According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 08/03/2017 Date of Issue: 08/03/2017 Version: 1.0 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: 1.2. Intended Use of the Product Use of the Substance/Mixture: Laundry Detergent 1.3. Name, Address, and Telephone of the Responsible Party Company Church & Dwight 500 Charles Ewing Blvd Ewing Township, NJ 08628 T 1-800-236-4175 www.churchdwight.com 1.4. Emergency Telephone Number Emergency Number : For Medical Emergency: 1-888-234-1828 (USA and Canada), 952-853-1925 (Outside USA and Canada); For Chemical Emergency (CHEMTREC): 1-800-424-9300 (USA and Canada), 1-703-741-5970 (Outside USA and Canada) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture GHS-US Classification Eye Irrit. 2 H319 Aquatic Acute 2 H401 Full text of hazard classes and H-statements : see section 16 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : Signal Word (GHS-US) Hazard Statements (GHS-US) Precautionary Statements (GHS-US) GHS07 : Warning : H319 - Causes serious eye irritation. H401 - Toxic to aquatic life. : P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, and eye protection. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations. 2.3. Other Hazards Exposure may aggravate pre-existing eye, skin, or respiratory conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Not applicable 3.2. Mixture Name Product Identifier % GHS-US classification Disodium carbonate (CAS No) 497-19-8 60-100 Eye Irrit. 2A, H319 08/03/2017 EN (English US) 1/5
Alcohols, C10-16, ethoxylated (CAS No) 68002-97-1 5-10 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Acute 1, H400 Full text of H-phrases: see section 16 The specific chemical identity and/or exact percentage of composition have been withheld as a trade secret [29 CFR 1910.1200]. SECTION 4: FIRST AID MEASURES 4.1. Description of First-aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists. First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain medical attention. 4.2. Most Important Symptoms and Effects Both Acute and Delayed Symptoms/Injuries: Causes serious eye irritation. Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation. Symptoms/Injuries After Skin Contact: Prolonged contact with large amounts of dust may cause mechanical irritation. Symptoms/Injuries After Eye Contact: Redness, pain, swelling, itching, burning, tearing, and blurred vision. Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. Chronic Symptoms: None expected under normal conditions of use. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Product is not flammable. Explosion Hazard: Product is not explosive. Reactivity: Hazardous reactions will not occur under normal conditions. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Carbon oxides (CO, CO2). Sodium oxides. Sulfur oxides. : Do not allow run-off from fire fighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing. 6.1.1. For Non-Emergency Personnel Protective Equipment: Use appropriate personal protective equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Avoid release to the environment. 6.3. Methods and Materials for Containment and Cleaning Up For Containment: Contain solid spills with appropriate barriers and prevent migration and entry into sewers or streams. 08/03/2017 EN (English US) 2/5
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Recover the product by vacuuming, shoveling or sweeping. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. 6.4. Reference to Other Sections See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Avoid breathing dust. Do not get in eyes, on skin, or on clothing. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Keep container closed when not in use. Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Finely powdered aluminum and magnesium. Phosphorus pentachloride. 7.3. Specific End Use(s) Laundry Detergent SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).8.2. Exposure Controls Appropriate Engineering Controls Personal Protective Equipment : For occupational/workplace settings: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. : For occupational/workplace settings and bulk quantities: Gloves. Protective clothing. Protective goggles. Materials for Protective Clothing Hand Protection Eye and Face Protection Skin and Body Protection Respiratory Protection SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State Appearance Odor Odor Threshold ph Evaporation Rate Melting Point Freezing Point Boiling Point Flash Point Auto-ignition Temperature Decomposition Temperature Flammability (solid, gas) : For occupational/workplace settings: Chemically resistant materials and fabrics. : For occupational/workplace settings: Wear protective gloves. : For occupational/workplace settings: Chemical safety goggles. : For occupational/workplace settings: Wear suitable protective clothing. : If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection. : When using, do not eat, drink or smoke. : Solid 08/03/2017 EN (English US) 3/5
Vapor Pressure Relative Vapor Density at 20 C Relative Density Solubility Partition Coefficient: N-Octanol/Water Viscosity 9.2. No additional information available SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions will not occur under normal conditions. 10.2. Chemical Stability: Stable under recommended handling and storage conditions (see section 7). 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, and incompatible materials. 10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Finely powdered aluminum and magnesium. Phosphorus pentachloride. 10.6. Hazardous Decomposition Products: None expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified Alcohols, C10-16, ethoxylated (68002-97-1) ATE (Oral) 500.00 mg/kg body weight LD50 Oral Rat 4090 mg/kg LC50 Inhalation Rat 2300 mg/m³ (Exposure time: 2 h) Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: Prolonged exposure may cause irritation. Symptoms/Injuries After Skin Contact: Prolonged contact with large amounts of dust may cause mechanical irritation. Symptoms/Injuries After Eye Contact: Redness, pain, swelling, itching, burning, tearing, and blurred vision. Symptoms/Injuries After Ingestion: Ingestion may cause adverse effects. Chronic Symptoms: None expected under normal conditions of use. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - General LC50 Fish 1 EC50 Daphnia 1 LC50 Fish 2 12.2. Persistence and Degradability Persistence and Degradability 12.3. Bioaccumulative Potential Bioaccumulative Potential : Toxic to aquatic life. 300 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) 265 mg/l (Exposure time: 48 h - Species: Daphnia magna) 310-1220 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Not established. Not established. BCF Fish 1 (no bioaccumulation) 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects : Avoid release to the environment. 08/03/2017 EN (English US) 4/5
SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste Treatment Methods Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations. Additional Information: Container may remain hazardous when empty. Continue to observe all precautions. Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways. SECTION 14: TRANSPORT INFORMATION The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued. 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1. US Federal Regulations SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Alcohols, C10-16, ethoxylated (68002-97-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)). Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State Regulations No additional information available SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Date of Preparation or Latest Revision : 08/03/2017 : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200 GHS Full Text Phrases: ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1 ------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2 Serious eye damage/eye irritation Category 2 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H400 Very toxic to aquatic life ------ H401 Toxic to aquatic life This Product is offered solely for your information, consideration and investigation. Church & Dwight Co., Inc. provides no warranties; either expressed or implied, and assumes no responsibility for the accuracy or completeness of data contained herein. Church & Dwight Co., Inc. urges persons receiving this information to make their own determination as to the information suitability for their particular application. SDS US (GHS HazCom) 08/03/2017 EN (English US) 5/5