ICN Biochemicals S. Chillicothe Road Aurora, OH Quality Control Fax # MSDS. Material Safety Data Sheet

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ICN Biochemicals Page 1 of 5 ICN Biochemicals 1263 S. Chillicothe Road Aurora, OH 44202 216 562 1500 Quality Control Fax # 216 562 2642 MSDS Material Safety Data Sheet General Properties Product: N,N,N',N'-Tetramethyl-p-Phenylene Diamine Dihydrochloride Synonym: N,N,N',N'-Tetramethyl-14-Benzenediamine Dihydrochloride Catalog Number: 195517, 218979 Chemical Formula: C 10 H 16 N 2.2HCl Physical Description: White powder Melting Point: 234 o C Boiling Point: Not available Specific Gravity: Not available Vapor Pressure: Not available Solubility in Water: Slightly soluble TLV of the Substance: Not established Storage: Room Temperature Remarks Toxic Solid, organic, n.o.s. (III) scu-mus LDLo: 20 mg/kg CAS # 637-0-4 RTECS # Not available

ICN Biochemicals Page 2 of 5 UN # 2811 (III) WHMIS D2A Dangerous Reactions Flammability: None Flash Point (method): Not available Minimum Ignition Temperature: Not established Risk of explosion? No Decomposition of the substance when heated or burned: YES, Toxic Fumes of NO x and HCl Any Dangerous Reactions? Yes, With Strong oxidizing agents and strong bases. Extinguishing Media: CO 2, dry chemical, or foam Toxicological Data Route(s) of Entry: Inhalation: Yes Skin: Yes Ingestion: Yes Health Hazards Acute and Chronic: Poisonous by subcutaneous route. A skin, eye and mucous membrane irritant. Signs and Symptoms of Exposure: Irritation. Safe Handling and Safe Use of Materials

ICN Biochemicals Page 3 of 5 Spill or Release of Material [ ] Absorb the liquid in dry sand, diatomite, vermiculite or other drying agent then shovel into suitable containers for disposal. [ ] Acid Spills Depending upon the situation neutralize with soda ash then use one of the following methods; soak up in an absorbent then shovel into suitable container for disposal, or flush away with a liberal amount of water. [ ] Alkaline Spills Depending upon the situation neutralize with NaHSO 4 and then use one of the following methods; soak up in an absorbent then shovel into suitable container for disposal, or flush away with a liberal amount of water. [X] Other procedures: Sweep into suitable container for disposal. Waste Disposal Method: Incinerate or landfill as complies with state and local laws. Handling Always wear gloves, mask, goggles or other protective clothing and use a hood. Follow proper laboratory procedures. Personal Protection

ICN Biochemicals Page 4 of 5 Respiratory Protection: YES Eye Protection: YES Protective Gloves: YES Is a local exhaust system required when the substance is used for its normal purpose? YES First Aid Procedures Substance in Contact with Skin [X] Remove contaminated clothing and rinse with copious amounts of soap and water for a considerable amount of time [ ] Produces severe caustic burns or general disorders, call a physician [X] Call a physician Substance has been Swallowed [X] Rinse mouth several times with water, do not swallow [ ] Drink 1 or 2 glasses of water within 15 minutes [ ] Induce vomiting [ ] In the case of imminent unconsciousness clear the respiratory tract and lay patient on side in a stable position [X] Always Call a physician or take patient to hospital Substance in Contact with Eyes [X] Rinse liberally with water for a considerable amount of time [X] Always call a physician or take to a hospital

ICN Biochemicals Page 5 of 5 Substance has been Inhaled [X] Take patient into the fresh air and allow to rest [ ] In the case of imminent unconsciousness clear the respiratory tract and lay patient on side in a stable position [X] Always Call a physician or take patient to hospital Additional Instructions: Observe proper laboratory procedures when handling material. Date of Preparation: 11-1-95 The information provided with this MSDS is furnished in good faith and without warranty of any kind. Personnel handling this material must consider these data only as supplemental to other information gathered by them and must make independent determinations of this suitability and completeness of information from all sources to assure proper use and disposal of the materials and the safety and health of employees and customers. ICN assumes no additional liability or responsibility resulting from the use of, or reliance on this information. CHEMTREC 1 800 424 9300 NATIONAL RESPONSE CENTER 1 800 424 8802