ACT ORIGINAL CODE : Revision date: 04/03/2019 Version: 102 Generated : 04/03/2019 SECTION 1: Identification of the substance/mixture and of the company/undertaking 11 Product identifier Product form : Mixture Product name : Product code : Type of product : Detergent 12 Relevant identified uses of the substance or mixture and uses advised against 121 Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture 122 Uses advised against 13 Details of the supplier of the safety data sheet SELDEN RESEARCH LIMITED : Professional use : For professional use only : Acidic descaling toilet cleaner STADEN LANE, BUXTON, DERBYSHIRE, SK17 9RZ, UNITED KINGDOM Tel: 01298 26226 Fax: 01298 26540 Email: safety@seldencouk 14 Emergency telephone number Emergency number : Mon to Fri 830am to 500pm - 01298 26226 SECTION 2: Hazards identification 21 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP] Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Full text of H statements : see section 16 H315 H319 Adverse physicochemical, human health and environmental effects 22 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP]Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) 23 Other hazards GHS07 : Warning : H315 - Causes skin irritation H319 - Causes serious eye irritation : P264 - Wash hands thoroughly after handling P280 - Wear eye protection, protective gloves P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse SECTION 3: Composition/information on ingredients 31 Substances Not applicable Document generated @ 04/03/2019 15:35:54 GB - en Page 11/6
32 Mixtures Name Product identifier % Classification according to Regulation (EC) No 1272/2008 [CLP] sulphamidic acid; sulphamic acid; sulfamic acid (CAS-No) 5329-14-6 (EC-No) 226-218-8 (EC Index-No) 016-026-00-0 (REACH-no) 01-2119488633-28 Full text of H-statements: see section 16 10-15 Eye Irrit 2, H319 Skin Irrit 2, H315 Aquatic Chronic 3, H412 SECTION 4: First aid measures 41 Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell : Remove person to fresh air and keep comfortable for breathing : Wash with plenty of water/ 42 Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause respiratory irritation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : IF IN EYES: Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do Continue rinsing If eye irritation persists: Get medical advice/attention : Give nothing or a little water to drink Get medical advice/attention if you feel unwell : Repeated exposure may cause skin dryness or cracking : Causes eye irritation 43 Indication of any immediate medical attention and special treatment needed Treat symptomatically SECTION 5: Firefighting measures 51 Extinguishing media Suitable extinguishing media 52 Special hazards arising from the substance or mixture 53 Advice for firefighters : May cause a light irritation of the linings of the mouth, throat, and gastrointestinal tract : Carbon dioxide Dry powder Foam SECTION 6: Accidental release measures 61 Personal precautions, protective equipment and emergency procedures 611 For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel 612 For emergency responders Protective equipment 62 Environmental precautions Avoid release to the environment 63 Methods and material for containment and cleaning up For containment : Collect spillage Methods for cleaning up : Use personal protective equipment as required : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible 64 Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" For further information refer to section 13 SECTION 7: Handling and storage 71 Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with eyes : Do not eat, drink or smoke when using this product 72 Conditions for safe storage, including any incompatibilities Technical measures : Does not require any specific or particular technical measures Storage conditions Incompatible products Special rules on packaging 73 Specific end use(s) : Keep container closed when not in use : Oxidizing agent Strong acids Strong bases : Keep only in original container Document (Version: generated 10) @ 04/03/2019 15:35:54 GB - en Page 22/6 04/03/2019 (Version: 102)
SECTION 8: Exposure controls/personal protection 81 Control parameters 82 Exposure controls Materials for protective clothing: Not required for normal conditions of use Hand protection: Chemical resistant gloves (according to European standard EN 374 or equivalent) Nitrile rubber gloves Eye protection: Safety glasses EN 166 Skin and body protection: Not required for normal conditions of use Respiratory protection: Not required for normal conditions of use Personal protective equipment symbol(s): SECTION 9: Physical and chemical properties 91 Information on basic physical and chemical properties Physical state : Liquid Appearance Colour Odour Odour threshold : Mobile liquid : Blue : Fresh ph : 17 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 106 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 92 Other information : Miscible with water SECTION 10: Stability and reactivity 101 Reactivity The product is non-reactive under normal conditions of use, storage and transport 102 Chemical stability Stable under normal conditions Document (Version: generated 10) @ 04/03/2019 15:35:54 GB - en Page 33/6 04/03/2019 (Version: 102)
103 Possibility of hazardous reactions No dangerous reactions known under normal conditions of use 104 Conditions to avoid None under recommended storage and handling conditions (see section 7) 105 Incompatible materials None under normal use 106 Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced SECTION 11: Toxicological information 111 Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Causes skin irritation ph: 17 : Causes serious eye irritation ph: 17 SECTION 12: Ecological information 121 Toxicity Acute aquatic toxicity Chronic aquatic toxicity sulphamidic acid; sulphamic acid; sulfamic acid (5329-14-6) LC50 fish 1 122 Persistence and degradability 123 Bioaccumulative potential 703 mg/l sulphamidic acid; sulphamic acid; sulfamic acid (5329-14-6) Log Pow 01 124 Mobility in soil 125 Results of PBT and vpvb assessment 126 Other adverse effects SECTION 13: Disposal considerations 131 Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 141 UN number UN-No (ADR) UN-No (IMDG) UN-No (IATA) 142 UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Document (Version: generated 10) @ 04/03/2019 15:35:54 GB - en Page 44/6 04/03/2019 (Version: 102)
143 Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) 144 Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) 145 Environmental hazards Dangerous for the environment Marine pollutant Other information 146 Special precautions for user Overland transport No data available Transport by sea No data available Air transport No data available : No : No : No supplementary information available 147 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information 151 Safety, health and environmental regulations/legislation specific for the substance or mixture 1511 EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Detergent Regulation : Labelling of contents: Component % perfumes Directive 2012/18/EU (SEVESO III) 1512 National regulations United Kingdom British National Regulations 152 Chemical safety assessment : Commission Regulation (EU) No 453/2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 Detergent Regulation (648/2004/EC) SECTION 16: Other information Full text of H- and EUH-statements: Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Irrit 2 Serious eye damage/eye irritation, Category 2 Skin Irrit 2 Skin corrosion/irritation, Category 2 H315 H319 H412 Causes skin irritation Causes serious eye irritation Harmful to aquatic life with long lasting effects Document (Version: generated 10) @ 04/03/2019 15:35:54 GB - en Page 55/6 04/03/2019 (Version: 102)
SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only It should not therefore be construed as guaranteeing any specific property of the product Document (Version: generated 10) @ 04/03/2019 15:35:54 GB - en Page 66/6 04/03/2019 (Version: 102)