1: Identification Product identifier Recommended use of the chemical and restriction on use Recommended use*: printer ribbon * The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: HUZHOU YUHUA STATIONERY CO.,LTD No.118 Jixiang Road, Fenghuang West District, Huzhou economy &technology zone, Zhejiang, China. Telephone: +86-572-2119996 E-mail address: monica-yuhua@foxmail.com Emergency telephone number Telephone: +86-572-2119996 2: Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Classification of the product Aquatic Acute 3 Hazardous to the aquatic environment,acute hazard Aquatic Chronic 3 Hazardous to the aquatic environment,long-term hazard Label elements The product does not require a hazard warning label in accordance with GHS criteria. Hazard Statement : H402 Harmful to aquatic life 1 / 8
H412 Harmful to aquatic life with long lasting effects Precautionary Statements (Prevention): P273 Avoid release to the environment. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified No specific dangers known, if the regulations/notes for storage and handling are considered. 3: Composition/Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 The product contains: CAS Number Content (W/W) Chemical name 495-54-5 0.1-1.0 % 4-(phenylazo)benzene-1,3-diamine 4. First-aid measures If inhaled: Due to physical form, inhalation is not expected. If on skin: In the unlikely event that irritation occurs, flush with water. If irritation persists, seek medical attention. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Accidental ingestion may necessitate medical attention. If symptoms occur, seek medical attention. Do not induce vomiting. Seek medical attention. 2 / 8
5. Fire-fighting measures Suitable extinguishing media: Dry powder, foam, carbon dioxide, water Hazards during fire-fighting: harmful vapors Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turnout gear. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions: Use personal protective clothing. Wear chemical resistant protective gloves. Environmental precautions: Do not discharge into environment. Cleanup: Shovel into suitable container for disposal. 7. Handling and storage Handling General advice: Ensure thorough ventilation of stores and work areas. Storage General advice: Keep product in a cool place. 8. Exposure controls and personal protection 3 / 8
Components with workplace control parameters None required with normal handling Personal protective equipment Respiratory protection: Respiratory protection should not be required for normal use and handling. Hand protection: Chemical resistant protective gloves. Eye protection: Wear safety glasses. Body protection: Wear protective clothing. 9. Physical and chemical properties Form, Color: Odor: ph value: Flash point Melting temperature: Boiling temperature: Evaporation rate: Flammability: Upper/lower flammability or explosive limits: Vapor pressure: Vapor density: Relative density: Solubility in water: Partition coefficient:n-octanal/water: Auto-ignition temperature: Decomposition temperature: Viscocity: Nylon tape saturated with ink,black Slight pungent odor >260 C Not highly flammable Not soluble Not applicable 4 / 8
10. Stability and reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid No conditions to avoid anticipated. Incompatible materials Substances to avoid: No further relevant information available. Hazardous decomposition products No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological information Information on toxicological effects Acute toxicity Assessment of acute toxicity: Oral Inhalation Not applicable Dermal Irritation 5 / 8
Respiratory/Skin sensitization. Carcinogenicity Assessment of carcinogenicity: Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. Reproductive toxicity Assessment of reproduction toxicity:. Developmental toxicity. Specific target organ toxicity (single exposure) Assessment of STOT single:. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity:. Aspiration hazard No aspiration hazard expected. 12. Ecological information Toxicity Harmful to aquatic life with long lasting effects Microorganisms/Effect on activated sludge Toxicity to microorganisms No applicable information available Persistence and degradability 6 / 8
Assessment biodegradation and elimination (H2O) No applicable information available. Bioaccumulative potential Assessment bioaccumulation potential No applicable information available. Mobility in soil Assessment transport between environmental compartments No applicable information available.. Additional information No applicable information available. Other ecotoxicological advice:. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Container disposal: Dispose of container in an environmentally safe manner. 14. Transport information Land transport USDOT Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 7 / 8
15. Regulatory information Federal Regulations Registration status: TSCA, US released / listed SARA hazard categories (EPCRA 311/312): Not hazardous; NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 0 Special: HMIS III rating Health: 1 Flammability: 1 Physical hazard: 0 16. Other information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use,processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. END OF DATA SHEET 8 / 8