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Transcription:

SAFETY DATA SHEET Issuing Date January 8, 2019 Revision Number 3 Product identifier Product Name Sulfuric Acid, 0.5N Other means of identification Manufacturer number: SA1590-A Distributor Address Best Sanitizers, Inc. PO Box 1360 Penn Valley, CA 95946 1. IDENTIFICATION Emergency telephone number Emergency Phone Numbers For Transportation Emergencies, call Aquaphoenix Scientific: 1-800-255-3924 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Label Elements Not Regulated There are no other hazards not otherwise classified that have been identified. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight % Trade Secret Sulfuric Acid 7664-93-9 < 5 - Purified Water 7732-18-5 > 95 - * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Eye Contact Skin Contact Inhalation Show this safety data sheet to the doctor in attendance. Hold eye(s) open and rinse slowly and gently with water for 30 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye(s). Get medical advice/attention. Wash affected area with warm water. Seek medical attention if skin irritation is experienced.. Move to fresh air. Seek immediate medical attention if discomfort or irritation persists. Page 3 / 11

Ingestion Most important symptoms and effects, both acute and delayed Nausea in case of ingestion. Gastric or intestinal disorders when ingested. Rinse mouth thoroughly. Do NOT induce vomiting. Drink sips of water. Seek immediate medical attention if irritation, discomfort or vomiting persists. Indication of any immediate medical attention and special treatment needed No relevant information available. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media The product is not flammable. Use fire fighting measures that suit the environment. Unsuitable Extinguishing Media None. Specific Hazards Arising from the Chemical Formation of toxic gases is possible during heating or in case of fire. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protection recommended in Section 8. Ensure adequate ventilation. For large spills, use respiratory protective device against the effects of fumes/dust/aerosol. Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Methods for Cleaning Up If in a laboratory setting, follow Chemical Hygiene Plan procedures. Always obey local regulations. Place into properly labeled containers for recovery or disposal. If necessary, use trained response staff/contractor. Use Limestone to neutralize and/or absorb spill. Clean affected areas with warm water. Conditions for safe storage, including any incompatibilities 7. HANDLING AND STORAGE Storage Use only receptacles specifically permitted for this substance/product. Unsuitable material for receptacle; aluminum. Store in cool, dry condition in well-sealed receptacles. Page 4 / 11

Incompatible Products Store away from foodstuffs. Do not store with alkalis. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sulfuric Acid 7664-93-9 0.2mg/m 3 1mg/m 3 - ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Keep away from foodstuffs. Wash hands before breaks and at the end of work. Immediately remove all soiled and contaminated clothing. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Wear safety glasses with side shields (or goggles). Wear impermeable and resistant to the product/substance/preparation protective gloves. Selection of glove material on consideration of the penetration times, rates of diffusion and degradation. Not required under normal conditions of use. Respiratory protection must be provided in accordance with current local regulations. The usual precautionary measures are to be adhered to when handling chemicals. Keep away from food, beverages and feed sources. Immediately remove all soiled and contaminated clothing. Wash face, hands and any exposed skin thoroughly after handling. Wash contaminated clothing and shoes before reuse. DO not Eat, Drink or Smoke when using this product. Do not inhale gases/fumes/dust/mist/vapors/aerosols. Avoid contact with eyes and skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Liquid Appearance Aqueous solution Odor Sulphurous Color Clear Odor Threshold No information available Property Values Remarks/ Method ph <1 None known Melting/freezing point Below 0 C None known Page 5 / 11

Boiling point / boiling range No data available None known Flash Point No data available None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure 23 hpa (17.3 mm Hg) None known Vapor density No data available None known Specific Gravity Approximately 1 None known Water Solubility Soluble in water. None known Solubility in other solvents No data available None known Partition coefficient: No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known 10. STABILITY AND REACTIVITY Reactivity No relevant information available. Chemical stability No decomposition if used and stored according to specifications Possibility of Hazardous Reactions Toxic fumes may be released if heated above the decomposition point. Reacts with certain metals. Reacts with Alkalis. Conditions to avoid Store away from oxidizing agents. Incompatible materials Alkalis. Hazardous Decomposition Products Oxides of Sulfur Component Information Bases on available data, the classification criteria are not met. Information on toxicological effects 11. TOXICOLOGICAL INFORMATION IARC: None of the ingredients are listed. NTP: 7664-93-9 Sulfuric acid K OSHA-Ca: None of the ingredients are listed Probable routes of exposure: Ingestion, Inhalation, Eye Contact, Skin Contact. Ecotoxicity No relevant data available 12. Ecological Data Persistence and Degradability Not applicable for text method. Bioaccumulation Not Bioaccumulative. Page 6 / 11

Mobility in soil Aqueous solution has high mobility in soil. Other adverse effects No relevant data available 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not dispose together with household garbage. Do not allow product to reach sewage system or open water. DOT Not Regulated 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION Chemical Inventories TSCA Complies DSL/NDSL Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Page 7 / 11

U.S. Federal Regulations SARA 313 None of the ingredients are listed. SARA 311/312 Hazard Categories None of the ingredients are listed US State Regulations California Proposition 65 None of the ingredients are known to cause cancer. 16. OTHER INFORMATION NFPA Health Hazards Flammability Instability Physical and Chemical Properties 1 0 0 W HMIS Health Hazards Flammability Physical Hazards Personal protection 1 0 0 X Prepared By Technical Department Preparation/Revision Date January 2019 Version 3 Reference General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 11