Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Company Name Colgate-Palmolive Pty Ltd (ABN 002 792 163) Address Australia: Level 14, 34 George Street, Sydney NSW 2000 Australia Emergency Tel. AUS 1800 638 6, NZ: 0800 764766 Telephone/Fax Number Tel: AUS (02) 9229 600 NZ: 04 76 6700 Fax: AUS (02) 9229 700, NZ: 04 68 883 Recommended Use Toothpaste for daily home use. Other Names Name Other 2. HAZARDS IDENTIFICATION Hazard Classification Risk Phrase(s) Safety Phrase(s) Total Plus Whitening Total Whitening New Zealand Address: Level 4, 4 Knights Road, Lower Hutt. Product Code NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Hazard classification according to the criteria NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code. R2/3 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S61 Avoid release to the environment. Refer to special instructions/safety data sheet. 3. COMPOSITION/INFORMATION ON INGREDIENTS on Product is a mixture water and additives, including those listed below. Composition Ingredients Name CAS Proportion Hazard Symbol Risk Phrase Glycerin 6-81- 10-<30 % D-Sorbitol 0-70-4 10-<30 % R48 Silica gel, 112926-00-8 10-<30 % precipitated, crystalline free 2-Butenedioic 213-40-6 < % acid, (Z)-, polymer with methoxyethene Sodium lauryl 11-21-3 < % sulphate Sodium Hydroxide 1310-73-2 <1 % Sodium fluoride 7681-49-4 <1 % Triclosan 3380-34- <0. % Alumina 1344-28-1 <0.1 % Mica 12001-26-2 <0.1 % Ingredients determined not to be hazardous Not required Balance 4. FIRST AID MEASURES Inhalation Not usually required, however under extreme circumstances if inhaled, remove from contaminated area. If symptoms develop and persist seek medical attention. Ingestion Wash out mouth with water. If irritation develops and persists seek medical attention. Print Date: 22/12/2011
Page: 2 Skin Eye First Aid Facilities Advice to Doctor Other Wash affected area thoroughly with soap and water. If symptoms develop and persist seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and persist seek medical attention. Eye wash and normal washroom facilities. Treat symptomatically. For advice in an emergency, contact a Poisons Centre (Phone Australia 13 1126; New Zealand 0800 POISON / 0800 764 766) or a doctor at once.. FIRE FIGHTING MEASURES Suitable Use appropriate fire extinguisher for surrounding environment. Extinguishing Media Hazards from Under fire conditions this product may emit toxic and/or irritating fumes and Combustion gases. Products Specific Hazards This product is non-combustible. However, following evaporation aqueous component under fire conditions, the non-aqueous component may decompose Precautions in connection with Fire and/or burn. Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage If possible contain the spill. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use steam, solvents or detergents. Dispose saturated absorbent or cleaning material appropriately. Dispose waste according to applicable regulations. It is essential that all who come into contact with this material maintain high standards personal hygiene ie. Washing hands prior to eating, drinking, smoking or using toilet facilities. Store in a cool dry place, out direct sunlight. Avoid contact with incompatible materials that support combustion, such as strong oxidising agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards No exposure value assigned for this specific material by the National Occupational Health and Safety Commission (NOHSC), Australia. However, the available exposure limits for ingredients are listed below: National Occupational Health And Safety Commission (NOHSC), Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Alumina (metal dust) - 10 - - - Mica - 2. (inspirable dust) - - Silica gel, precipitated, crystalline free 10 - - - - Sodium hydroxide - 2 (peak limitation) - - TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. Peak Limitation: A ceiling concentration which should not be exceeded over a measurement period which should be as short as possible but not exceeding 1 Print Date: 22/12/2011
Page: 3 Biological Limit Values Engineering Controls Respiratory Protection Eye Protection Hand Protection Body Protection minutes. No biological limit allocated. No special engineering controls required. Under industrial conditions, use with good general ventilation. If mists or vapours are produced local exhaust ventilation should be used. Not applicable. Industrial conditions, if engineering controls are not effective in controlling airborne exposure then respiratory protective equipment should be used suitable for protecting against airborne contaminants. Final choice appropriate breathing protection is dependant upon actual airborne concentrations and the type breathing protection required will vary according to individual circumstances. Expert advice may be required to make this decision. Reference should be made to Australian Standards AS/NZS 171, Selection, Use and maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices. Not applicable. Industrial conditions, safety glasses with side shields, goggles or full-face shield as appropriate recommended. Final choice appropriate eye/face protection will vary according to individual circumstances i.e. methods handling or engineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications. For industrial applications, wear gloves impervious material. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance. Not applicable. Industrial conditions, wear appropriate clothing including chemical resistant apron where clothing is likely to be contaminated. It is advisable that a local supplier personal protective clothing is consulted regarding the choice material. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Blue and white striped paste. Odour Not available Melting Point Not available Boiling Point Not available Solubility in Water Soluble Specific Gravity 1.29 ph Value 7.2 Vapour Pressure Not available Vapour Density Not available (Air=1) Flash Point Not applicable Flammability Not combustible, however if involved in a fire may generate toxic vapours. Auto-Ignition Not available Temperature Flammable Limits - Not applicable Lower Flammable Limits - Not applicable Upper 10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions storage and handling. Conditions to Avoid Extremes temperature. Incompatible Not available Materials Print Date: 22/12/2011
Page: 4 Hazardous Decomposition Products Hazardous Polymerization Thermal decomposition may result in the release toxic and/or irritating fumes. Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicology No toxicity data available for this material. Inhalation Inhalation product vapours may cause irritation the nose, throat and respiratory system. Ingestion Ingestion this product may irritate the gastric tract causing nausea and vomiting. Skin May cause redness, itching and irritation. Eye May cause eye irritation, tearing, stinging, blurred vision, and redness. Chronic Effects No known chronic effects. 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Persistence / Not available Degradability Mobility Not available Environ. Protection Do not discharge this material into waterways, drains and sewers. 13. DISPOSAL CONSIDERATIONS Disposal Dispose waste according to applicable local and national regulations. Considerations 14. TRANSPORT INFORMATION Transport Road and Rail Transport: Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail (7th edition). Marine Transport (IMO/IMDG): Not classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. Air Transport (ICAO/IATA): Not classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. 1. REGULATORY INFORMATION Regulatory Poisons Schedule AICS (Australia) 16. OTHER INFORMATION Date preparation or last revision MSDS Contact Person/Point Not classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled All components this product are listed on the Australian Inventory Chemical Substances (AICS). MSDS Reviewed: December 2011 Supersedes: December 2001, January 2007 24Hr Emergency Response Australia- 1800 638 6 New Zealand- 0800 764 766...End Of MSDS... Print Date: 22/12/2011
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