Date of issue: 19/03/2014 Revision date: 15/07/2016 Supersedes: 10/06/2014 Version: 9919.3 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Squash Court Coating - Epoxy Resin Product group : Squash 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category Use of the substance/mixture : Professional use : Part A component of paint for roller application to plastered squash court walls. 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Armourcoat Surface Finishes Morewood Close, London Road TN13 2HU Sevenoaks. Kent - United Kingdom T +44 (0) 1732 460668 technical@armourcoat.co.uk - armourcoat.com 1.4. Emergency telephone number Emergency number : +44 (0) 1732 467985 (0900-1730 UK time) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Sensitisation Skin, Category 1 Hazardous to the aquatic environment Chronic Hazard, Category 2 H315 H319 H317 H411 Full text of H statements : see section 16 Calculation method Expert judgment Calculation method Expert judgment Adverse physicochemical, human health and environmental effects Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects. 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Warning 15/07/2016 EN (English) 1/8 GHS09 : Bisphenol A-(Epichlorhydrin) Reaction Product; Oxirane, mono[(c12-14alkyloxy)methyl]derivatives; Bisphenol F Epichlorohydrin Resin with number average : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H411 - Toxic to aquatic life with long lasting effects : P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower P391 - Collect spillage P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Bisphenol A-(Epichlorhydrin) Reaction Product (CAS No) 25068-38-6 (EC no) 500-033-5 (EC index no) 603-074-00-8 Oxirane, mono[(c12-14alkyloxy)methyl]derivatives (CAS No) 68609-97-2 (EC no) 271-846-8 (EC index no) 603-103-00-4 50-80 Eye Irrit. 2, H319 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 2, H411 10-25 Skin Irrit. 2, H315 Skin Sens. 1, H317 Bisphenol F Epichlorohydrin Resin with number average (CAS No) 28064-14-4 10-25 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Specific concentration limits: Name Product identifier Specific concentration limits Bisphenol A-(Epichlorhydrin) Reaction Product (CAS No) 25068-38-6 (EC no) 500-033-5 (EC index no) 603-074-00-8 Full text of H-statements: see section 16 (C >= 5) Eye Irrit. 2, H319 (C >= 5) Skin Irrit. 2, H315 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Irritation (itching, redness, blistering). Irritation. May cause an allergic skin reaction. Symptoms/injuries after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 15/07/2016 EN (English) 2/8
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing mist. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing mist. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Viscous. Colour : Yellow. Odour : Characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Not applicable Freezing point Boiling point : > 100 C Flash point : > 100 C Auto-ignition temperature 15/07/2016 EN (English) 3/8
Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 1.12 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity : Not applicable The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Squash Court Coating - Epoxy Resin LD50 oral LD50 dermal > 2000 mg/kg > 2000 mg/kg Oxirane, mono[(c12-14alkyloxy)methyl]derivatives (68609-97-2) LD50 oral rat 17100 mg/kg Bisphenol A-(Epichlorhydrin) Reaction Product (25068-38-6) LD50 oral rat 11400 mg/kg LD50 dermal rabbit > 20 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Toxic to aquatic life with long lasting effects. 15/07/2016 EN (English) 4/8
12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment Squash Court Coating - Epoxy Resin This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) : 3082 UN-No. (IMDG) : 3082 UN-No. (IATA) : 3082 UN-No. (RID) : 3082 : Dispose of contents/container in accordance with licensed collector s sorting instructions. 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : Environmentally hazardous substance, liquid, n.o.s. : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, (E) : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS : UN 3082 Environmentally hazardous substance, liquid, n.o.s., 9, III, ENVIRONMENTALLY HAZARDOUS : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, ENVIRONMENTALLY HAZARDOUS 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 9 Danger labels (ADR) : 9 : IMDG Transport hazard class(es) (IMDG) : 9 Danger labels (IMDG) : 9 : IATA 15/07/2016 EN (English) 5/8
Transport hazard class(es) (IATA) : 9 Hazard labels (IATA) : 9 : RID Transport hazard class(es) (RID) : 9 Danger labels (RID) : 9 : 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : III : III : III : III : Yes : Yes : No supplementary information available 14.6. Special precautions for user - Overland transport Classification code (ADR) : M6 Special provisions (ADR) : 274, 335, 601, 375 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5l : E1 : P001, IBC03, LP01, R001 : PP1 : MP19 : T4 : TP1, TP29 : LGBV : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) : V12 : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) EAC code : E : 3Z - Transport by sea Special provisions (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L 15/07/2016 EN (English) 6/8
Excepted quantities (IMDG) Packing instructions (IMDG) Special packing provisions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) : E1 : P001, LP01 : PP1 : IBC03 : T4 : TP2, TP29 : F-A : S-F : A - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : E1 : Y964 : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Rail transport Classification code (RID) : 450L : A97, A158, A197 : 9L : M6 Special provisions (RID) : 274, 335, 375, 601 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5L : E1 : P001, IBC03, LP01, R001 : PP1 : MP19 : T4 Transport category (RID) : 3 Special provisions for carriage Packages (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) : TP1, TP29 : LGBV : W12 : CW13, CW31 : CE8 Hazard identification number (RID) : 90 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: 15/07/2016 EN (English) 7/8
Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, Category 1 H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 15/07/2016 EN (English) 8/8