- PROA SECTION 1. PREPARATION INFORMATION Date: 6/28/08 Manufactured by: 8 Bronte Drive Taft, TN 38488 SECTION 2. PRODUCT INFORMATION Trade Name: ArtiKool PROA Emergency Phone: 931-433-0908 Transportation NFPA Code: Health: 1 Fire: 1 Reactivity: 0 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS -This material is not known to contain greater than 0.1% of any carcinogen required to be listed under the OSHA Hazard Communication Standard (29CFR 1910.1200). -Severely Hydrotreated Heavy Naphthenic petroleum oil: CAS NO. 64742-52-5; OSHA PEL: TWA: 5 mg/m³ (oil mist), STEL: none estab. ACGIH TLV: TWA: 5mb/m³ (oil mist). -Fatty Acid Dimers and Trimers Mixture, CAS NO 61788-89-4 Exposure Limits: None Established -N,N-bis(2Hydroxethyl) Tallowamine. CAS NO 68155-39-5 Exposure Limits: None Established. -Additive Package (E.P., Anti-Wear, Rust & Corrosion), Proprietary Blend. SECTION 4. HAZARD IDENTIFICATION EMERGENCY OVERVIEW Dark brown liquid with fatty odor. Avoid contact with eyes, skin and vapor or mist inhalation. Avoid contact with strong oxidizers, mineral acids, nitrites, nitrosating agents, trimethylol propane derived products, clay rockwool, insulation, rags and paper. Protect against decomposition product of phosphoric acid, oxides of carbon, nitrogen compounds, and sulfur compounds. SECTION 5. FIRE AND EXPLOSION DATA Flash Point: >350 F (ASTM D-93) Autoignition Temperature: >450 F Upper Flammable Limit: Lower Flammable Limit: Extinguishing Media: CO2, Dry chemical, foam, water spray, water fog. Special Firefighting Procedures: Self-contained full face breathing apparatus. Unusual Fire & Explosion Hazards: Toxic fumes may evolve on burning. Explosion Data: Not sensitive to mechanical impact or static discharge.
6/28/08 P.2 SECTION 6. HEALTH HAZARD DATA Oral Toxicity: Greater than 10,000mg/kg in rats. Based on component data or similar material. Eye Irritation: Severely irritating, cause eye irritation. Based on component data or similar material. Skin Irritation: Prolonged contact can result in sever irritation or chemical burn. Based on component data or similar material. Inhalation Toxicity: Aspiration may cause pneumonitis. Respiratory Irritation: If material is misted or if vapors are generated from heating, exposure may cause irritation of mucous membranes and the upper respiratory tract similar to that observed with mineral oil. Based on data from components or similar materials. Under good industrial hygiene practices where all exposure limits are observed, respiratory irritation should not be a problem. --CHRONIC EXPOSURE Chronic Toxicity: No data available to indicate product or components present at greater than 1% are chronic health hazards. Carcinogenicity: Not listed as human carcinogen by OSHA, IARC, or NTP. Material contains one or more amines which may react with nitrates or other nitrosating agents to form nitrosamines. Some nitrosamines have been shown to carcinogenic in laboratory animals. Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Reproductive Toxicity: No data available to indicate either product or components present at greater than 0.1% that may cause reproductive toxicity. Teratogenicity: No data available to indicate product or any components contained at greater than 0.1% may cause birth defects. Subchronic Effects: Repeated or prolonged exposure may cause kidney and liver damage. --Additional Information Other: Exposure Limits: No other health hazards known. Contains mineral oil. Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter, ACGIH STEL of 10 mg per cubic meter.
SECTION 7. Skin: Eye: Inhale: Oral: Additional: 6/28/08 P.3 EMERGENCY FIRST AID PROCEDURES Wash with soap and water. Get medical attention if irritation develops. Launder contaminated clothing before reuse. Flush with water 15 minutes. See Physician if eye irritation develops or persists. Remove to fresh air. See physician if irritation persists. Do not induce vomiting. Get immediate medical attention. Note to physician Treat symptomatically. SECTION 8. SPECIAL PROTECTION INFORMATION Ventilation Procedure: Use local exhaust ventilation to control mists or vapors. Additional ventilation or exhaust may be required to maintain air concentrations below recommended exposure limits. Gloves Protection: Neoprene or Nitrile rubber gloves recommended. Eye Protection: Under normal use conditions, respirator is not usually required. Use NIOSH/MSHA approved full face respirator with an organic vapor cartridge if the recommended exposure limit is exceeded. Use self-contain breathing apparatus for entry into confined space and for other poorly ventilated areas and for large spill clean-up sites. Clothing Recommendation: Long sleeve shirt is recommended. Wear a chemically protective apron when contact with material may occur. Do not wear rings, watches or similar apparel that could entrap the material and cause a skin reaction. Launder contaminated clothing before reuse. SECTION 9. PHYSICAL DATA Vapor Pressure: Not Determined. Specific Gravity: 0.9273 Water Solubility: Insoluble. Percent Volatile: Unknown. Vapor Density: Not determined Evaporation rate: Not determined Odor: Mild Odor Threshold: Unknown Appearance: Dark Brown liquid
6/28/08 P.4 SECTION 10. REACTIVITY DATA Stability: Stable under normal ambient and anticipated storage and handling conditions. Conditions to Avoid: Avoid heating to decomposition; avoid contact with nitrites, nitrosating agents, clay, rockwool, insulation, rags and paper. Incompatibility: Strong oxidizing agents and strong mineral acids. Polymerization: Will not occur Thermal Decomposition: Smoke, carbon monoxide, carbon dioxide, and other products of incomplete combustion. Under combustion conditions, oxides of the following elements will be formed: Phoshoric Acid, Oxides of Carbon, Nitrogen compounds, Sulfur compounds. SECTION 11. Spill Procedures: Water Disposal: SECTION 12. SPILL OR LEAK PROCEDURES Ventilate area. Shut-off any source of fire, heat or sparks. Wear chemical splash goggles. Wear rubber boots. Safely stop flow of spill. Evacuate non-essential personnel from immediate area due to slipping hazard, and/or possible fire if a source of ignition is near by. Prevent entry into sewers, waterways. Pick up free liquid with sand or other inert noncombustible absorbent materials and place in appropriate containers for later recycle or disposal. For larger spills, verify that responders are properly HAZWOPER-trained and wear appropriate protective clothing/equipment, including organic respirators or supplied air. Dike far ahead of a spill to ensure complete collection. Pick-up free liquid for recycle and/or disposal if it can be accomplished safely with explosionproof equipment. This product will float on water. Absorbent pads and similar material can be used. The spilled material and any soil or water it has contacted may be hazardous to animal and/or aquatic life. If disposed of this material, conditions of use may cause this material to become a hazardous waste, as defined by state or federal laws. Use approved treatment, transporters, and disposal sites in compliance with all applicable regulations. SPECIAL PRECAUTIONS Special Precautions: Store in well ventilated area away from sparks, flame, and heat. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Remove contaminated clothing and launder before reuse. Discard contaminated shoes. Do not take internally.
6/28/08 P.5 SECTION 13. TRANSPORTATION AND LABELING DOT Proper Shipping Name: DOT Hazard Class: DOT Label: DOT ID NUMBER (UN NO.): IMO CLASS: SECTION 14. OTHER REGULATORY INFORMATION_ U.S. TSCA Inventory: All components are included in the U.S. TSCA inventory. CERCLA Hazardous Substances: None Known SARA EXT. HAZ. SUBST.: This product is not known to contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substances List. SARA Section 313 Status: This product is not known to contain greater than 1.0% (greater than 0.1% for carcinogenic substance) of any chemical substances listed under SARA Section 313. International Regulations: Canadian WHMIS: Unknown Canadian Environmental Protection Act (CEPA): Unknown EINECS: Unknown State Regulations: Massachusetts: Ethanol, 2,2 2 - Nitrilotris 102-71-6 Right-to-Know MSL reporting requirement (=>1%) Additional information available upon request. Revised: 6-28-08 Replaces: 9-23-02 The information presented herein has been compiled from sources considered to be dependable and is accurate to the best of Energy Design Services, LLC s knowledge. makes no warrant whatsoever, expressed or implied, or of Merchantability of fitness for the particular purpose. The information relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Customers are encourages to conduct their own tests before using the product and to read its label for specific instructions. assumes no responsibility for injury to buyer, or to third persons, or for any damage to any property, and recipient assumes all such risks.