Revised edition: 14.06.2013 1. 1. 1. Version: 2 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Tung Oil 1. 2. Article No.: 73900 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Chemical for different applications. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H317 Cat.: 1 Classification according to EC Regulation No. 67/548 or No. 1999/45 Irritating (Xi) R43 Skin sensitization, hazard category 1 May cause an allergic skin reaction. May cause sensitization by skin contact. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07-1 Signal word: Warning Hazard designation: 2
H317 May cause an allergic skin reaction. Page 2 Safety designation: P260 P280 P303+P361+P353 P333+P313 Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ clothing/ eye/ face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical attention. 2. 3. 3. 3. 1. 3. 2. Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Tung Oil CAS-Nr: 8001-20-5 EINECS-Nr: 232-272-3 EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air. If required give artificial respiration. Keep patient warm. Consult physician if symptoms persist. Wash off with plenty of water and soap. Consult a physician if irritation persists. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth thoroughly with plenty of water and drink plenty of water. Consult a physician. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Treat symptomatically. 3
Page 3 5. 5. 1. Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: CO2, extinguishing powder, water jet. Fight larger fire with water jet or alcohol resistant foam. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet. 5. 3. Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon monoxide and dioxide, acrolein. Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Cool exposed containers with water spray. Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. 6. 2. Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Floor may be slippery; use care to avoid falling. Avoid contact with skin, eyes and clothing. Do not ingest or inhale. Ensure adequate ventilation. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent spillage of large quantities into drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent, inert material (sand, diatomaceous earth, acid absorbent) and dispose accordingly. Do not use flammable material, e.g. saw dust! Ensure adequate ventilation. Protective clothing, see Section 8. See Section 13 for information on disposal. Provide adequate ventilation. Do not inhale vapors or mist. Hygienic measures: 4
Avoid contact with eyes and skin. 7. 2. Conditions for Safe Storage, including any Incompatibilities Page 4 Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry and cool room. Store containers in a well ventilated location. Water law provisions have to be met. Finely distributed hot particles have the tendency to self-ignite. Do not store together with: oxidants. Storage class (VCI): 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs, beverages and feed. Avoid contact with eyes and skin. Do not inhale gas/fumes/vapor/aerosol. Avoid contact with eyes and skin. Respiratory equipment required in case of insufficient ventilation, filter type A. Protective gloves Protective glove material: 5
Page 5 Nitrile rubber (480 min, 0.4 mm) Please note the manufacturers detailed statements, especially about the minimum thickness and the minimum breakthrough time. Eye protection: Body protection: Tightly fitting safety goggles (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent from getting into the soil, surface water and sewage system. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: liquid yellow - brownish mild Flash point: > 260 C Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: not available no information available no information available 0.95 g/cm3 (20 C) not very miscible Coefficient of variation (n- Octanol/Water): 6
no information available Page 6 9. 2. 10. 10.1. 10.2. 10.3. 10.4. Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: not available Product is not explosive. No further information. No decomposition if used according to specifications. No decomposition if used according to specifications. Finely distributed hot particles have the tendency to self-ignite. No decomposition if used according to specifications. Thermal decomposition: 10.5. Imcompatible Materials Strong oxidizing agents. 10.6. Hazardous Decomposition Products Carbon monoxide and dioxide. Irritating fumes/vapors. Acrolein. 7
10.7. Further Information 11. Toxicological Information 11. 1. Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects 12. 12. 1. Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Prolonged and/or repeated skin contact can cause irritations. Slight but reversible irritation. No information available May cause sensitization. Algae toxicity: 8
12. 2. Persistency and Degradability 12. 3. Bioaccumulation 12. 4. Mobility 12. 5. Results of PBT- und vpvp Assessment Not applicable. 12. 6. Other Adverse Effects Page 8 Water hazard class: Not hazardous. Behaviour in sewage systems: Further ecological effects: No special effects or hazards known. 13. 13. 1. AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Must not be disposed together with household garbage. Do not let product enter water systems. The waste code is determined according to the code of the European Waste Catalog. Dispose of according to official local regulations. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. not applicable Tunnel no.: 9
IMDG Class (sea): Page 9 Hazard no.: EmS No.: IATA Class: 14. 4. Hazard no.: Packaging Group ADR/RID: not applicable IMDG: 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Not classified as a dangerous good under transport regulations. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: Employment restrictions: 0, not hazardous (self-assessment) Not listed. The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed. 15. 2. 15. 3. 16. Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.