Material Safety Data Sheet Revision Number: 003.0 Issue date: 01/18/2011 1. PRODUCT AND COMPANY IDENTIFICATION Product type: Tough acrylic Item number: 17099 Region: United States Company address: Contact information: Henkel Corporation Telephone: 860.571.5100 One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Paste HEALTH: *2 Color: White FLAMMABILITY: 1 Odor: Mild PHYSICAL HAZARD: 1 Personal Protection: See MSDS Section 8 WARNING: CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. May cause central nervous system depression. Moderate skin irritation. May cause allergic skin reaction. May be harmful if absorbed through skin. Contact with eyes will cause irritation. May be harmful if swallowed. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. Page 1 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Aluminium hydroxide 21645-51-2 60-100 Tetrahydrofurfuryl methacrylate 2455-24-5 10-30 Unknown, Non Hazardous~ Unknown 5-10 Hydroxyalkyl methacrylate 27813-02-1 5-10 Cumene hydroperoxide 80-15-9 1-5 Saccharin 81-07-2 1-5 Ethylene glycol 107-21-1 0.1-1 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. If skin irritation persists, call a physician. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get immediate medical attention. Ingestion: Keep individual calm. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get immediate medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: > 93.3 C (> 199.94 F) Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool with water spray. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Uncontrolled polymerization may cause rapid evolution of heat and increase in pressure that could result in violent rupture of sealed storage vessels or containers. Oxides of carbon. Oxides of nitrogen. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up. Page 2 of 6
7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. Refer to Section 8. For safe storage, store at or below 38 C (100.4 F) Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Aluminium hydroxide 10 mg/m3 TWA (as Al) Total dust. 1 mg/m3 TWA Respirable fraction. 15 mg/m3 TWA (as Al) Total dust. 5 mg/m3 TWA (as Al) Respirable fraction. Tetrahydrofurfuryl methacrylate None None None None Unknown, Non Hazardous~ None None None None Hydroxyalkyl methacrylate None None None Cumene hydroperoxide None None None 1 ppm (6 mg/m3) TWA (SKIN) None 1 ppm TWA 3 ppm STEL Saccharin None None None None Ethylene glycol 100 mg/m3 Ceiling Aerosol. None None None None Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Safety showers and eye wash stations should be available. Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: White Odor: Mild Odor threshold: ph: Not applicable Vapor pressure: < 5 mm hg (27 C (80.6 F)) Boiling point/range: > 149 C (> 300.2 F) Melting point/ range: Specific gravity: 1.0 Vapor density: Flash point: > 93.3 C (> 199.94 F) Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Slight Partition coefficient (n-octanol/water): Page 3 of 6
VOC content: 26.6 %; 266 g/l EPA Method 24 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials. Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organic vapours. Strong oxidizing agents. Free radical initiators. Reducing agents. Strong acids. Oxygen scavengers. Other polymerization initiators. Heavy metals. Amines. Peroxides. Alkalis. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Do not freeze. Protect from direct sunlight. UV light. Inert gas blanketing. Avoid moisture. 11. TOXICOLOGICAL INFORMATION Acute oral product toxicity: Acute dermal product toxicity: LD50 (rat) > 5,000 mg/kg (Estimated) LD50 (rabbit) > 2,000 mg/kg (Estimated) Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Aluminium hydroxide No No No Tetrahydrofurfuryl methacrylate No No No Unknown, Non Hazardous~ No No No Hydroxyalkyl methacrylate No No No Cumene hydroperoxide No No No Saccharin No No No Ethylene glycol No No No Hazardous components Aluminium hydroxide Tetrahydrofurfuryl methacrylate Unknown, Non Hazardous~ Hydroxyalkyl methacrylate Cumene hydroperoxide Saccharin Ethylene glycol Health Effects/Target Organs Irritant, Lung, Respiratory Irritant, Allergen No Data Irritant, Allergen Allergen, Central nervous system, Corrosive, Irritant, Mutagen No Target Organs Blood, Bone Marrow, Central nervous system, Developmental, Eyes, Irritant, Kidney, Liver, Metabolic 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Environmentally hazardous substances, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Reportable quantity: alpha,alpha-dimethylbenzylhydroperoxide, Saccharin International Air Transportation (ICAO/IATA) Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimus None above reporting de minimus Immediate Health, Delayed Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2). Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg) Saccharin (CAS# 81-07-2) 100 lbs. (45.4 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 1,2,3,4,5,10,11,14,15 Prepared by: Katherine Caddy, Regulatory Affairs Specialist Page 5 of 6
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6