SAFETY DATA SHEET. Anderol DDF 32

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Transcription:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product Use Description: Lubricant Company: Manufacturer Anderol Specialty Lubricants, a division of Chemtura Corporation 215 Merry Lane East Hanover, NJ 07936 United States of America Telephone: +1 203-573-4596, Toll Free: +1 888-263-3765 Email: Emergency telephone number: msdsrequest@chemtura.com CHEMTREC: (24 hours) 800-424-9300 : Chemtura Corporation Emergency Response: CHEMTURA : 800-292-5898 For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by Product Safety Department (US) +1 866-430-2775 MSDSRequest@chemtura.com Recommended use of the chemical and restrictions on use Recommended use : Lubricant SECTION 2. HAZARDS IDENTIFICATION Form Colour Odour liquid clear GHS Classification Aspiration hazard : Category 1 Acute aquatic toxicity : Category 3 Chronic aquatic toxicity : Category 3 GHS Label element Signal word : Danger SAP 6.0 SDS 2012-2 NA GHS 1 / 10 SDS Number: 400000002012

Hazard pictograms : Hazard statements Other hazards : H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. : None Precautionary statements : Prevention: P273 Avoid release to the environment. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P331 Do NOT induce vomiting. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Carcinogenicity: IARC OSHA NTP Group 3: Not classifiable as to its carcinogenicity to humans Distillates (petroleum), 64742-47-8 hydrotreated light 128-37-0 No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration (%) Distillates (petroleum), hydrotreated light naphthenic 64742-53-6 >= 50 - < 70 % Distillates (petroleum), hydrotreated light 64742-47-8 >= 10 - < 20 % Phenol, isobutylenated, phosphate (3:1) 68937-40-6 >= 0.1 - < 1 % 128-37-0 >= 0.1 - < 1 % SECTION 4. FIRST AID MEASURES If inhaled : If inhaled SAP 6.0 SDS 2012-2 NA GHS 2 / 10 SDS Number: 400000002012

Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of bluish discolouration (lips, ear lobes, fingernails), give oxygen as quickly as possible. Call a physician or poison control centre immediately. In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Notes to physician : In case of skin contact Wash off with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. Get medical attention if irritation develops and persists. : In case of eye contact Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist. : If swallowed, DO NOT induce vomiting. Call a physician or poison control centre immediately. : Aspiration may cause pulmonary oedema and pneumonitis. : For specialist advice physicians should contact the Poisons Information Service. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Carbon dioxide (CO2) Dry powder Foam Alcohol-resistant foam Water mist Unsuitable extinguishing media Specific hazards during firefighting : High volume water jet : Burning produces noxious and toxic fumes. Specific extinguishing methods Special protective equipment for firefighters : In the event of fire, cool tanks with water spray. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, : Use personal protective equipment. SAP 6.0 SDS 2012-2 NA GHS 3 / 10 SDS Number: 400000002012

protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Ensure adequate ventilation. : Should not be released into the environment. Do not contaminate water. Do not flush into surface water or sanitary sewer system. : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage Materials to avoid : Keep container closed when not in use. Do not use pressure to empty drums. Ensure all equipment is electrically grounded before beginning transfer operations. : Keep container tightly closed in a dry and well-ventilated place. : Strong acids and strong bases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Form of exposure Distillates (petroleum), hydrotreated light naphthenic Distillates (petroleum), hydrotreated light Permissible concentration Basis 64742-53-6 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA 5 mg/m3 ACGIH (Inhalable fraction) TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL TWA (Mist) 5 mg/m3 OSHA P0 64742-47-8 TWA 500 ppm OSHA Z-1 2,000 mg/m3 TWA 200 mg/m3 ACGIH TWA 400 ppm OSHA P0 1,600 mg/m3 128-37-0 TWA 10 mg/m3 OSHA P0 TWA 2 mg/m3 ACGIH (Inhalable fraction and vapor) TWA 2 mg/m3 ACGIH SAP 6.0 SDS 2012-2 NA GHS 4 / 10 SDS Number: 400000002012

(Inhalable fraction and vapor) TWA 10 mg/m3 NIOSH REL Engineering measures : Effective exhaust ventilation system Ensure that eyewash stations and safety showers are close to the workstation location. Personal protective equipment Respiratory protection : Breathing apparatus needed only when aerosol or mist is formed. In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : Neoprene gloves : Safety glasses with side-shields Tightly fitting safety goggles : impervious clothing : Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color Odor ph : clear pour point : 60 C Method: No information available. not determined Boiling point/boiling range Flash point : 114 C Method: Cleveland open cup Upper explosion limit Lower explosion limit Vapour pressure Relative density SAP 6.0 SDS 2012-2 NA GHS 5 / 10 SDS Number: 400000002012

Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Viscosity Viscosity, dynamic Viscosity, kinematic : 0.8795 g/cm3 : slightly soluble : 28.20-35.20 mpa.s (40 C) Method: ASTM D 445 SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : No dangerous reaction known under conditions of normal use. : Stable under normal conditions. : Hazardous polymerisation does not occur. : Contamination Heat, flames and sparks. : Strong acids and strong bases Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: > 2,930 mg/kg Species: Rat Method: OECD Test Guideline 401 Acute dermal toxicity : LD50: > 2,000 mg/kg Species: Rat Method: OECD Test Guideline 402 Skin irritation : Species: Rabbit Result: No skin irritation SAP 6.0 SDS 2012-2 NA GHS 6 / 10 SDS Number: 400000002012

Eye irritation : Species: Rabbit Result: No eye irritation Sensitisation : Species: Guinea pig Classification: Did not cause sensitisation on laboratory animals. Aspiration toxicity (Product) : May be fatal if swallowed and enters airways. CMR effects : Mutagenicity: Animal testing did not show any mutagenic effects. Teratogenicity: No effects on or via lactation Reproductive toxicity: No toxicity to reproduction Further information (Product) : There is no data available for this product. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish (Product) : Remarks: Toxicity to daphnia and other aquatic invertebrates (Product) Toxicity to algae (Product) : Remarks: : Remarks: Toxicity to fish (Chronic toxicity) Phenol, isobutylenated, : NOEC: 0.093 mg/l phosphate (3:1) Exposure time: 90 d Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) Phenol, isobutylenated, : NOEC: 0.0399 mg/l phosphate (3:1) Exposure time: 21 d Elimination information (persistence and degradability) SAP 6.0 SDS 2012-2 NA GHS 7 / 10 SDS Number: 400000002012

Bioaccumulation (Product) : Remarks: Mobility (Product) : Remarks: Biodegradability : aerobic Result: According to the results of tests of biodegradability this product is not readily biodegradable. 4.5 % Further information on ecology Ecotoxicology Assessment Results of PBT assessment (Product) This substance is not considered to be persistent, bioaccumulating and toxic (PBT). Additional ecological : There is no data available for this product. information (Product) SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : In accordance with local and national regulations. : Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION ADR RID MERCOSUR DOT IATA IMDG SAP 6.0 SDS 2012-2 NA GHS 8 / 10 SDS Number: 400000002012

SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ (lbs) (lbs) formaldehyde 50-00-0 100 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA304 Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 302: formaldehyde 50-00-0 0.000 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. formaldehyde 50-00-0 The components of this product are reported in the following inventories: US.TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL. AICS NZIoC ENCS KECI PICCS IECSC SECTION 16. OTHER INFORMATION Further information Other Emergency Phone Number SAP 6.0 SDS 2012-2 NA GHS 9 / 10 SDS Number: 400000002012

Latin America: Brazil +55 113 711 9144 All other countries +44 (0) 1235 239 670 Mexico: +52 555 004 8763 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP 6.0 SDS 2012-2 NA GHS 10 / 10 SDS Number: 400000002012