Safety data sheet NEO GOLD RATPACKS. 1. Substance/preparation and company identification. 2. Hazard identification

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Transcription:

Safety data sheet Page: 1/7 1. Substance/preparation and company identification NEO GOLD RATPACKS Use: rodenticide, biocide Company: BASF SE 67056 Ludwigshafen GERMANY Contact address: BASF PLC PO Box 4, Earl Road Cheadle Hulme, Cheshire GREAT BRITAIN SK8 6QG Telephone: +44 161 485-6222 Telefax number: +44 161 4274 E-mail address: product-safety-north@basf.com Emergency information: International emergency number: Telephone: +49 180 2273-112 2. Hazard identification Possible Hazards No specific dangers known, if the regulations/notes for storage and handling are considered.

Page: 2/7 3. Composition/information on ingredients Chemical nature rodenticide, Bait, biocide Contains: Difenacoum (Content (W/W): 0.005 %) 4. First-Aid Measures General advice: Avoid contact with the skin, eyes and clothing. Take off immediately all contaminated clothing. First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If difficulties occur: Obtain medical attention. Show container, label and/or safety data sheet to physician. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. On skin contact: After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek medical attention. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth immediately with water. If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting unless told to by a poison control center or doctor. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Note to physician: Symptoms: coagulation disorders, blood in urine, loss of appetite, weakness Hazards: The product contains a blood coagulation inhibitor. Symptoms of poisoning may only appear after several hours. Treatment: Symptomatic treatment (decontamination, vital functions). Antidote: Vitamin K1 preparation as antidote. Medical monitoring for at least 24-48 hours. 5. Fire-Fighting Measures Suitable extinguishing media: carbon dioxide, dry extinguishing media, water fog, water spray, foam Unsuitable extinguishing media for safety reasons: water jet Specific hazards: carbon monoxide, carbon dioxide, nitrogen oxides

Page: 3/7 The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing. Further information: Keep containers cool by spraying with water if exposed to fire. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. In case of fire and/or explosion do not breathe fumes. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Remove contaminated clothes, undergarments and shoes immediately. Avoid dust formation. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil. Methods for cleaning up or taking up: For small amounts: Contain with dust binding material and dispose of. For large amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. 7. Handling and Storage Handling No special measures necessary if stored and handled correctly. If dead and/or dying rats or mice are found during and after the control program, these must be cleared away immediately in order to avoid secondary poisoning phenomena. Do not apply in the open (use bait boxes, bait cartons or foil bags). Protection against fire and explosion: Dust can form an explosive mixture with air. Avoid dust formation. Avoid deposition of dust. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy. Storage Segregate from foods and animal feeds. Further information on storage conditions: Keep only in the original container in a cool, well-ventilated place. Keep container dry. Keep away from heat. Protect from direct sunlight. Protect against moisture. Storage stability: Storage duration: 24 Months

Page: 4/7 8. Exposure controls and personal protection Personal protective equipment Respiratory protection: Respiratory protection not required. Hand protection: Although gloves are not required for the safe use of the product, they are recommended for protection against rodent-borne diseases. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is recommended. Remove contaminated clothing immediately and dispose of safely. Store work clothing separately. Keep away from food, drink and animal feeding stuffs. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift. 9. Physical and Chemical Properties Form: Colour: Odour: Melting point: Flash point: Flammability: Self ignition: granules blue-green odourless not applicable Substance/product is non-flammable. does not ignite not determined Explosion hazard: not explosive Fire promoting properties: not fire-propagating Density: 0.83 g/cm3 (approx. 20 C) Solubility in water: insoluble Partitioning coefficient n-octanol/water (log Pow): not applicable

Page: 5/7 10. Stability and Reactivity Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Hazardous reactions: No hazardous reactions if stored and handled as prescribed/indicated. The product is chemically stable. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Experimental/calculated data: LD50 rat (oral): 1.8 mg/kg Experimental/calculated data: LC50 rat (by inhalation): 0.00346-0.005848 mg/l 4 h Experimental/calculated data: LD50 rat (dermal): 63 mg/kg Irritation Assessment of irritating effects: Not irritating to eyes and skin. Respiratory/Skin sensitization Assessment of sensitization: No sensitizing effect. Other relevant toxicity information Misuse can be harmful to health. 12. Ecological Information Ecotoxicity Toxicity to fish:

Page: 6/7 LC50 (96 h) 0.064 mg/l, Oncorhynchus mykiss Aquatic invertebrates: LC50 (48 h) 0.52 mg/l, Daphnia magna Aquatic plants: No observed effect concentration (72 h) 0.25 mg/l (growth rate), Pseudokirchneriella subcapitata Assessment of terrestrial toxicity: Hazardous to birds and mammals. Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. The product has not been tested. The ecological data given are those of the active ingredient. 13. Disposal Considerations Must be dumped or incinerated in accordance with local regulations. This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (GB) The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom). Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product. 14. Transport Information Land transport ADR

Page: 7/7 RID Inland waterway transport ADNR Sea transport IMDG Air transport IATA/ICAO 15. Regulatory Information Regulations of the European union (Labelling) / National legislation/regulations EEC Directives: The product does not require a hazard warning label in accordance with EC Directives. Other regulations The data should be considered when making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials' (United Kingdom). 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. If you have any queries relating to this MSDS, it's contents or any other product safety related questions, please write to the following e-mail address: product-safety-north@basf.com The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.