Safety Data Sheet Revision Number: 003.3 Issue date: 06/20/2017 1. PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE M-AC M POWDERED CONDITIONING AGENT known as FIXODINE M Product type: Product for industrial surface treatment Restriction of Use: identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 Contact information: Telephone: +1 (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Avoid breathing dust or fumes. Wash affected area thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face protection. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. Page 1 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Tetrasodium pyrophosphate 7722-88-5 50-60 Phosphoric acid, manganese salt 10124-54-6 40-50 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: If inhaled, immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Immediately wash skin thoroughly with soap and water. If symptoms develop and persist, get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes. If symptoms develop and persist, get medical attention. Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Symptoms: See Section 11. Notes to physician: Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. Not a fire hazard. Formation of toxic gases is possible during heating or in fires. Irritating and toxic gases or fumes may be released during a fire. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Wear appropriate personal protective equipment. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Sweep up or gather material and place in appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing dust. For industrial use only. Keep the container tightly closed and in a cool, well-ventilated place. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 6
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Tetrasodium pyrophosphate 0.02 mg/m3 TWA (as Mn) Respirable Phosphoric acid, manganese salt fraction. 5 mg/m3 Ceiling (as 0.1 mg/m3 TWA (as Mn) Mn) Inhalable fraction. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A written respiratory protection program, including provisions for medical certification, training, fit testing, exposure assessments, maintenance, inspection, cleaning, and convenient, sanitary storage must be implemented. If concentrations are below the TLV and/or PEL, a NIOSH approved disposable dust/mist respirator may be used for personal comfort. For concentrations above the TLV and/or PEL but less than 10 times these limits, a NIOSH approved half-facepiece respirator equipped with dust-mist cartridges may be used. For concentrations greater than 10 times these limits, consult the NIOSH respirator decision logic found in Publication No. 87-116 or ANSI Z88.2-1992. Wear chemical goggles. Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Butyl, Neoprene, PVC or Nitrile gloves recommended. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: Solid White Odorless Appreciable Not determined Page 3 of 6
10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. Will not occur. expected. This product reacts with acids. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: This product is irritating to the respiratory system. Inhalation may result in metal fume fever. Metal fume fever has flu-like symptoms including fever, chills, perspiration, cough, nasal irritation, chest pain, nausea, head ache, vomiting and muscular weakness. Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis. This product may cause irritation to the eyes. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Tetrasodium pyrophosphate Corrosive, Irritant, Metabolic Behavioral, Blood, Developmental, Irritant, Phosphoric acid, manganese salt Kidney, Liver, Lung, Mutagen, Nervous System, Reproductive, Respiratory, Vascular Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Tetrasodium pyrophosphate No No No Phosphoric acid, manganese salt No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. This chemical contains phosphates. Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimis above reporting de minimis. Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Phosphoric acid, manganese salt (CAS# 10124-54-6). No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New information added in Section(s): 2 Prepared by: Regulatory Affairs Issue date: 06/20/2017 Page 5 of 6
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6