Section 1 Identification Trade Name: General Info Phone: (770) 424-7550 Product Identification: 5880 Emergency Phone: (800) 255-3924 Synonyms: DEET mixture Product Use Description: Insect repellent Section 2 Hazards Identification Classifications Flammable Aerosols - Category 1 Gasses under pressure - Liquefied gas Eye Irritation - Category 2 Specific Target Organ Toxicity (single exposure) - Category 3 Supplier: ATCO International 1401 BARCLAY CIRCLE SE MARIETTA, GA 30060 Flammable Compressed Gas Irritant Signal Word: Danger Hazard Statements Keep out of reach of children. Read label and SDS before use. Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause drowsiness or dizziness. Causes serious eye irritation. Precautionary Statements Prevention Avoid breathing mist/spray. Use only outdoors or in a well-ventilated area. Keep away from heat, sparks, open flames and hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid overapplication of this product. Do not spray directly onto face; spray on hands first and then apply sparingly and avoid eyes. After returning indoors wash treated skin with soap and water. Response If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. Storage Trade Name: SDS #: 5880 Page 1 of 6
Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Store in a well-ventilated place. Store locked up. Disposal Dispose of contents and container in accordance with all local, regional, and national regulations. Hazards Not Otherwise Specified Not applicable Section 3 Composition Concentration Chemical Name CAS # % by Weight Isopropanol 67-63-0 >=60 <= 70 Propane 74-98-6 >=10 <= 15 Isobutane 75-28-5 >=1 <= 5 N,N-diethyl-m-toluamide 134-62-3 =15 Section 4 First Aid EMERGENCY OVERVIEW DANGER. Extremely flammable. Contents under pressure. Keep away from heat and flame. Avoid breathing spray. Keep away from eyes. EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. SKIN: Wash with plenty of soap and water after returning indoors. If skin irritation or rash occurs get medical attention. INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. INGESTION: May be harmful if swallowed. Seek medical attention immediately. Do NOT induce vomiting. Section 5 Fire Fighting Measures Trade Name: SDS #: 5880 Page 2 of 6
Suitable fire extinguishing media: Use water spray, fog or foam. Specific hazards arising from the chemical: Flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Hazardous thermal decomposition products: Carbon Dioxide, Carbon Monoxide Specific fire-fighting methods: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective equipment for fire fighters: Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in a positive pressure mode. Section 6 Accidental Release Measures Personal precautions: Put on appropriate personal protective equipment (see section 8) Environmental precautions and clean-up methods: Stop all leaks. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Eliminate all ignition sources. Disperse vapors with water spray. Prevent runoff from entering drains, sewers, streams or other bodies of water. Absorb spill with inert material. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Section 7 Handling and Storage Do not use or store near heat, sparks or open flame. Exposure to temperatures above 120 F may cause bursting. Do not puncture or incinerate container. Store in a cool, dry place. Do not get in eyes. Intentional misuse by deliberately concentrating and inhaling may be harmful or fatal. Keep out of reach of children. Section 8 Exposure Controls/Personal Protection Isobutane ACGIH TLV 1000 ppm Isopropanol ACGIH TLV OSHA PEL Propane ACGIH TLV 400 ppm 400 ppm 1000 ppm Trade Name: SDS #: 5880 Page 3 of 6
Eye Protection: Wear safety glasses or goggles. Skin Protection: To prevent repeated or prolonged contact, wear impervious gloves (made from rubber, nitrile or neoprene). Respiratory Protection: Not required under typical use conditions. When respiratory protection is required use an organic vapor cartridge. A respiratory program that meets OSHA's 29 CFR 1910.34 & ANSI Z88.2requirements must be followed. Engineering Controls: Good general ventilation required. Section 9 Physical and Chemical Properties Property Value Appearance CLEAR SPRAY/MIST Auto Ignition Temp NOT AVAILABLE Boiling Point NOT AVAILABLE Color COLORLESS Decomposition Temperature NOT AVAILABLE Evaporation Rate NOT AVAILABLE Explosive Limit Ranges NOT AVAILABLE Explosive Properties NOT AVAILABLE Flash Point 50 F (liquid portion) Melting/Freezing Point NOT AVAILABLE Odor PLEASANT Odor Threshold NOT AVAILABLE Other Information VOC content (wt. %): 81 Oxidizing Properties NOT AVAILABLE Partition Coeff NOT AVAILABLE Physical State LIQUID Relative Density 0.9 Solubility (Water) PARTIAL Vapor Density NOT AVAILABLE Vapor Pressure NOT AVAILABLE Viscosity NOT AVAILABLE ph NOT APPLICABLE Section 10 Stability and Reactivity Reactivity : Chemical Stability : Incompatible Materials : Conditions to Avoid : Decomposition Products: Under normal conditions of storage and use, hazardous reactions will not occur. Stable under normal conditions. Acids, strong oxidizers. High temperatures, open flames, sparks, welding. CO, CO2 Vapors may ignite at temperatures exceeding flash point. Section 11 Toxicological Information Primary Route of Entry: Inhalation, eye and skin contact Acute/Potential Health Effects: EYES: Causes serious eye irritation. Symptoms include stinging, tearing and redness. SKIN: May cause skin reactions in rare cases. Symptoms may include redness and drying of skin. INHALATION: High vapor/aerosol concentrations (>1000 ppm) are irritating to the eyes and respiratory tract. May cause nose, throat and respiratory tract irritation, coughing and headache. INGESTION: May be harmful if swallowed. Chronic / Long Term Effects: Overexposure to this material through inhalation may cause central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness). Target Organ Effects: Central nervous system. Reproductive/Developmental Information: None known. Carcinogenic Information: This material is not listed as a carcinogen by IARC, NTP or OSHA. Acute Toxicity Values: DEET: Oral, rat: LD50 = 1892 mg/kg. Trade Name: SDS #: 5880 Page 4 of 6
Section 12 Ecological Information DEET: LC50 Fish: Rainbow trout - 97 mg/l, 96 hr; EC50 Daphnia -75 ppm, 48 hr.. Section 13 Disposal Considerations Waste must be disposed of in accordance with federal, state and local environmental control regulations. See label for further instructions. Section 14 Transport Information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. UN number 1950 Proper shipping name Class 2.1 Packing group - Aerosols, flammable Section 15 Regulatory Information If identified components of this product are CERCLA hazardous substances and/or listed under Sections 302, 304, or 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 (also known as EPCRA, the Emergency Planning and Community Right-To-Know Act), or under California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act), they are listed above in Section 15 of this SDS. If identified components of this product are listed under Section 313, this product contains toxic chemicals subject to the reporting requirements of Section 313. This information must be included in all SDS that are copied and distributed for this material. Title III Section 311/312 Hazardous Categories - 40 CFR 370.2: ACUTE (X) Chronic (X) Fire (X) Pressure (X) Reactive ( ) Not Applicable ( ) T.S.C.A. Status: All chemical substances found in this product comply with the Toxic Substances Control Act inventory reporting requirements. RCRA Status: Under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. If this product becomes hazardous waste it would be assigned RCRA Code(s) D001 FIFRA information This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information Trade Name: SDS #: 5880 Page 5 of 6
required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. Signal word: WARNING. Hazard statement: Causes substantial but temporary eye injury. Harmful if swallowed. Section 16 Other Information HMIS Ratings : 1 4 0 A Disclaimer: This Manufacturer believes that the information contained in the Safety Data Sheet is accurate. The suggested procedures are based on experience as of the date of the publication. They are not necessarily all inclusive nor fully adequate in every circumstance. Also, the suggestions should not be confused with, nor followed in violation of applicable laws, regulations, rules or insurance requirements. Preparation/Revision Date: 6/11/15 Trade Name: SDS #: 5880 Page 6 of 6