Page: 1 Compilation date: 29/01/2015 Revision No: 1 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Company name: LMA Services Ltd Halifax Way Pocklington Industrial Estate Pocklington York YO42 1NR United Kingdom Tel: 01759 304676 Fax: 01759 305809 Email: technical@aerosol.uk.com 1.4. Emergency telephone number Emergency tel: 01759 304676 (office hours only) Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: F+: R12; N: R51/53; -: R66; -: R67 Classification under CLP: STOT SE 3: H336; Aquatic Chronic 2: H411; Eye Irrit. 2: H319; Flam. Aerosol 1: H222; -: H229 Most important adverse effects: Extremely flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 2.2. Label elements Label elements: Hazard statements: Signal words: H222: Extremely flammable aerosol. H229: Pressurised container: May burst if heated H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. H411: Toxic to aquatic life with long lasting effects. Danger
Hazard pictograms: GHS02: Flame GHS07: Exclamation mark GHS09: Environmental Page: 2 Precautionary statements: Label elements under CHIP: Hazard symbols: P102: Keep out of reach of children. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211: Do not spray on an open flame or other ignition source. P251: Do not pierce or burn, even after use. P280: Wear protective gloves/protective clothing/eye protection/face protection. P304+340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P410+412: Protect from sunlight. Do not expose to temperatures exceeding 50 ºC. Extremely flammable. Dangerous for the environment. Risk phrases: Safety phrases: Precautionary phrases: R12: Extremely flammable. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. S2: Keep out of the reach of children. S23: Do not breathe spray. S24/25: Avoid contact with skin and eyes. S29: Do not empty into drains. S51: Use only in well-ventilated areas. S61: Avoid release to the environment. Refer to special instructions / safety data sheets. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. 2.3. Other hazards Other hazards: PBT: In use, may form flammable / explosive vapour-air mixture. This product is not identified as a PBT/vPvB substance.
Page: 3 Section 3: Composition/information on ingredients 3.2. Mixtures HYDROCARBONS, C9-12, N-ALKANES, ISOALKANES, CYCLICS, (2-25%) AROMATICS EINECS CAS CHIP Classification CLP Classification Percent 919-446-0 - Xn: R65; N: R51/53; -: R10; -: R66; -: R67 PROPANE Flam. Liq. 3: H226; STOT SE 3: H336; Asp. Tox. 1: H304; Aquatic Chronic 2: H411; -: EUH066 10-30% 200-827-9 74-98-6 F+: R12 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 10-30% PROPAN-2-OL 200-661-7 67-63-0 F: R11; Xi: R36; -: R67 Flam. Liq. 2: H225; Eye Irrit. 2: H319; STOT SE 3: H336 10-30% BUTANE 203-448-7 106-97-8 F+: R12 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 1-10% HYDROCARBONS, C9, AROMATICS 918-668-5 - Xn: R65; Xi: R37; N: R51/53; -: R10; -: R66; -: R67 ISOBUTANE Flam. Liq. 3: H226; Asp. Tox. 1: H304; Aquatic Chronic 2: H411; STOT SE 3: H335; STOT SE 3: H336 1-10% 200-857-2 75-28-5 F+: R12 Substance with a Community workplace exposure limit. Flam. Gas 1: H220; Press. Gas: H280 1-10% Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Eye contact: Ingestion: Inhalation: Wash immediately with plenty of soap and water. Bathe the eye with running water for 15 minutes. Consult a doctor. Do not induce vomiting. Consult a doctor. Move to fresh air in case of accidental inhalation of vapours. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: Eye contact: Ingestion: Inhalation:
Delayed / immediate effects: Page: 4 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable. Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. 5.2. Special hazards arising from the substance or mixture Exposure hazards: Extremely flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of ignition. If outside do not approach from downwind. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Absorb into dry earth or sand. Do not use equipment in clean-up procedure which may produce sparks. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Smoking is forbidden. Use non-sparking tools. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Suitable packaging: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from direct sunlight. Keep away from sources of ignition. Must only be kept in original packaging.
Page: 5 7.3. Specific end use(s) Specific end use(s): Section 8: Exposure controls/personal protection 8.1. Control parameters PROPANE Workplace exposure limits: Respirable dust State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL UK 1800 mg/m3 7200 mg/m3 - - PROPAN-2-OL UK 999 mg/m3 1250 mg/m3 - - BUTANE UK 1450 mg/m3 1810 mg/m3 - - HYDROCARBONS, C9, AROMATICS EU - - 100 mg/ml3 - ISOBUTANE UK 2400 mg/m3 9600 mg/m3 - - DNEL/PNEC Values HYDROCARBONS, C9, AROMATICS Type Exposure Value Population Effect DNEL Oral 11 mg/kg Consumers Systemic DNEL Dermal 11 mg/kg Consumers Systemic DNEL Dermal 25 mg/kg Workers Systemic DNEL Inhalation 150 mg/m3 Workers Systemic 8.2. Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Environmental: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection not required. Chemically resistant gloves. Safety glasses. Ensure eye bath is to hand. Protective clothing. Prevent from entering in public sewers or the immediate environment.
Page: 6 Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Aerosol Colour: Pale yellow Odour: Pleasant Flash point C: -60 9.2. Other information Other information: Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. Stable at room temperature. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. 10.4. Conditions to avoid Conditions to avoid: Direct sunlight. Heat. Hot surfaces. Sources of ignition. Flames. 10.5. Incompatible materials Materials to avoid: Strong oxidising agents. Strong acids. 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects PROPAN-2-OL IVN RAT LD50 1088 mg/kg ORL MUS LD50 3600 mg/kg ORL RAT LD50 5045 mg/kg SCU MUS LDLO 6 gm/kg Toxicity values: Symptoms / routes of exposure Skin contact: Eye contact:
Ingestion: Inhalation: Delayed / immediate effects: Other information: Not applicable. Page: 7 Section 12: Ecological information 12.1. Toxicity HYDROCARBONS, C9, AROMATICS ALGAE 72H IC50 2.9 mg/l DAPHNIA 48H EC50 3.2 mg/l FISH 96H LC50 9.2 mg/l 12.2. Persistence and degradability Persistence and degradability: 12.3. Bioaccumulative potential Bioaccumulative potential: 12.4. Mobility in soil Mobility: 12.5. Results of PBT and vpvb assessment PBT identification: This product is not identified as a PBT/vPvB substance. 12.6. Other adverse effects Other adverse effects: Toxic to aquatic organisms. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: Recovery operations: Disposal of packaging: NB: Transfer to a suitable container and arrange for collection by specialised disposal company. Not applicable. Not applicable. The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information 14.1. UN number UN number: UN1950
Page: 8 14.2. UN proper shipping name Shipping name: AEROSOLS 14.3. Transport hazard class(es) Transport class: 2 14.4. Packing group 14.5. Environmental hazards Environmentally hazardous: Yes Marine pollutant: No 14.6. Special precautions for user Special precautions: No special precautions. Tunnel code: D Transport category: 2 Section 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Specific regulations: Not applicable. 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. Section 16: Other information Other information Other information: Phrases used in s.2 and s.3: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. EUH066: Repeated exposure may cause skin dryness or cracking. H220: Extremely flammable gas. H222: Extremely flammable aerosol. H225: Highly flammable liquid and vapour. H226: Flammable liquid and vapour. H229: Pressurised container: May burst if heated H304: May be fatal if swallowed and enters airways. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H411: Toxic to aquatic life with long lasting effects. R10: Flammable. R11: Highly flammable. R12: Extremely flammable.
Page: 9 R36: Irritating to eyes. R37: Irritating to respiratory system. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]