Materials Safety Data Sheet Lewis s Medical Supplies 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION Product Name: Intended Use: Supplied By: Insect Repellent Autan Aerosol Spray 100ml 5175N Insect Repellent Body Spray Lewis s Medical Supplies Bankside House Bankside Business Park Coronation Street South Reddish Stockport Cheshire SK5 7PG Tel: 0161 480 6797 Fax: 0161 480 4787 Email: sales@lewisplast.co.uk Web: www.lewisplast.co.uk 2. COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT CAS NO. Ethanol 64175 Butane 106978 Icaridine 1191515387 Propane 74986 EINECS WEIGHT% SYMBOL RPHRASES 2005786 2034487 2008279 5075 1020 1020 15 F F+ F+ R11 R12 R12 (R11) Highly Flammable (R12) Extremely Flammable 3. HAZARDS IDENTIFICATION (ALSO SEE SECTIONS 11 & 12) Hazard to Human Health: Not classified as dangerous according to Dangerous Preparations Directive (99/45/EC) & amendments. Spray mist, fog or vapour may cause respiratory irritation. Intentional misuse by deliberately concentrating & inhaling contents can be harmful or fatal. May cause irritation. No adverse effects expected. It is not anticipated that significant quantities of aerosol product can be ingested. If ingested: may cause abdominal discomfort.
PhysicoChemical Hazards: Environmental Hazards: Extremely Flammable. This preparation is Not Classified as Environmentally Hazardous according to Directive (1999/45/EC), as amended. 4. FIRST AID MEASURES Remove patient to fresh air. If difficulty or discomfort in breathing is experienced, get medical attention. If substance has got into eyes, immediately wash out with plenty of water for several minutes. Seek medical attention if irritation persists. In the unlikely event of skin irritation, wash affected area with plenty of soap & water. Do not induce vomiting. Rinse mouth with water (do not swallow) When in doubt or symptoms persist, seek medical attention. 5. FIRE FIGHTING MEASURES Extinguisher: Special Procedures: Special Hazards: Other Warnings: In case of fire use water spray or foam as appropriate to the circumstances. In case of fire and/or explosion, do not breathe fumes. Heating may cause an explosion. Carbon oxides may be found. Wear suitable protective clothing & gloves. Refer to current EN or National standard as appropriate. Wear Breathing Apparatus. 6. ACCIDENTAL RELEASE MEASURES Spill Control: Personal Precautions: Environmental Protection: If damage occurs to the aerosol can: Shut off all ignition sources. Absorb spillage in suitable inert material. Do not absorb spillage in sawdust or other combustible material. Sweep or shovelup spillage & remove to a safe place. Use nonsparking equipment. Take precautionary measures against static discharges. Clean residue from spill site. Wear suitable gloves. Wear safety glasses. Refer to current EN or National standard as appropriate. Wash thoroughly after dealing with spillage. Outside of normal use avoid release to the environment. Use appropriate containment to avoid environmental contamination. 7. HANDLING AND STORAGE
Handling: Storage: Conditions to Avoid: Materials to avoid: Ensure adequate ventilation. Do not breathe spray/mists. Keep away from heat & sources of ignition. Pressurized container: protect from sunlight & do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on or near naked flame or any incandescent material. Wash thoroughly after use. Keep out of reach of children. Keep away from heat & sources of ignition. Pressurised container: protect from sunlight & do not expose to temperatures exceeding 50 C. Keep container in a well ventilated place. Keep away from heat. None known. 8. EXPOSURE CONTROLS / SPECIAL PROTECTION Exposure Control: General room ventilation is usually adequate. May be necessary to control air contaminations below listed occupational exposure limits with local exhaust ventilation. EXPOSURE LIMITS: INGREDIENT 8 HOUR TWA 15 MINUTE TWA Ethanol (Cas#64175) EH40 Butane (Cas#106978) EH40 1920 mg/m3. 1000 ppm OES UK HSE 600 ppm 1450 mg/m3. OES UK HSE EH40 Not determined 750 ppm 1810 mg/m3. OES UK HSE PROTECTIVE EQUIPMENT: Respiratory: Hands / General: Safety glasses 9. PHYSICAL AND CHEMICAL PROPERTIES Colour..Clear Physical State Aerosol Odour..Characteristic odour Boiling Point/Range..N/A Melting Point/Range.N/A Vapour Pressure N/A Flash Point..N/A Solubility in Water.Appreciable Explosive Limits %Vol..Not determined ph N/A Autoignition Temperature.Not determined Relative Density (D20/4)..0.78 Oxidising Properties.N/A Viscosity.N/A
10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Hazardous Decomposition Products: Product is stable & unreactive under normal household conditions of use. Keep away from heat & sources of ignition. None identified. 11. TOXICOLOGICAL INFORMATION (ALSO SEE SECTION 3) Estimated LD50 (Oral): Estimated LD50 (Dermal): >2g/Kg >2g/Kg Spray mist, fog or vapour may cause respiratory irritation. Intentional misuse by deliberately concentrating & inhaling contents can be harmful or fatal. No adverse effects expected. May cause irritation. May cause abdominal discomfort. 12. ECOLOGICAL INFORMATION Environmental Classification: Summary: This preparation is Not Classified as Environmentally Hazardous according to Directive (1999/45/EC) as amended. On the basis of available information this preparation is not expected to produce any significant adverse environmental effects, when used as directed. 13. DISPOSAL CONSIDERATIONS Material Disposal: Container Disposal: Disposal should be in accordance with local, state or national legislation. Disposal should be in accordance with local, state or national legislation. Please recycle empty packaging. 14. TRANSPORT INFORMATION Road/Rail (ADR/RID): UN 1950 Class 2 Label 2.1 Packing Group N/A Entry Description AEROSOLS Flammable Derogation Limited quantities derogation may be applicable to this product, please check transport documents.
Sea (IMDG): Air (ICAO/IATA) UN UN1950 Class 2 Label 2.1 Entry Description AEROSOLS Flammable EmS.FD SU MFAG..Not Applicable Marine Pollutant.No Derogation.. Limited quantities derogation may be applicable to this product, please check transport documents. ICAO Class...Not determined 15. REGULATORY INFORMATION Classification & Labelling according to: Eu. Dangerous Preparations Directive (99/45/EC) as amended. Aerosol Directive (75/324/EEC) as amended. Classification: R Phrases: S Phrases: Additional Labelling: Labelling for Biocidal Products (98/8/EC): EINECS/TSCA Status: Extremely Flammable. (R12) Extremely Flammable. (S2) Keep out of reach of children. (S16) Keep away from sources of ignition No Smoking. (S23) Do not breathe spray/mists. (S51) Use only in well ventilated areas. Pressurized container: protect from sunlight & do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on or near naked flame or any incandescent material. Contains Icaridine All components are included in these inventories. 16. OTHER INFORMATION Additional Information: Refer below for issue & revision dates. Refer to Section 2 for full text of any R Phrases that relate to components listed in Section 2. The information herein is given in good faith. No warranty, expressed or implied is made. Any use of these data & information must be determined by the user to be in accordance with applicable Federal, State & Local laws & regulations. The information contained in this form is confidential & is submitted solely for your organisation s internal use. Issue Date: 07/05/2009 Revision No: 1 Checked By: JW