GAF Safety Data Sheet SDS # 2104 SDS Date: December 2014 SECTION 1: PRODUCT AND COMPANY INFORMATION PRODUCT NAME: TRADE NAME: CHEMICAL NAME / SYNONYM: CHEMICAL FAMILY: MANUFACTURER: EverGuard H2O Bonding Adhesive Adhesive Mixture GAF ADDRESS: 1 Campus Drive, Parsippany, NJ 07054 24-HOUR EMERGENCY PHONE (CHEMTREC): 800 424 9300 INFORMATION ONLY: 800 766 3411 PREPARED BY: APPROVED BY: Corporate EHS Corporate EHS SECTION 2: HAZARD IDENTIFICATION NFPA and HMIS RATINGS: NFPA Hazard Rating HMIS Hazard Rating Health 2 Health 2 Flammable 0 Flammable 0 Reactive 0 Reactive 0 Special Hazards - Personal Protection X GHS LABEL ELEMENTS: GHS CLASSIFICATION: Eye Irritant - Category 2 Skin Irritant - Category 2 Skin sensitizer - Category 1 Target Organ (SE) - Category 3 Carcinogen - Category 2 Acute Toxicity - Category 4 Hazardous to the Aquatic Environment (chronic) - Category 3 Page 1 of 7
GHS PICTOGRAMS: SIGNAL WORD: Danger HAZARD STATEMENTS: Causes skin irritation Causes eye irritation May cause respiratory irritation Suspected of causing cancer Harmful if inhaled Harmful to aquatic life with long lasting effects ADDITIONAL HAZARD IDENTIFICATION INFORMATION: PRIMARY ROUTE OF EXPOSURE: Eyes, Skin, Inhalation SIGNS & SYMPTOMS OF EXPOSURE EYES: SKIN: INGESTION: INHALATION: ACUTE HEALTH HAZARDS: CHRONIC HEALTH HAZARDS: CARCINOGENICITY: Eye contact may cause eye irritation. Prolonged or repeated skin contact may cause irritation, dermatitis and drying of the skin. May cause gastrointestinal tract irritational if swallowed. Inhalation may cause respiratory system irritation. See above. None known. The International Agency for Research on Cancer (IARC) has determined that there is limited or inadequate evidence in humans for the carcinogenicity of exposure to Vinyl Acetate. It is Classified as a Group 2B carcinogen (Possibly Carcinogenic to Humans). SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS OCCUPATIONAL EXPOSURE LIMITS CHEMICAL NAME CAS # % (BY WT) OSHA ACGIH OTHER 2-Propenoic Acid, butly ester, polymer with ethenyl acetate and 2-propenenitrile 28063-87-8 10 30 NE NE NE Rosin, modified NE 10 30 NE NE NE Page 2 of 7
Al-silicate Kaolin 1332-58-7 5 10 5 mg/m3 resp. 15 mg/m3 total 2 mg/m3 TWA Respirable REL: 5 mg/m3 resp. 10 mg/m3 total Vinyl acetate 108-05-4 0.1 1 NE 10 ppm 4 ppm NE = Not Established SECTION 4: FIRST AID MEASRURES FIRST AID PROCEDURES EYES: SKIN: INHALATION: INGESTION: NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get immediate medical attention. Immediately wash skin thoroughly with soap and water. Remove contaminated clothing and footwear. Get immediate medical attention. Move to fresh air. If not breathing, give artificial respiration. Get immediate medical attention. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical attention. No information available. SECTION 5: FIRE FIGHTING PROCEDURES SUITABLE EXTINGUISHING MEDIA: HAZARDOUS COMBUSTION PRODUCTS: RECOMMENDED FIRE FIGHTING PROCEDURES: UNUSUAL FIRE & EXPLOSION HAZARDS: Use media appropriate for surrounding material. Carbon dioxide, carbon monoxide, ammonia. Wear impermeable protective clothing and self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Do not allow product to enter sewer or waterways. Keep unnecessary personnel away. Ensure adequate ventilation. Wear appropriate protective equipment and clothing during clean-up. Page 3 of 7
SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: OTHER PRECAUTIONS: For safe storage, store at or above 0 C (32 F). Wear suitable protective clothing, safety glasses and gloves. Avoid contact with eyes, skin and clothing. None SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS / VENTILATION: RESPIRATORY PROTECTION: EYE PROTECTION: SKIN PROTECTION: OTHER PROTECTIVE EQUIPMENT: WORK HYGIENIC PRACTICES: EXPOSURE GUIDELINES: Work should be done in an adequately ventilated area. Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Eye washes and safety showers could also be provided. Wash exposed skin prior to eating, drinking or smoking and at the end of each shift. Wash contaminated clothing prior to reuse. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE & ODOR: Cream colored liquid with a acrylic odor. FLASH POINT: Aqueous Solution LOWER EXPLOSIVE LIMIT: No data METHOD USED: No data UPPER EXPLOSIVE LIMIT: No data EVAPORATION RATE: Slower than diethyl ether BOILING POINT: 100 C (212 F) ph (undiluted product): 7.7 8.3 MELTING POINT: No data Page 4 of 7
SOLUBILITY IN WATER: Miscible SPECIFIC GRAVITY: 1.1 (Water = 1) VAPOR DENSITY: Heavier than air. PERCENT VOLATILE: No data VAPOR PRESSURE: No data MOLECULAR WEIGHT: No data VOC WITH WATER (LBS/GAL): No data WITHOUT WATER (LBS/GAL): No data SECTION 10: STABILITY AND REACTIVITY THERMAL STABILITY: STABLE X UNSTABLE CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): HAZARDOUS DECOMPOSITION OR BY- PRODUCTS: HAZARDOUS POLYMERIZATION: Freezing conditions. Carbon dioxide and carbon monoxide. Will not occur. SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: No information available. SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: No information available. SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: RCRA HAZARD CLASS: This product, as supplied, is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Comply with state and local regulations for disposal. None. Page 5 of 7
SECTION 14: TRANSPORTATION INFORMATION U.S. DOT TRANSPORTATION PROPER SHIPPING NAME: HAZARD CLASS: ID NUMBER: PACKING GROUP: LABEL STATEMENT: OTHER: This product is not classified as a hazardous material for transport. SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA: This product and its components are listed on the TSCA 8(b) inventory. CERCLA: Vinyl acetate (CAS# 108-05-4). SARA 311/312 HAZARD CATEGORIES: Acute Health Hazard, Chronic Health Hazard 313 REPORTABLE INGREDIENTS: Vinyl acetate 108-05-4 0.1 1% CALIFORNIA PROPOSITION 65: None. Other state regulations may apply. Check individual state requirements. The following components appear on one or more of the following state hazardous substances lists: Chemical Name CAS # CA MA MN NJ PA RI 2-Propenoic Acid, butly ester, polymer with ethenyl acetate and 2-propenenitrile 28063-87-8 No No No No No No Rosin, modified NE No No No No No No Al-silicate Kaolin 1332-58-7 No Yes Yes Yes Yes Yes Vinyl acetate 108-05-4 Yes Yes Yes Yes Yes Yes Page 6 of 7
SECTION 16: OTHER INFORMATION ADDITIONAL COMMENTS: DATE OF PREVIOUS SDS: October 2013 CHANGES SINCE PREVIOUS SDS: Headquarters Address Change This information relates to the specific material designated and may not be valid for such material used on combination with any other materials or in any process. Such information is to the best of our knowledge and belief accurate and reliable as of the date compiled. However, no representation, warranty or guarantee, expressed or implied, is made as to its accuracy, reliability, or completeness. It is the user s responsibility to satisfy himself as to the suitability and completeness of such information for his particular use. We do not accept liability for any loss or damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license of valid patents. Page 7 of 7