Click http//www.guidechem.com/cas-111/111-90-0.html for suppliers of this product Ethanol,2-(2-ethoxyethoxy)- (cas 111-90-0) MSDS 1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. Diethylene glycol monoethyl ether 537616-111-90-0 1.2 Relevant identified uses of the substance or mixture and uses advised against 2. 2.1 2.2 2.3 Identified uses Laboratory chemicals, Manufacture of substances HAZARDS IDENTIFICATION Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. This substance is not classified as dangerous according to Directive 67/548/EEC. Label elements The product does not need to be labelled in accordance with EC directives or respective national laws. Other hazards - none 3. 3.1 COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms CARBITOL? 2-(2-Ethoxyethoxy)ethanol Ethyldiglycol Diethylene glycol ethyl ether DE Solvent Formula Molecular Weight C6H14O3 134,17 g/mol 4. 4.1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. 4.2 4.3 In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Indication of any immediate medical attention and special treatment needed 5. 5.1 5.2 5.3 FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Advice for firefighters
5.4 6. 6.1 6.2 6.3 6.4 7. 7.1 7.2 7.3 Wear self contained breathing apparatus for fire fighting if necessary. Further information ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Specific end uses 8. 8.1 8.2 EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9. 9.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) Appearance Odour Form liquid, clear Colour colourless
c) d) e) f) g) Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point 202 C - lit. 96 C - closed cup h) Evaporation rate 0,02 i) Flammability (solid, gas) j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density m) Relative density n) Water solubility 9.2 o) p) q) r) s) t) Partition coefficient n- octanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties Other safety information Upper explosion limit 23,5 %(V) Lower explosion limit 1,2 %(V) 0,16 hpa at 20 C 4,63 - (Air = 1.0) 0,999 g/cm3 at 25 C soluble 10. 10.1 10.2 10.3 10.4 10.5 10.6 11. 11.1 STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides Hazardous decomposition products Other decomposition products - TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral - rat - 10.502 mg/kg LC50 Inhalation - rat - > 200 mg/l LD50 Dermal - rabbit - 9.143 mg/kg Skin corrosion/irritation Skin - rabbit - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - Mild eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. May be harmful if swallowed. May be harmful if absorbed through skin. May cause skin irritation. Causes eye irritation. Signs and Symptoms of Exposure Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information RTECS KK8750000 12. 12.1 12.2 12.3 12.4 12.5 12.6 13. 13.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects DISPOSAL CONSIDERATIONS LC50 - Pimephales promelas (fathead minnow) - 9.650 mg/l - 96 h LC50 - Daphnia magna (Water flea) - 3.340 mg/l - 48 h Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. 14. TRANSPORT INFORMATION 14.1 UN number ADR/RID - 14.2 UN proper shipping name ADR/RID IMDG Not dangerous goods Not dangerous goods IATA Not dangerous goods 14.3 Transport hazard class(es) ADR/RID - 14.4 Packaging group ADR/RID - 14.5 Environmental hazards ADR/RID no 14.6 Special precautions for user IMDG - IMDG - IMDG - IMDG Marine pollutant no IATA - IATA - IATA - IATA no 15. REGULATORY INFORMATION
15.1 15.2 16. This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment OTHER INFORMATION Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.