Material Safety Data Sheet 1. Company Identification and Product Information Product Name: Application Hydrogen Peroxide Synergised with Silver Supplier: Accepta Ltd Statham House Talbot Road Manchester M32 0FP Telephone 0161 877 2334 Fax 0870 135 6389 Email info@accepta.com Website www.accepta.com Emergency (only) Telephone: 0161 877 2334 2. Hazard Identification Main Hazards: Contact with combustible material may cause fire. Causes burns. Hazard Symbols: C: Corrosive Risk Phrases: R8 R34 The Full Text for all R-Phrases are Displayed in Section 15 3. Composition Information Chemical Name CAS- No EINECS Concentration [%] Hydrogen Peroxide 7722-84-1 231-765-0 >50% Phosphoric Acid 7664-38-2 231-633-2 <10% Silver Nitrate 7761-88-8 231-853-9 <5% 1
4. First Aid Measures Eyes: Skin: Ingestion: Inhalation: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible. Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible. 5. Fire Fighting Measures General Information: Extinguishing Media: Not combustible. Corrosive. In combustion emits toxic fumes. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Keep containers cool by spraying with water. This product will decompose on heating to form oxygen Use extinguishing media suitable for surrounding fire 6. Accidental Release Measures General Information: Environmental Precaution: Spill Clean up Procedures: Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not discharge into drains or rivers. Contain the spillage using bunding. DO NOT use organic material (eg sawdust) to absorb spillages Transfer to a suitable container. Wash spillage area with large amounts of water. 7. Handling and Storage Handling: Storage: Ensure there is sufficient ventilation of the area. Avoid direct contact with the substance. Smoking is forbidden. Store in cool, well ventilated area. Keep container tightly closed. 2
8. Exposure Controls Engineering Controls: Personal Protective Equipment Eyes: Hand: Clothing: Respirators: Ensure eyewash stations and emergency shower in the vicinity are operational. Ensure there is sufficient ventilation of the area. Safety goggles. Face-shield. Ensure eye bath is to hand. Protective gloves. Protective clothing with elasticated cuffs and closed neck. Boots made of PVC. PVC apron covering the tops of the boots. Ensure safety shower is to hand. Self-contained breathing apparatus must be available in case of emergency. 9. Physical and Chemical Properties Physical State: Colour: Oxidising: ph: Liquid Colourless Oxidising (by EC criteria) Acidic 10. Stability and Reactivity Chemical Stability: Conditions to Avoid: Materials to avoid: Hazardous Decomposition: Stable Heat Reducing agents. Organic materials. In combustion it may emits toxic fumes of NOx 11. Toxicological Information Acute effect: Potential Health Effect: Skin contact: Eye contact: Ingestion: Inhalation: Causes burns. Irritation or pain may occur at the site of contact. Blistering may occur. Severe burns may occur. There may be irritation and redness. The eyes may water profusely. Corneal burns may occur. There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Corrosive burns may appear around the lips. Nausea and stomach pain may occur. There may be vomiting. There may be a feeling of tightness in the chest with shortness of breath. Exposure may cause coughing or wheezing. There may be congestion of the lungs causing severe shortness of breath. 3
There may be loss of consciousness. 12. Ecological Information Persistence and degradability: Bioaccumulative potential: Other adverse effect: PBT Identification: Photodegradable. Low bioaccumulation potential. Harmful to fauna. This substance is not identified as a PBT substance. 13. Disposal Considerations The appropriate regulatory agencies should be contacted prior to disposal. 14. Transportation Information RID/ ADR IMDG IATA (Land Transport) (Sea Transport) (Air Transport) Shipping Name: OXIDISING LIQUID CORROSIVE, N.O.S. (Contains Hydrogen Peroxide) Hazard Class: 5.1 5.1 5.1 Subsidiary risk: 8 UN Number: 3098 3098 3098 Packing Group: II II II Labelling: 5.1+8 15. Regulatory Information European/International Regulations European Labelling in Accordance with EC Directives 4
Hazard Symbols: Risk Warnings: Risk Phrases: Safety Phrases: R8: Contact with combustible material may cause fire. R34: Causes burns. S17: Keep away from combustible material. S24/25: Avoid contact with skin and eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28: After contact with skin, wash immediately with plenty of soap and water. S36/37/39: Wear suitable protective clothing, gloves and eye / face protection. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 16. Other Information The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication, however no guarantee is made to its accuracy. The information given is prepared only as guidance for safe handling, use, processing, storage, transportation, disposal and release and should not be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material when used in combination with any other materials or in any process, unless specified in this Safety Data Sheet. Date 09 August 2011 Version 11.8 5