SAFETY DATA SHEET (SDS) for: Incandescent Bulbs

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Transcription:

SAFETY DATA SHEET (SDS) for: Incandescent Bulbs Section 1. Identification 1.1. Company: Damar Worldwide 4 LLC Telephone: (800) 238-9080 805 N Carnation Dr Aurora, MO 65605 1.2. Product: Incandescent Bulbs Section 2. Hazards Identification NOTE Grinding, sanding and/or mechanical manipulation of this product may change and alter the hazards and information listed in all of the following sections in ways that can not be predicted. 2.1. Hazard Classification: Inert, Article 2.2. OSHA Regulatory Status: This product, when intact, is not known to be hazardous as defined by OSHA s Hazard Communication Standard, 29 CFR 1910.1200. This product is exempt from OSHA s Hazard Communication Standard requirements for an MSDS because it meets the definition of an article. An article is a manufactured item: (1) which is formed to a specific shape or design during manufacture (2) which has end use function(s) dependent in whole or in part upon its shape or design during end use: and (3) which does not release, or otherwise result in exposure to, a hazardous chemical under normal conditions of use. Any product which meets the definition of an article is exempt from the requirements of the Standard. 2.3. Hazardous Ingredients Ingredient CAS Number OSHA PEL mg/m 3 ACGIH TLV % By Weight Inert Materials (metals, glass, ceramics) >99% Lead (7439-92-1) 0.015 0.05 <0.01 2.4. GHS Classification: 2.4.1. Acute toxicity oral: unknown; unlikely 2.4.2. Acute toxicity dermal: unknown; unlikely Rev Date: 10/22/15 Page 1 of 7

2.4.3. Aspiration hazard: unknown; unlikely 2.5. Signal Word: Not Applicable 2.6. Hazard Statement: This article is essentially inert under most conditions likely to be present in a fire or other emergency situation. 2.7. Pictograms: Not Applicable including those most 2.8. Precautionary Statement: Call a POISON CENTER if you feel unwell. This product is an electrical device that when used in or along with appropriate equipment designed for those products and constructed for use with such products, has no special health or safety concerns. Additional information regarding applications or technical specifications for this product may be available at http://www.damarww.com. 2.9. Description of any hazards not otherwise classified: 2.9.1. Primary routes of particulate entry: Ingestion, Eye/Skin Contact. 2.9.2. Skin Exposure: 2.9.2.1. Minor laceration and/or abrasion may occur if product is broken, sharp objects pierce coating and then come into contact with skin. Alteration/damage to the product can result in exposure to additional unforeseen and unpredictable hazards including but not limited to electrical hazards.. 2.9.2.2. Refer to Sections 7 and 8 for additional information regarding Handling and Personal Protective Equipment (PPE). 2.9.3. Eye Exposure: Injury may occur if eyes are subjected to prolonged direct exposure to bright light. 2.9.4. Respiratory Exposure: Inhalable dust and particulates may be generated if product is pulverized. As with any particulate matter, respirable particles may cause mechanical irritation of the respiratory system and/or lung injury. 2.10. NFPA Rating: Health 1 Fire 1 Instability/Reactivity 0 Section 3. Section 4. Composition/Information on Ingredients 3.1. Exempt article ingredients not measured First Aid Measures 4.1. Eyes: Not Applicable 4.2. Skin: 4.2.1. Wash with soap and water. 4.2.2. Treat lacerations using standard first aid procedures. 4.2.3. Seek medical attention. Rev Date: 10/22/15 Page 2 of 7

4.3. Inhalation: Not Applicable 4.4. Call poison center if you feel unwell. 4.5. Physicians: Treat according to person s condition and specifics of exposure. Section 5. Section 6. Section 7. Section 8. Fire Fighting Measures 5.1. Flash point: Not applicable/determined 5.2. Lower/Upper Explosive Limit: Not applicable/determined 5.3. Extinguishing Media: Water, CO2, and sand. 5.4. Extinguishing Media to Avoid: None 5.5. Protection of Firefighters 5.5.1. Hazardous Decomposition Products: Not applicable/determined 5.5.2. Unusual Fire and Explosion Data: Material may be electrically conductive. 5.5.3. Protective Equipment and Precautions for Firefighters: Standard protective equipment and precautions Self-contained breathing apparatus (SCBA) and full firefighting turnout gear 5.6. Unusual Fire Hazards: None known Accidental Release Measures 6.1. Pieces of broken fixture components may form sharp edges and fine particulate matter can be created. Sweep up loose material while wearing eye protection, respiratory protection, and gloves as needed to prevent irritation and/or lacerations. Place gathered material in an impermeable container and label appropriately. 6.2. Refer to Sections 5 and 8 for personal protective equipment requirements. 6.3. Refer to Sections 13 and 15 for possible additional guidance regarding regulatory requirements. Handling & Storage 7.1. Use normal good material and housekeeping practices to avoid breakage. 7.2. Always disconnect power before installing, inspecting, removing or replacing bulbs. 7.3. After disconnecting power allow sufficient time for bulb to cool before attempting to make contact. Heat resistant gloves may be suggested for additional safety. 7.4. Follow NFPA 654 (dusts) and 484 for metal dust for managing dust hazards. Exposure Controls/Personal Protection 8.1. Appropriate Engineering Controls: Do not use any light bulb in applications where humans and/or animals will be Rev Date: 10/22/15 Page 3 of 7

subjected to direct long-term uncomfortable visual exposure to light emissions as this could result in eye injury. If bulb appears damaged, remove power and then repair or replace the product before returning it to service. If any materials are to be processed in such a manner as to create particulates (mechanical breaking as part of end of product life disposal and recycling), use exhaust ventilation and/or wet working methods to minimize release of particulate to workroom air and employee breathing 8.2. Personal Protective Equipment 8.2.1. Respiratory: None required under normal use conditions. Appropriate local ventilation or an air purifying respirator should be used if the articles are being abraded or reduced in size using mechanical methods. 8.2.2. Skin Protection: 8.2.2.1. If risk of breakage is present impermeable and/or cut resistant gloves should be worn. 8.2.2.2. Operating light bulbs are hot. Use of temperature resistant gloves is recommended. **Always allow sufficient time for product to cool prior to touching.** 8.2.3. Eye/Face Protection: Wear safety glasses with side shields to avoid chance of product getting into unprotected eye. If service personnel need to work with a lit bulb without light diffusers and/or filters installed, appropriate light filtering eye wear should be used. 8.3. General Hygiene Considerations: Workers should wash their face and hands prior to eating, drinking, or smoking. 8.4. Additional Exposure Information: Not Applicable Section 9. Physical and Chemical Properties 9.1. Physical form: Solid 9.2. Color: Opaque/Translucent 9.3. Odor Little / none 9.4. Odor threshold: Not applicable/determined 9.5. ph: Not applicable/determined 9.6. Sublimes at: Not applicable/determined 9.7. Decomposition temperature: No vapor expected 9.8. Evaporation rate: 0 9.9. Relative density (g/cc): Not applicable/determined 9.10. Vapor density (air = 1): No vapor expected 9.11. Fat solubility (mg/kg, C): Not applicable/determined 9.12. Water solubility (mg/kg C): Not applicable/determined Rev Date: 10/22/15 Page 4 of 7

9.13. Partition coefficient (low Pow): Not applicable/determined 9.14. Flammability: Not applicable/determined Flash point ( C): Not applicable/determined Explosivity limits (% v/v): Not applicable/determined 9.15. Auto-ignition temperature ( C): Not applicable/determined 9.16. Volatility by Weight: <0.01% 9.17. Oxidizing properties: None known 9.18. Other physical-chemical properties: None known 9.19. Viscosity: Solid Section 10. Section 11. Stability and Reactivity 10.1. Reactivity: Normally stable 10.2. Chemical Stability: Normally stable 10.3. Hazardous polymerization Conditions: Will not occur 10.4. Conditions to avoid: Rapid temperature change may result in broken envelope. 10.5. Materials to Avoid (incompatible): Because of heat generated by bulb during operation flammable materials and objects adversely affected by heating or drying action should be avoided. Toxicological Information 11.1. Acute toxicity oral: None known 11.2. Carcinogenicity: 11.2.1. Some components may contain carcinogens listed by IARC, but these quantities typically are well below 0.1% of the total. 11.3. Acute toxicity inhalation: None known 11.4. Skin irritation / corrosion: None known 11.5. Serious damage to eyes / eye irritation: None known 11.6. Skin and respiratory sensitization: None known 11.7. Specific target organ toxicity following single or repeated exposure: None known 11.8. Toxicity following single exposure: Oral: Inhalation: None known None known 11.9. Toxicity repeated exposure: None known 11.10. Reproductive toxicity: Not applicable/determined 11.11. STOT - single exposure: Not applicable/determined 11.12. STOT - repeated exposure: Not applicable/determined Rev Date: 10/22/15 Page 5 of 7

11.13. Aspiration hazard: Not applicable/determined Section 12. Section 13. Section 14. Section 15. Ecological Information 12.1. Air: Atmospheric contamination should not occur 12.2. Water: Solid; little to no solubility; may sink in water 12.3. Soil: Transformation in landfill unlikely 12.4. Degradation: not biodegradable 12.5. Toxicity to water organisms: unlikely/low risk 12.6. Toxicity to soil organisms: unlikely/low risk 12.7. Bioaccumulation: Solid; little to no solubility 12.8. Water treatment plants: Solid; little to no solubility; unlikely to affect bacteria Disposal Considerations 13.1. Waste Disposal Method: Method must comply with all Federal, local and state laws and regulations. Be sure to check Local requirements as they may be more stringent than those of higher jurisdictions. 13.2. Hazardous waste classification: In its manufactured state this product is not classified as hazardous waste. Transport Information 14.1. This material is not classified as a hazardous material or dangerous good by the U.S. Department of Transportation, the International Air Transport Association, or the International Maritime Organization Regulatory Information 15.1. The contents of this SDS comply with United Nations (GHS) or Globally Harmonized System of Classification and Labeling of Chemicals. 15.2. U.S. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65): This product may contain chemicals or product chemicals when heated known to the state of California to cause cancer, birth defects, or other reproductive harm. 15.3. Section 302 Extremely Hazardous Substances (40 CFR 355): None 15.4. Section 304 CERCLA Hazardous Substances (40 CFR 302): None 15.5. Section 311/312 Hazard Class (40 CFR 370): 15.5.1. Acute: No 15.5.2. Chronic: No 15.5.3. Fire: No 15.5.4. Pressure: No Rev Date: 10/22/15 Page 6 of 7

15.5.5. Reactive: No 15.6. Section 311 Toxic Chemicals (40 CFR 372): None present in a regulated quantity nor intentionally added Section 16. Other Information 16.1. Preparer: Damar Worldwide 4 LLC, Technical and Testing Department 16.2. Disclaimer: The information contained in this Material Safety Data Sheet is supplied in conformity with 29 CFR 1910.1200 of the OSHA Hazard Communication Standard. The information set forth herein is presented in good faith and believed to be correct. No representations are made as to the completeness or accuracy thereof. The purchaser is solely responsible for compliance with all applicable laws and regulations concerning the use of this product. Neither Preparer nor Company assumes any liability or responsibility for its use. Rev Date: 10/22/15 Page 7 of 7