Date of issue: 8/21/2015 Revision date: 3/29/2016 Supersedes: 12/15/2015 Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Intended for general public Main use category Industrial/Professional use spec Use of the substance/mixture : Industrial use,professional use,consumer use : Wide dispersive use : It is modified gypsum based mixture with high adhesive strength. It is intended for building massive gypsum panels or blocks for not-load bearing partition walls, free standing protective structures, inspection manholes, etc., as well as their connection with adjacent construction elements. 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier MARISAN & Kolev AD 15 Kalna Dere Str.; East Industrial Zone 7009 Ruse - Bulgaria T +359-82-519 721 office@marisanbg.com - http://www.marisanbg.com/en 1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment National Poisons Information Grosvenor Road BT12 6BA Belfast Service (Belfast Centre) Royal Victoria Hospital National Poisons Information Service (Birmingham Centre) City Hospital, Guy's & St Thomas' Hospital Trust National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Wolfson Unit NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh, Centre Hospitalier Universitaire Bab el Oued Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Centre Hospitalier Universitaire de Constantine National Poisons Information Service (Newcastle Centre) Regional Drugs and Therapeutics Centre SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Dudley Road B18 7QH Birmingham Penarth CF64 2XX Cardiff 51 Little France Crescent EH16 4SA Edinburgh Avonley Road SE14 5ER London Claremont Place Newcastle-upon-Tyne NE1 4LP Newcastle 0870 243 2241 Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety practice. 3/29/2016 EN (English) 1/6
2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Precautionary statements (CLP) : P102 - Keep out of reach of children 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 77231 (CAS No) 7778-18-9 (EC no) 231-900-3 CITRIC ACID (CAS No) 77-92-9 (EC no) 201-069-1 Full text of H-statements: see section 16 78-85 Not classified 15-22 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Recover mechanically the product. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. 3/29/2016 EN (English) 2/6
SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Protect from moisture. Store in a well-ventilated place. Keep cool. 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Powder. Colour : Grey. Odour : odourless. Odour threshold ph ph solution : 7.5-8.5 Relative evaporation rate (butyl acetate=1) Melting point Freezing point : Boiling point Flash point : Auto-ignition temperature : Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density : Solubility Log Pow Viscosity, kinematic : Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : 9.2. Other information 3/29/2016 EN (English) 3/6
SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Additional information : Industrial waste. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) UN-No. (IMDG) : : 3/29/2016 EN (English) 4/6
UN-No. (IATA) UN-No. (ADN) UN-No. (RID) 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : : : : : : : : : IMDG Transport hazard class(es) (IMDG) : IATA Transport hazard class(es) (IATA) : ADN Transport hazard class(es) (ADN) : RID Transport hazard class(es) (RID) 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : : : : : : : No : No : No supplementary information available 14.6. Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list 3/29/2016 EN (English) 5/6
Contains no REACH Annex XIV substances 15.1.2. National regulations Labelling according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Regulation (EC) No. 1272/2008 [CLP] National regulations 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 3/29/2016 EN (English) 6/6