Page 1 Product Identification Product Name: Synonyms: Total ionic strength adjustment buffer, concentrate; TISAB concentrate Chemical Formula: Mixture Formula Weight: Chemical Family: Laboratory solution Integra Product Numbers: F586.7A Hazard Overview HMIS Rating: 2-0-1-C NFPA Rating: Warning Label: WARNING! Contact causes severe irritation or burns. Avoid contact with skin, eyes and clothing. Use only with adequate ventilation. Wash thoroughly after handling. Components Component CAS # % 07732-18-5 57 00064-19-7 21 07647-14-5 20 1,2-Cyclohexanediaminetetraacetic acid 13291-61-7 02 Physical Data Boiling Point: Specific Gravity: Melting Point: Evaporation Rate Vapor Pressure: Vapor Density: Air = 1 Solubility: Miscible with water. Appearance and Odor: Clear, colorless liquid. Pungent, vinegar odor. Fire and Explosion Data Flash Point: Test Method: Auto-ignition Temperature: Flammable Limits (% by volume in air): Fire Extinguishing Media: Upper: Lower: Use extinguishing media appropriate for surrounding fire. Special Firefighting Procedures: Use water to cool nearby containers and structures. Wear full protective equipment, including suitable respiratory protection. Unusual Fire and Explosion Hazards: None identified Effects of Overexposure Ski C t t
Page 2 Skin Contact: Contact may cause severe irritation or burns. Eye Contact: Contact may burn or damage the eyes. Ingestion: Harmful if swallowed. Ingestion may cause nausea, vomiting and gastrointestinal irritation and burns to the mouth and throat. Inhalation: Harmful if inhaled. Causes severe irritation or burns to the respiratory system, coughing, difficulty in breathing, chest pains, pulmonary edema, lung inflammation. Chronic Effects of Overexposure: Exposure Limits: TWA OSHA PEL STEL Ceiling 10 ppm 1,2-Cyclohexanediaminetetraacetic acid 10 ppm 15ppm 1,2-Cyclohexanediaminetetraacetic acid Toxicity Data: No information available LC50 (inhalation, mouse) TClo (human) LD50 (oral, rat) LD50 (skin, rabbit) Irritation (skin, human) Irritation (eye, rabbit) Irritation (skin, rabbit) LD50 (oral, rat) 1,2-Cyclohexanediaminetetraacetic LD50 (intraperitoneal, mouse) acid LD50 (intraperitoneal, rat) Medical Conditions Generally Aggravated by Exposure: Target Organs: Reproductive Effects: TWA ACGIH TLV STEL 5620 ppm/1h 816 ppm/3 min 3310 mg/kg 1060 mg/kg Mild, 50 mg/24 hr Moderate, 100 mg/24 hr Mild, 500 mg/24 hr 3000 mg/kg 150 mg/kg 413 mg/kg Ceiling
Page 3 Carcinogenicity: Component NTP Listing IARC Listing OSHA Regulated No listing No Listing No listing No listing No listing No Listing 1,2- Cyclohexanediaminetet raacetic acid No listing No listing Skin Contact: Emergency First Aid Procedures Immediately remove contaminated clothing. Flush skin with water for at least 15 minutes. Seek immediate medical attention. Eye Contact: Immediately flush eyes with large amounts of water, holding lids apart to ensure rinsing of entire surface. Washing eyes within several seconds of contact is essential to achieve maximum effectiveness. Get immediate medical attention. Inhalation: Remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult administer oxygen. Seek medical attention. Ingestion: Do not induce vomiting. If victim is conscious, give water. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Additional First aid and Treatment Notes: No information available Reactivity Data Stability: Stable Hazardous Polymerization: Will Not Occur Incompatibles: Incompatible with strong bases and strong oxidizers Amines. Decomposition Products: Oxides of carbon (CO, CO2) Conditions to Avoid: Contamination. Spill and Disposal Procedures Spill and Leak Procedures: Prevent spread of spill. Neutralize with soda ash or lime and sweep or scoop into suitable disposal container. Flush residues with water. Disposal Procedures: Dispose in accordance with all Local, State and Federal regulations.
Page 4 Protective Equipment Ventilation: Use general or local exhaust ventilation to meet TLV and PEL requirements. Respiratory Protection: Respiratory protection required if airborne concentrations exceed PEL or TLV. A chemical cartridge respirator with an acid/organic cartridge is recommended. Skin and Eye Protective Equipment: Safety goggles, protective clothing and gloves. Maintain an eyewash station and safety shower nearby. Storage and Handling Precautions Storage Area: CORROSIVE, ACID Store in a cool, dry, corrosive materials storage area. Minimize exposure to air and light. Protect containers from physical damage. Transportation Information Regulated Material domestic ground transportation (reference: CFR Title 49, Transportation) Proper Shipping Name: Acetic acid solution UN or Identification number: UN2790 Hazard Class and Label: 8 Packing Group: III Subsidiary Risk and Label: Corrosive Regulated Material via Air Transportation (reference: ICAO Technical Instructions for the Safe Transport of Dangerous Goods by Air) Proper Shipping Name: Acetic acid solution UN Identification Number: UN2790 Hazard Class and Label: 8 Corrosive Packing Group: III Subsidiary Risk and Label: Packing Instruction Max net qty per package Passenger Aircraft: 809/Y809 1/0.5 L Cargo Aircraft: 813 30 L Regulatory Information TSCA CERCLA SARA EHS SARA 313 Toxic Release Component Inventory RQ TPQ de minimus lbs lbs lbs 5000 lbs lbs lbs lbs lbs lbs 1,2-Cyclohexanediaminetetraacetic acid lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity 1,2-Cyclohexanediaminetetraacetic acid Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting
Page 5 MSDS Revision History: 002 - Changed header phone number 003 - Format revisions; updated header phone number 004 - Updated Header Information 005 - Updated Transportation Information Regulatory Information Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting 1,2-Cyclohexanediaminetetraacetic acid = Not established, = Not applicable or Not available The information presented above is offered for informational purposes only. This MSDS, and the associated product, is intended for use only by technically qualified persons, and at their own discretion and risk. Since conditions and manner of use are outside the control of Integra Chemical Company, we make no warranties, either expressed or implied, and assume no liability in connection with any use of this information. ***** END OF MSDS *****