SAFETY DATA SHEET Issue Date 23-Jun-2011 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product Identifier Product Name Other Means of Identification SDS # Safe n' Easy Limestone Cleaner DCI-035 Recommended Use of the Chemical and Restrictions on Use Recommended Use Heavy Duty Cleaner. Details of the Supplier of the Safety Data Sheet Supplier Address Dumond Chemicals, Inc. 83 General Warren Blvd Suite 190 Malvern, PA 19355 Emergency Telephone Number Company Phone Number 1-609-655-7700 Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) Classification 2. HAZARDS IDENTIFICATION Serious eye damage/eye irritation Category 2A Signal Word Warning Hazard Statements Causes serious eye irritation Appearance Clear to yellow liquid Physical State Liquid Odor Slight ammoniacal odor Precautionary Statements - Prevention Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Page 1 / 8
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Causes mild skin irritation Other Hazards Toxic to aquatic life with long lasting effects Toxic to aquatic life 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Tetrasodium EDTA 64-02-8 10-20 Ethoxylated Nonylphenol 9016-45-9 1-5 Trisodium Nitrilotriacetate 5064-31-3 <1 First Aid Measures 4. FIRST AID MEASURES Inhalation Eye Contact Ingestion Skin Contact Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get immediate medical advice/attention. If conscious give 1 glass of water to dilute. Do not induce vomiting without medical advice. Never give anything by mouth to a person who is unconscious or convulsing. Immediate medical attention is required. Wash thoroughly with soap and water until no traces of the chemical remain. Remove and wash contaminated clothing before reuse. Get medical attention if irritation occurs. Most Important Symptoms and Effects, both Acute and Delayed Symptoms May cause respiratory irritation. Inhalation of the dust may cause coughing and sneezing. Exposed individuals may experience eye tearing, redness and discomfort. May cause skin irritation with redness and swelling. Will cause gastrointestinal tract irritation. Indication of any Immediate Medical Attention and Special Treatment Needed Note to Physicians Treat symptomatically. Individuals with chronic respiratory or skin diseases may be at risk from exposure. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Page 2 / 8
Specific Hazards Arising from the Chemical None known. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Environmental Precautions Use personal protective equipment as required. Prevent entry into waterways, sewers, basements or confined areas. Methods and Material for Containment and Cleaning Up Methods for Containment Methods for Cleaning Up Dike spill and prevent spill from entering sewers and waterways. Collect using an inert absorbent material and place in appropriate containers for disposal. Wash spill area with plenty of water. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for Safe Handling Advice on Safe Handling Avoid contact with skin and eyes. Avoid breathing vapors or mists. Wash face, hands, and any exposed skin thoroughly after handling. Use personal protection recommended in Section 8. Follow all SDS/label precautions even after container is emptied because it may retain product residues. Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a cool, well-ventilated place. Store only in stainless steel, polyethylene, or plastic lined containers. Incompatible with oxidizing agents. Aluminum. Zinc. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Appropriate Engineering Controls Engineering Controls Good general room ventilation (equivalent to outdoors) should be adequate under normal conditions. If the recommended exposure limit is exceeded increased mechanical ventilation such as local exhaust may be required. For operations where contact can occur, a safety shower and an eye wash facility should be available. Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection Skin and Body Protection Chemical safety goggles/faceshield. Do not wear contact lenses. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Wear protective Neoprene gloves. Page 3 / 8
Respiratory Protection General Hygiene Considerations Ensure adequate ventilation, especially in confined areas. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Handle in accordance with good industrial hygiene and safety practice. Information on Basic Physical and Chemical Properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Clear to yellow liquid Odor Slight ammoniacal odor Color Clear to yellow Odor threshold Property Values ph 10 Melting point/freezing point -13.5 C / 7.7 F Boiling point/boiling range 106.6 C / 224 F Flash point Non-flammable Evaporation rate Same as water Flammability (solid, gas) Flammability limits in air Upper flammability limits Not applicable Lower flammability limit Not applicable Vapor pressure 760 mmhg Vapor density Not available Specific gravity ~1.18 Water solubility Miscible in water Solubility in other solvents Partition coefficient Not available Autoignition temperature Not applicable Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing Properties Remarks Method @ 107 C Other Information VOC Content (%) VOC Content 0% 0 lbs/gal 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization Hazardous polymerization does not occur. Conditions to Avoid Contact with aluminum and zinc may release flammable hydrogen gas. Page 4 / 8
Incompatible Materials Incompatible with oxidizing agents. Aluminum. Zinc. Hazardous Decomposition Products Thermal decomposition may yield carbon dioxide, carbon monoxide, and nitrogen oxides. Information on Likely Routes of Exposure Product Information 11. TOXICOLOGICAL INFORMATION Inhalation Eye Contact Skin Contact Ingestion Avoid breathing vapors or mists. Causes serious eye irritation. Causes mild skin irritation. May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water > 90 ml/kg ( Rat ) - - 7732-18-5 Tetrasodium EDTA = 10 g/kg ( Rat ) - - 64-02-8 Ethoxylated Nonylphenol = 1310 mg/kg ( Rat ) = 2 ml/kg ( Rabbit ) - 9016-45-9 Trisodium Nitrilotriacetate = 920 mg/kg ( Rat ) - > 5 mg/l ( Rat ) 4 h 5064-31-3 Information on Physical, Chemical and Toxicological Effects Symptoms May cause respiratory irritation with coughing and labored breathing. May cause irritation to the gastro-intestinal tract. May cause skin irritation with redness and swelling. May cause severe irritation with redness, pain, and blurred vision. Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. However, the product as a whole has not been tested. Exposure to nitrilotriacetic acid and its salts occurs during their production, formulation and use in synthetic laundry and dishwashing detergents and related products as metal chelating and sequestering agents. Chemical Name ACGIH IARC NTP OSHA Trisodium Nitrilotriacetate Group 2B X 5064-31-3 IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Numerical Measures of Toxicity- Product The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 2996 mg/kg ATEmix (dermal) 56000 mg/kg ATEmix (inhalation-vapor) 410 mg/l Page 5 / 8
12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Tetrasodium EDTA 1.01: 72 h Desmodesmus 41: 96 h Lepomis 64-02-8 subspicatus mg/l EC50 macrochirus mg/l LC50 static 59.8: 96 h Pimephales promelas mg/l LC50 static Trisodium Nitrilotriacetate 5064-31-3 560-1000: 96 h Chlorella vulgaris mg/l EC50 93-170: 96 h Pimephales promelas mg/l LC50 flow-through 175-225: 96 h Lepomis macrochirus mg/l LC50 static 252: 96 h Lepomis macrochirus mg/l LC50 470: 96 h Pimephales promelas mg/l LC50 static 560-1000: 96 h Oryzias latipes mg/l LC50 560-1000: 96 h Oryzias latipes mg/l LC50 semi-static 72-133: 96 h Oncorhynchus mykiss mg/l LC50 static 560-1000: 96 h Poecilia reticulata mg/l LC50 semi-static 560-1000: 96 h Poecilia reticulata mg/l LC50 114: 96 h Pimephales promelas mg/l LC50 Crustacea 610: 24 h Daphnia magna mg/l EC50 560-1000: 48 h Daphnia magna mg/l LC50 Persistence and Degradability. Bioaccumulation. Mobility. Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances Page 6 / 8
DOT IATA IMDG Not regulated Not regulated Not regulated 15. REGULATORY INFORMATION International Inventories TSCA DSL AICS Listed Listed Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances US Federal Regulations SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes No No No No US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Trisodium Nitrilotriacetate X 5064-31-3 U.S. EPA Label Information Page 7 / 8
16. OTHER INFORMATION NFPA HMIS Health Hazards 2 Health Hazards Flammability 0 Flammability Instability 0 Physical Hazards Special Hazards Personal Protection Issue Date Revision Date Revision Note 23-Jun-2011 12-Dec-2012 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8