Binder Modified with a Combination of PPA and SBS: The NCAT Test Track Experience PPA Workshop April 7, 2009

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Binder Modified with a Combination of PPA and SBS: The NCAT Test Track Experience PPA Workshop April 7, 2009

Acknowledgments Jean-Valery Martin, Ph.D. Innophos, Inc. Gaylon Baumgardner Paragon Technical Services Staff at the National Center for Asphalt Technology and Paragon Technical Services, Inc.

Content Introduction PPA/SBS Modified Binders PPA/SBS Binders for 00 and 03 Test Track Construction of 00 and 03 Test Track Weather Rutting Fatigue Moisture Damage Conclusion

Introduction National Center for Asphalt Technology (NCAT) Pavement Test Track 309 acre site near Auburn University Auburn Alabama Used and Sponsored by Government Agencies Throughout U.S. Designed to Aid in Research to Extend the Life of Flexible Pavements Provides Opportunity for Sponsors to Answer Questions Through Accelerated Testing

Test Track Description 1.7 mile Closed Loop Facility Consists of Forty-Six 200 ft. Test Sections Each Section Cooperatively Funded Operation and Research Managed by NCAT

Test Track Design Concept Uniform Perpetual Foundation Materials and Mix Design Unique to Each Section Design Lifetime of 10 Million ESALs Design Load Applied Over Two Year Cycle Axle Loading Precisely Monitored Surface Parameters Measured Weekly

Section Schematic

PPA/SBS Modified Binders Pre-SuperPave SBS Modified Asphalt Post-SuperPave SBS Modified Asphalt

PPA/SBS Modified Binders

PPA/SBS Binders for NPTT-2000 NCAT No Specific Objective for Binder or Binder Supplier Single Source Binder Supplier PG67-22 and PG76-22 Binder Supplier Selected Binder Formulation Performance Economics Results of Mississippi I-55 Field Trial Current Products Marketed

PPA/SBS Binder for NPTT-2000 2000 Test Track Formulation SuperPave PG76-22 Venezuelan Crude Source 3.5 Weight Percent SBS Block Co-Polymer 0.25 Weight Percent Polyphosphoric Acid (105) 0.05 Weight Percent Amine Anti-Stripping Agent

PPA/SBS Binder for 2000 Test Track (PG76-22)

PPA/SBS Binders for 2003 Test Track NCAT No Specific Objective for Binder or Binder Supplier Sponsors Recommended Binder and Binder Supplier Primary Binder Supplier Selected Binder Formulation PG70 and PG76-22 Performance Economics Results of Mississippi I-55 Field Trial Current Products Marketed

PPA/SBS Binder for 2003 Test Track (PG76-22) 2003 Test Track Formulation (Identical to 2000 formulation) SuperPave PG76-22 Venezuelan Crude Source 3.5 Weight Percent SBS Block Co-Polymer 0.25 Weight Percent Polyphosphoric Acid (105) 0.05 Weight Percent Amine Anti-Stripping Agent

PPA/SBS Binder for 2003 Test Track (PG76-22)

PPA/SBS Binder for 2003 Test Track (PG70-22) 2003 Test Track Formulation SuperPave PG70-22 Venezuelan Crude Source 1.4 Weight Percent SBS Block Co-Polymer 0.25 Weight Percent Polyphosphoric Acid (105) 0.05 Weight Percent Amine Anti-Stripping Agent

PPA/SBS Binder for 2003 Test Track (PG70-22)

Construction of 2000 Test Track Ten Sponsoring Entities Nine State DOTs Federal Highway Administration Designed to Suit All Sponsor Experimental Needs Underlying Pavement Structure Identical in Every Section Common Interest Effect of Gradations (ARZ and BRZ) Effect PG on Rutting Performance

Construction of 2000 Test Track Two States- Effect of Mix Design Methodology on Rutting Performance Two States- Compare Gravel to Stone Mixes One State- Compare Different NMAS

Construction of 2000 Test Track Eighteen Sections Contained PPA/SBS Modified PG76-22 Various Aggregates Limestone Slag Gravel Granite Marble Schist Combinations of the Above

Construction of 2000 Test Track Moisture Sensitivity not Specific Area of Interest All Sections With the Exception of N11 and N12 Contained Liquid Amine Anti-Stripping Some Sections Contained both Liquid Amine Anti-Stripping Agent and Hydrated Lime Sections N11 and N12 Contained Only Hydrated Lime

Construction of 2003 Test Track Eleven Sponsoring Entities Ten State DOTs Federal Highway Administration Sponsors of 2000 Test Track Were Allowed to Leave Sections to Extended Traffic Rutting Expected to be Minimal in Sections left to Traffic

Construction of 2003 Test Track Twenty-Three of the Existing Sections were left to Extended Traffic Nine Sections Left to Extended Traffic Utilized PPA/SBS Modified PG76-22 Twenty-Two New Sections Built Nine Sections Reconstructed or Partially Reconstructed Using PPA/SBS Modified Binder Six PG76-22 and Three PG70-22

Construction of 2003 Test Track (22 New Sections) New Sponsor Sections Designed to Suit All Sponsor Experimental Needs Underlying Pavement Structure Identical in Every Section as with 2000 Test Track Objective Evaluate Potential to Predict Performance

Construction of 2003 Test Track (22 New Sections) Sponsors Supplied Variety of Aggregates Sponsors Relied on Various Sources of Binder In Sections Discussed, PG76 and PG70 Supplied by Single Source All Newly Constructed Sections Contained Liquid Amine Anti-Strip

Construction of 2003 Test Track (22 New Sections) Eight Sections were Utilized for a Structural Experiment Did not Contain PPA/SBS Modified Binder Fourteen New Sections were Shallow Mill and Inlay for Rutting Study Nine Inlay Sections Contained PPA/SBS Modified Binder

Weather

PERMANENT DEFORMATION

Permanent Deformation 2000 Test Track

Permanent Deformation 2000/2003 Test Tracks Extended bars represent additional rutting from 10 million ESALs of 2003 Track

Permanent Deformation 2000 Test Track Rutting Considered to be Minimal to None in all Sections PPA/SBS Sections Minimum of 0.6 mm (0.02 inch) Maximum of 4.95 mm (0.19 inch) Unmodified PG67-22 Sections Minimum of 2.1 mm (0.08 inch) Maximum of 8.1 mm (0.32 inch)

Permanent Deformation 2003 Test Track

Permanent Deformation 2003 Test Track *PG 70-22 ** Fatigue Failure 2,000,000 ESALs Gray bar sections= SBS Modified PG 76-22 in upper layer

Permanent Deformation 2003 Test Track Rutting in all Tangent Sections of 2003 Test Track Considered to be Minimal at 2-5 mm Average Accumulated Rut Depth of Sections Containing PPA/SBS Modified Binders was a low of 2.14 mm (0.084 inch) PG76 to a High of 4.48 mm (0.191 inch) PG70

Permanent Deformation 2003 Test Track Sections Using Conventional SBS Modified Binders Exhibited More Rutting than PPA/SBS Modified Sections SuperPave Grade Bumping Proved Beneficial in Reduction of Permanent Deformation PG76 < PG70 < PG67

FATIGUE

Fatigue 2000 Test Track Fatigue Cracking Observed in Four Test Sections of 2000 Test Track. All Fatigue Cracked Sections were Polymer Modified Only One Section Contained PPA/SBS Modified Binder PPA/SBS Modified Section Left to 20M ESALs of Traffic All Gravel BRZ Mix (Least Rutting) Stiff-Low Binder Content (Top Down 50-100mm)

Fatigue 2003 Test Track Fatigue Cracking Observed in Three Test Sections All Sections Within the Eight Structural Sections None of the Fatigue Cracked Sections Contained PPA/SBS Modified Binder Two Sections Contained SBS Modified Binder

Moisture Damage Average Annual Rainfall in Excess of 40 inches Some Aggregates in Construction of Both Research Cycles Susceptible to Moisture Damage Moisture Damage was not a Mode of Failure Identified in Either Research Cycle In Top Down Cracked Sections Moisture Damage was not Apparent

Conclusion Effect of PPA on Binder and Pavement Performance Extremely Studied/Documented Use of PPA Debated /Banned without Just Cause Research from NCAT Test Track Provided Information in Six Years that Would Normally Take about 20 Years NCAT Pavement Test Track Provided Comprehensive Performance Evaluation of PPA/SBS Modified Binders

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