Product Safety Information (PSI) PyroBubbles Replaces the safety data sheet. No hazardous substance according to CLP regulation, see chapter 2 Please note the general information in chapter 16 other data 1. Product Details / Manufacturer 1.1 Product Identifier Trade name PyroBubbles REACH registration number No obligation to register 1.2 Relevant Identifiable uses of the Substance or Mixture and uses we advise against Application of the substance Not recommended applications Functional lightweight filler None 1.3 Details on the Distributor, who provides the Product Safety Information Supplier Genius Technologie GmbH, Am Theresenhof 2 15834 Rangsdorf, Deutschland E-Mail (responsible person) 1.4 Emergency Information Telefon: +49 3375 24 609 60 Telefax: +49 3375 24 609 66 info@genius-group.de Emergency number supplier Cell phone OSTHOFF OMEGA PRODUCTION & TECHNOLOGIE GmbH Am Theresenhof 2, D-15834 Rangsdorf +49 3375 24 609 70 +49 172 38 23 171 22.05.2016
2. Possible Dangers 2.1 Classification of the Substance or Mixture Classification according to regulation (EG) Nr. 1272/2008 Information concerning particular hazards for human and environment Not classified according to CLP-regulation In solid form, this material is not hazardous. Dust generated from grinding etc. may cause irritation. Please note the information of this Material Safety Data Sheet. 2.2 Labelling Elements Classification according to regulation (EG) Nr. 1272/2008 Hazard pictograms Signal word Hazard statements Hazard classification No labelling required 2.3 Other Dangers Other dangers 3. Composition / Specification of the Elements Continued contact with respirable dust in high concentration of this product can affect the lung function. This product is not respirable when being supplied. 3.1 Chemical Characterization Description Dangerous substances Multi cellular glass hollow spheres None 4. First Aid Measures 4.1 Description of First Aid Measures General Information After inhalation After skin contact After eye contact After swallowing If symptoms persist or in case of doubt, seek medical advice Supply fresh air, consult doctor in case of complaints Wash with water and soap. Remove contaminated clothes and shoes. Rinse the eyes with open eyelids for 10-15 minutes with water. Consult doctor in case of persistent complaints Rinse mouth with water. Spit all liquid out again. Seek medical treatment. 4.2 Medical Treatment or special Treatment Most important symptoms and effects, both acute and delayed Medical treatment or special Treatment After swallowing: Irritant effect on the respiratory tract Irritation of mucous membranes Symptomatic treatment
5. Fire Fighting Measures 5.1 Extinguishing Agent Suitable extinguishing agents For safety reasons unsuitable extinguishing agents: The product is not combustible and does not support combustion High volume water jet 5.2 Special Dangers originating from the Product or Mixtures Special dangers None 5.3 Instructions for Fire Extinguishing Self-contained breathing apparatus 6. Measures in Case of unintentional Emission 6.1 Precautions, Protection Equipment and applicable Methods in Case of Emergencies Person-related safety precautions 6.2 Measures for Environmental Protection Measures for environmental protection 6.3 Measures for Cleaning/Collecting Bulk material 6.4 References to other Chapters Avoid contact with eyes and skin. Avoid formation of dust. Ensure adequate ventilation. Please notice chapter 8 No special measures required Information on safe handling See section 7 Information on personal protection See section 8 equipment Disposal See chapter 13 Recover and dispose in suitable containers. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ake sure to recycle or dispose of in suitable receptacles. Dispose contaminated material as waste according to item 13 7. Handling and Storage 7.1 Information for safe Handling Information for safe handling Avoid formation of dust, and must be regularly removed. Wear suitable protective gear (for example googles, gloves ). If dust concentration exceeds the regulated limits a suitable, approved breathing apparatus must be used. Prolonged exposure to the skin should be avoided. Wash hands after handling Information about protection against explosions and fires 7.2 Requirements for safe Storage, considering Incompatibilities Requirements to be met by storerooms and receptacles Information about storage in one common storage facility No special measures required. The product is non-combustible, non-oxidizing and not explosive Not required Storage 7.3 Specific Applications Specific applications Class 13 non-combustible solid (VCI) Avoid milling and other processes which may produce respirable dust
8. Limitation and monitoring of Exposition / Personal Protective Gear about design of technical systems Mechanical ventilation/ exhaustion is recommended 8.1 Monitoring of significant Parameters Components with threshold values that require monitoring at the workplace The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace The general limits of 3 mg/m³ for alveolar dust and 10 mg/m³ for inhalable dust fraction is to be heeded. For details see TRGS 900 8.2 Limitation and monitoring of Exposition Eyes- / face protection Skin- / hand protection Respiratory protection In case of dust formation, the use of protective googles is advised The use of protective gloves is advised while handling the material In case of unintentional release of the substance, exceeding the occupational exposure limit value, use short term filter device. particle filter P2 General protective- and hygienic precautions Do not inhale dust/ smoke/ mist. Use skin protection cream for skin protection. Do not eat, drink or smoke while working. Contaminated clothing should be cleaned with a vacuum cleaner, do not brush or blow the clothing. Wash hands bevor breaks and after work 9. Physical and chemical Properties 9.1 Information about elementary Physical and Chemical Properties Physical form Solid Shape Spherical Color White Odor Odorless Grain gross density (kg/m³) 380-520 Bulk density (kg/m³) 235 ± 10% Solubility in / Miscibility with Water Not miscible or difficult to mix 9.2 Additional Information Other parameters listed in appendix 2 REACH regulation are not applicable
10. Stability and Reactivity 10.1 Reactivity Reactivity 10.2 Chemical Stability Chemical stability 10.3 Possibility of dangerous Reactions Dangerous reactions 10.4 Circumstances to Avoid Circumstances to avoid 10.5 Incompatible Materials Incompatible materials 10.6 Dangerous Products of Decomposition Dangerous products of decomposition No dangers regarding to reactivity Stable under normal conditions No dangerous reactions known No special requirements No incompatible materials known No dangerous products of decomposition are known 11. Potential Health Risks 11.1 Potential Health Risks Potential health risks 11.2 Acute Toxicity Acute toxicity 11.3 Irritation: Skin, Eye Irritation Serious eye damage/irritation 11.4 Corrosion Corrosion 11.5 Sensitization Sensitization 11.6 Toxicity repeated application Toxicity 11.7 Germ cell Mutagenicity Mutagenicity 11.8 Carcinogenicity Carcinogenicity 11.9 Reproductive Toxicity Reproductive Toxicity Does not meet the requirements for classification dangerous according to regulation (EG) Nr. 1272/2008 (CLP). See section 7, 8 and 16 No irritating effect; however, long or repeated mechanical contact may lead to redness an slight irritation Eye irritation is possible after mechanical influence (dust) No corroding effect Non-toxic
12. Environment related Information 12.1 Toxicity Toxicity 12.2 Persistence and Degradability Degradability 12.3 Bioaccumulation Potential Bioaccumulation 12.4 Mobility in Soil Mobility in soil General Notes Material is not classified as dangerous. No aquatic toxicity, not toxic for treatment plants Not applicable. The material is inorganic. The material is not photosensitive, no chemical or biological degradation is to be expected Not applicable. The material is inorganic. No significant bioaccumulation is to be expected No data available Generally not hazardous for water According to appendix 4 of VwVwS dated 17.05.1999(German regulation) 12.5 Results of the PBT- and vpvb-evaluation Results of the evaluation No PBT- or vpvb-properties 12.6 Other Harmful Effects No other harmful effects are known. The material is not deemed as harmful to environment, according to CLP 13. Disposal Considerations 13.1 Procedure of waste Treatment Disposal Considerations European waste catalogue Recommendation 14. Information regarding Transport Must be recycled or disposed of according to the regulations. Waste hast to be classified according to the European Waste Catalogue based on the identification of the waste generating source. Disposal according to instructions of local authorities. 06 00 00 WASTE FROM INORGANIC CHEMICAL PROCESSES 06 13 00 wastes from inorganic chemical processes not otherwise specified 06 13 99 wastes not otherwise specified Packagings that cannot be cleaned are to be disposed of in the same manner as the product. Empty contained packaging thoroughly. They can be recycled after thorough and proper cleaning. Disposal must be made according to official regulations. 14.1 Information regarding Transport UN Land transport ADR/RID ADR/RID- GGVSEB Maritime transport IMDG/GGVsee Air transport ICAO/IATA Non-hazardous goods according to the regulation. Non-hazardous goods according to the regulation Non-hazardous goods according to the regulation
15. Legal Regulations 15.1 Regulations regarding Safety, physical Health and environment Protection / Specific Regulations for the Substance or Mixture Additional regulations 15.2 Chemical safety Assessment Safety assessment Specific national regulations must be fulfilled This PSI was made in compliance with (EG) Nr. 1907/2006 (REACH) and (EG) Nr. 1272/2008 (CLP) 15.3 Water hazard Class Water hazard WGK 1 (mildly water polluting) self classification according annex 3 VwVws 16. Other Data 16.1 General Information Reasons for amendments: General revision Replaces version dated: 15.04.2016 Department issuing SDS: Osthoff Omega Production & Technologie GmbH Member of Genius Group Am Theresenhof 2 D-15834 Rangsdorf Phone: +49 3375 24 609 70 Fax: +49 3375 24 609 69 According to chapter 1.5.2 of the globally Harmonized System of Classification, Labelling and Packaging of Chemicals (GHS), article 58 (2)(a) and article 59(2)(b) of regulation (EG) Nr. 1272/2008 (CLP), which complements the article 31(1) REACH regulation, safety data sheets for substances and/or mixtures are only mandatory if the criteria concerning physical, health related and/or ecologic dangers are met. The product does not meet these requirements, a safety data sheet is not issued. The safety data sheet is replaced with the PSI to inform about important data concerning physical, health and/or ecologic dangers. The article 31(7) of the REACH regulation demands that relevant exposure scenarios of the chemical safety report (CSR) are listed in the appendix of the safety data sheet. According to REACH regulation appendix I, appendix 0, sub-appendix 0.6. Nr. 4 and 5 only substances and/or mixtures which are classified as dangerous have to be listed with the necessary exposure scenarios. The product is not classified as dangerous, no exposure scenarios are listed. Sources: Information provided by manufacturer 16.2 Legal Notice All information in this PSI relate to the requirements necessary for safe handling of the substance and complies with the best of our knowledge with our insights at the time of its preparation. The Fire-Shield I AG gives no guarantee, warranty or declaration concerning the accuracy, reliability or completeness. It is therefore the responsibility of the customer to check the information in terms of adequacy and completeness for his particular purposes.