Revised 12.09.2012, replaces version 17.08.2012 PAGE: 1 (von 9) 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY PRODUCT NAME Armaflex 520 Adhesive USE OF THE PRODUCT MANUFACTURER /DISTRIBUTOR Special Adhesive for processing of all flexible Armaflex Insulating material (except HT/Armaflex) Armacell GmbH Robert-Bosch-Straße 10, D-48153 Münster Tel: +49 (0)251-7603 - 200 Fax: +49 (0)251-7603 - 561 www.armacell.com Technical contact point: Dr. Dirk Seiling Quality Manager Tel: +49 (0)251-7603 664 Fax: +49 (0)251-7631 - 664 dirk.seiling@armacell.com EMERGENCY INFORMATION Beratungsstelle für Vergiftungserscheinungen und Embryonaltoxikologie (Giftnotruf Berlin) Tel: +49 (0)3030686790 www.giftnotruf.de 2. HAZARDS IDENTIFICATION HAZARD DESIGNATION ADDITIONAL INFORMATION Highly flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to eyes and skin. Vapours may cause drowsiness and dizziness. At use formation of explosive / highly flammable vapour-air mixtures is possible. 3. COMPOSITION / INFORMATION ON INGREDIENTS DESCRIPTION Contact adhesive based on polychloroprene, free from aromatic solvents. HAZARDOUS INGREDIENTS HYDROCARBONES, C6-C7, ISOALKANES, CYCLICS, < 5% N-HEXANE REACH registration No. : 01-2119486291-36 EC No: 926-605-8 Weight fraction : 25-50 % Classification: F ; R11 N ; R51/53 Xn ; R65 R67 R66 Classification CLP: Flam. Liq. 2 ; H225 Asp.Tox. 1 ; H304 STOT SE 3 ; H336 Aquatic Chronic 2 ; H411
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 2 (von 9) ETHYL ACETATE REACH registration No. : 01-2119475103-46 EC No : 205-500-4 CAS No. : 141-78-6 Weight fraction : 20-25 % Classification: F ; R11 Xi ; R36 R67 R66 Classification CLP: Flam. Liq. 2 ; H225 Eye Irrit. 2 ; H319 STOT SE 3 ; H336 ACETONE REACH registration No. : 01-2119471330-49 EC No : 200-662-2 CAS No. : 67-64-1 Weight fraction : 5-20 % Classification: F ; R11 Xi ; R36 R67 R66 Classification CLP: Flam. Liq. 2 ; H225 Eye Irrit. 2 ; H319 STOT SE 3 ; H336 BUTANONE REACH registration No. : 01-2119457290-43 EC No : 201-159-0 CAS No. : 78-93-3 Weight fraction : 1-5 % Classification: F ; R11 Xi ; R36 R67 R66 Classification CLP: Flam. Liq. 2 ; H225 Eye Irrit. 2 ; H319 STOT SE 3 ; H336 PROPAN-2-OL REACH registration No. : 01-2119457558-25 EC No : 200-661-7 CAS No. : 67-63-0 Weight fraction : 1-5 % Classification: F ; R11 Xi ; R36 R67 Classification CLP: Flam. Liq. 2 ; H225 Eye Irrit. 2 ; H319 STOT SE 3 ; H336 ZINC OXIDE EC No : 215-222-5 CAS No. : 1314-13-2 Weight fraction : < 0,25 % Classification: N ; R50/53 Classification CLP : Aquatic Chronic 1 ; H410 4. FIRST-AID MEASURES IN CASE OF INHALATION Provide with fresh air. Consult a physician in case of symptoms.
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 3 (von 9) IN CASEOF SKIN CONTACT Wash off with soap and water and rinse. IN CASE OF EYE CONTACT Flush with plenty of water (10-15 min.). Remove contact lenses, keep eyelids open. Call a physician. IN CASE OF INGESTION Consult a physician immediately. 5. FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA EXTINGUISHING MEDIA WHICH MUST NOT BE USED FOR SAFETY REASONS Carbon dioxide, extinguishing powder or water spray jet. In case of larger fire use water spray jet or alcohol resistant foam. Full water jet. SPECIAL EXPOSURE HAZARDS ARISING FROM THE PREPARATION May form explosive vapour-air mix. 6. ACCIDENTAL RELEASE MEASURE PERSONAL PRECAUTIONS Keep away from ignition sources on account of the organic solvent content and air room well. Do not inhale vapours. ENVIRONMENTAL PRECAUTIONS Do not allow poduct to reach sewage system or waters. Prevent material from reaching sewage systems, holes or cellars. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with local regulations. METHODS FOR CLEANING UP / TAKING UP Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, saw dust). Dispose of the material collected according to regulations. Provide adequate ventilation. 7. HANDLING AND STORAGE HINTS FOR SAFE HANDLING Only use in locations with adequate exhaust ventilation. HINTS FOR PROTECTION AGAINST FIRE AND EXPLOSION Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. HINTS FOR SEPARATION OF IMCOMPATIBLE PRODUCTS Do not store together with food.
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 4 (von 9) FURTHER INFORMATION ON STORAGE CONDITIONS Keep container tightly closed in a cool, well-ventilated place. STORAGE CLASS VCI 3A 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ADDITIONAL INFORMATION ON ENIGINEERING MEASURES Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL (=Occupational Exposure Limit), suitable respiratory protection must be worn. CONSTITUENTS WITH OCCUPATIONAL EXPOSURE LIMITS REQUIRERING MONITORING (*) HYDROCARBONES, C6-C7, ISOALKANES, CYCLICS, < 5% N-HEXANE Limit value : 400 mg/m3 Version : ETHYL ACETATE ; CAS No. : 141-78-6 Limit value : 400 ppm / 1500 mg/m3 Peak limitation : 2(I) Remark : Y Version : 01.06.2008 ACETONE ; CAS No. : 67-64-1 Limit value : 500 ppm / 1200 mg/m3 Peak limitation : 2(I) Version : 15.01.2006 Limit value type (country of origin) : TWA ( EC ) Limit value : 500 ppm / 1210 mg/m3 Version :
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 5 (von 9) BUTANONE ; CAS No. : 78-93-3 Limit value : 200 ppm / 600 mg/m3 Peak limitation : 1(I) Remark : H, Y Version : 01.06.2008 Limit value type (country of origin) : STEL ( EC ) Limit value : 300 ppm / 900 mg/m3 Version : 08.06.2000 Limit value type (country of origin) : TWA ( EC ) Limit value : 200 ppm / 600 mg/m3 Version : 08.06.2000 PROPAN-2-OL ; CAS No. : 67-63-0 Limit value : 200 ppm / 500 mg/m3 Peak limitation : 2(II) Remark : Y Version : 01.04.2007 GENERAL HEALTH MEASURES The usual precautionary measures for the handling of chemicals have to be observed. Do not eat or drink during work - no smoking. Wash hands before breaks and after work. Immediately remove all contaminated clothing. Avoid contact with skin and eyes. RESPIRATORY PROTECTION Breathing protection equipment required in inadequately ventilated places and during spraying. For short term use: protection mask with filter combination filter type AX-P3 (for gases and vapours of organic compounds, boiling point below 65 C / particles, colour code: brown / white) HAND PROTECTION Disposable gloves are suitable as protection against splashes and should be removed immediately after moistening. EYE PROTECTION Use tightly fitting safety glasses. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE liquid COLOUR light tan ODOUR like solvent
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 6 (von 9) MELTING POINT not applicable BOILING POINT > 56 C FLASH POINT approx. - 20 C LOWER EXPLOSION LIMIT approx. 1 Vol-% UPPER EXPLOSION LIMIT approx. 13 Vol-% VAPOUR PRESSURE AT 50 C < 1100 hpa DENSITY AT 20 C approx. 0.9 g/cm 3 WATER SOLUBILITY AT 20 C slightly soluble 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID None if handled according to order. HAZARDOUS REACTION No dangerous reactions known. HAZARDOUS DECOMPOSITION PRODUCTS No dangerous decomposition products during appropriate storage and handling. 11. TOXICOLOGICAL INFORMATION EXPERIENCE MADE IN PRACTICE On the skin: irritant to skin and mucous membranes On the eye: irritant Sensitization: no sensitizing effect known 12. ECOLOGICAL INFORMATION ADDITIONAL ECOLOGICAL INFORMATION Do not allow to enter drains/surface water/ground-water. 13. DISPOSAL CONSIDERATIONS DISPOSAL PRODUCT Dispose waste according to applicable local, state and federal regulations.
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 7 (von 9) LIST OF PROPOSED WASTE CODES IN ACCORDANCE WITH EWC European Waste Catalogue: 08 04 09* (waste adhesives and sealants containing organic solvents or other dangerous substances) Please note: The classification of waste for this product may change according to the field of application. Please observe Decision 2001/118/EC. DISPOSAL PACKAGES Packaging must be emptied of all residues. Packaging with traces of cured product can be re-cycled. Packaging with uncured product must be disposed of in the same manner as the medium. 14. TRANSPORT INFORMATION LAND TRANSPORT (GGVSE/ADR) UN-NO. 1133 PROPER SHIPPING NAME Adhesives CLASS F1 PACKING GROUP II HAZARD LABEL SPECIAL MARKING 3 Symbol (Fish and Tree) ADR 5.2.1.8.3 NO. FOR HAZARD DESIGNATION 33 REMARK Special provision 640 D, LQ6, Tunnel restriction code: D1E MARINE TRANSPORT (IMDG) UN-NO. 1133 PROPER SHIPPING NAME Adhesives CLASS OR DIVISION 3 PACKING GROUP II HAZARD LABEL 3 EMS NO. F-E, S-D STOWING AND SEGREGATION Category B MARINE POLLUTANT The product is not to be classified as marine pollutant (IMDG 3.2) SUBSIDIARY RISK AIR TRANSPORT (ICAO-TI / IATA-DGR) UN OR ID-NO. 1133 PROPER SHIPPING NAME Adhesives CLASS OR DIVISION 3 PACKING GROUP II HAZARD LABEL 3
Revised 12.09.2012, replaces version 17.08.2012 PAGE: 8 (von 9) 15. REGULATORY INFORMATION LABELLING HAZARD(OUS) SYMBOL(S) AND INDICATION(S) OF DANGER F Xi N Highly flammable Irritant Dangerous for the environment R-PHRASES 11 Highly flammable 51/53 Toxic to aquatic organisms, may cause longterm adverse effects on the aquatic environment 36 Irritating to eyes 67 Vapours may cause drowsiness and dizziness 66 Repeated exposure may causes skin dryness or cracking S-PHRASES 16 Keep away from sources of ignition - no smoking 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 29 Do not empty into drains. 33 Take precautionary measures against static discharges 51 Use only in well-ventilated areas 61 Avoid release to the environment. Refer to special instructions/safety data sheets. NATIONAL REGULATIONS REGULATION OF INFLAMMABLE LIQUIDS (VBF) WATER POLLUTION CLASSIFICATION INTERNATIONAL REGULATIONS VbF Class A 1 Class: 2 according VwVwS According to test results of used raw materials R 51/53 is assigned. 16. OTHER INFORMATION RELEVANT R-PHRASES 11 Highly flammable 36 Irritating to eyes 38 Irritating to skin 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 51/53 Toxic to aquatic organisms, may cause longterm adverse effects on the aquatic environment 65 Harmful: may cause lung damage if swallowed 66 Repeated exposure may causes skin dryness or cracking 67 Vapours may cause drowsiness and dizziness
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