category 2 Eye irritation, hazard category 2 Specific Target Organ Toxicity (single exposure), hazard category 3 (Respiratory tract irritation) Carcinogenity, hazard category 2 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. May cause cancer. 2. 2. Safety Phrases: Possible Environmental Effects: Label Elements See Section 12. Classification according to Regulation 2
(EC) No. 1272/2008 (CLP/GHS) Page 2 Hazard designation: GHS07 GHS08-1 Signal word: Hazard designation: Safety designation: H315 H319 H335 H351 P201 P280 P302+P352 P305+P351+P338 P308+P313 P337+P313 Warning Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Suspected of causing cancer. Obtain special instructions before use. Wear protective gloves/ clothing/ eye/ face protection. If on skin: Wash with soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If exposed or concerned: Get medical advice/attention. If eye irritation persists: Get medical advice/ attention. 2. 3. 3. 3. 1. 3. 2. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Dye, woodstain.c20h20cln3. Basic Violet 14, C.I. 42510 Information on Components / Hazardous Ingredients: Fuchsin (Carc. 2, H351-315-319-335) 100 % CAS-Nr: 632-99-5 EINECS-Nr: 211-189-6 EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: Seek medical attention in case of complaints. Supply fresh air and seek medical advice in case of complaints. 3
After skin contact: Page 3 Remove contaminated clothing. Wash off immediately with plenty of water and soap. Get medical attention. After eye contact: Rinse open eyes with plenty of water for at least 15 minutes. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immdiately give water to drink (at the most 2 glasses). Consult a doctor. Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Foam, carbon dioxide (CO2), extinguishing powder, water. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. 5. 3. Special hazards: Advice for Firefighters Protective equipment: Combustible. Formation of hazardous combustion gases or vapors possible in the event of fire. In case of fire: formation of nitrogen oxide, hydrogen chloride. Wear self-contained respiratory protective device and full protective gear. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water. Reduce escaping fumes with water. Personal precautions: Do not inhale dust. Avoid contact with eyes and skin. Evacuate the danger area, observe emergency procedures, 4
consult an expert. 6. 2. Environmental Precautions Page 4 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Cover drains. Collect, bind and pump off spills. See Section 13 for information on disposal. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Take off contaminated clothing immediately. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry room. Accesible for authorized persons only. No special measures necessary. Combustible material. 11; Combustible solids 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: See Section 1.2.; no other uses provided Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): No values available. Predicted No-Effect Concentration 5
(PNEC): No values available. Page 5 8. 2. Additional Information: Exposure Controls Technical protective measures: Use local exhaust ventilation in case of dust and/or fume formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Remove contaminated clothing immediately. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. In case of formation of dust. Wear protective mask, particle filter P2 or FFP2 or NIOSH N95 (for solid and liquid particles, EN 143, 149) if dust occurs. Protective gloves (EN 374) Nitrile rubber (> 480 min, 0.11 mm). Tightly fitting safety goggles (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: Do not allow entering sewerage system. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: solid green light 5-6 (25 C; 1 g/l H2O) Melting temperature: 235 C Boiling temperature: not available Flash point: not available Evaporation rate: 6
Flammability (solid, gas): not available Page 6 Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: Vapor density: Density: not available Solubility in water: 4 g/l (25 C) Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: No data available. Viscosity, dynamic: not available Explosive properties: Oxidizing properties: no information available Bulk density: 500 kg/m3 9. 2. Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: No further information. 10. Stability and Reactivity 10.1. Reactivity 7
10.2. 10.3. 10.4. Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Page 7 No decomposition if used according to specifications. Reacts with strong oxidants. 10.5. 10.6. 10.7. 11. 11. 1. Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Strong oxidizing agents. In the event of fire: see chapter 5. Irritating to skin. Causes serious eye irritation. No information available No relevant data found. No relevant data found. No relevant data found. Can cause cancer. Specific target organ toxicity (STOT): 8
12. 12. 1. Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Page 8 Handle in accordance with good industrial hygiene and safety practice. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. 14. 14. 1. Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number PBT/vPvB assessment not available as chemical safety assessment is not required / not conducted. 3, hazardous No quantitative ecological data available for this product. Do not let product enter waterways or sewage system. Do not let product enter water systems. Dispose of according to official national and local regulations. Uncontaminated packaging may be recycled. Packaging may be disposed of in the same manner as the product. ADR, IMDG, IATA 9
14. 2. UN Proper Shipping Name Page 9 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Not classified as a dangerous good under transport regulations. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: Employment restrictions: 3, very hazardous for water (German Regulation) Seveso III Directive: under Directive 2012/18/EC. The employment restrictions for young workers in accordance with the Youth Employment Protection Law ( 22 JArbSchG) are to be observed. The employment restrictions for expectant and nursing mothers 10
are to be observed ( 4 und 5 MuSchRiV). Page 10 15. 2. 15. 3. 16. Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.