Material Safety Data Sheet The Valvoline Company Date Prepared: 02/10/95 Date Printed: 10/19/99 MSDS No: 503.0234630-004.006I NAPA CITRUS ORANGE HAND CLEANER W/PUMICE 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: NAPA CITRUS ORANGE HAND CLEANER W/PUMICE General or Generic ID: DETERGENT Company Telephone Numbers The Valvoline Company Emergency: 1-800-274-5263 P.O. Box 14000 Lexington, KY 40512 Information: 1-606-357-7847 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS Number % (by weight) -------------------------------------------- ------------- ------------- POTASSIUM SODIUM ALUMINOSILICATE 1332-09-8 2.5-13.0 LIMONENE 5989-27-5 2.5-13.0 NONIONIC SURFACTANT 68154-97-2 1.0-8.0 TRIETHANOLAMINE 102-71-6 1.0-6.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Skin Swallowing Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation Symptoms of Exposure
Target Organ Effects Developmental Information Cancer Information Other Health Effects Primary Route(s) of Entry Skin absorption, Ingestion. 4. FIRST AID MEASURES Eyes Skin If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. Swallowing Do not induce vomiting. This material is an aspiration hazard. If individual is drowsy or unconscious, place on left side with the head down. Seek medical attention. If possible, do not leave individual unattended. Inhalation Note to Physicians 5. FIRE FIGHTING MEASURES Flash Point 193.0 F (89.4 C) SETA Explosive Limit (for component) Lower.7 % Autoignition Temperature Hazardous Products of Combustion Fire and Explosion Hazards
Extinguishing Media carbon dioxide, dry chemical. Fire Fighting Instructions Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment section of this MSDS. No special precautions necessary when fighting fires involving this product. NFPA Rating Health - 0, Flammability - 0, Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spill Flush area with water. Large Spill Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occured. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Storage 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Skin Protection Respiratory Protections Not required under normal conditions of use. Engineering Controls Not required under normal conditions of use.
Exposure Guidelines Component ---------- POTASSIUM SODIUM ALUMINOSILICATE (1332-09-8) No exposure limits established LIMONENE (5989-27-5) No exposure limits established NONIONIC SURFACTANT (68154-97-2) No exposure limits established TRIETHANOLAMINE (102-71-6) ACGIH TLV 5.000 mg/m3 - TWA 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point (for component) 212.0 F (100.0 C) @ 760 mmhg Vapor Pressure (for component) 17.500 mmhg @ 68.00 F Specific Vapor Density Specific Gravity 1.030 @ 60.00 F Liquid Density 8.580 lbs/gal @ 60.00 F 1.030 kg/l @ 15.60 C Percent Volatiles (Including Water) Volitile Organic Compounds (VOC) (Maximum) 9.200 % 95.000 g/l Evaporation Rate Appearance State LIQUID Physical Form LOTION Color WHITE
Odor ph ORANGE 5.5 Solubility in Water SOLUBLE 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition Chemical Stability Stable. Avoid heat, open flame, and prolonged storage at elevated temperatures. This product should not be heated above 140 F(60 C) in the presence of aluminum due to excessive corrosion and potential chemical reaction releasing flammable hydrogen gas. Incompatibility 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: Not Regulated
Container/Mode: CASES/SURFACE - NO EXCEPTIONS NOS Component: RQ (Reportable Quantity) - 49 CFR 172.101 15. REGULATORY INFORMATION US Federal Regulations TSCA (Toxic Substances Control Act) Status TSCA (UNITED STATES) The intentional ingredients of this product are listed. CERCLA RQ - 40 CFR 302.4 SARA 302 Components - 40 CFR 355 Appendix A Section 311/312 Hazard Class - 40 CFR 370.2 Immediate( ) Delayed( ) Fire( ) Reactive( ) Sudden Release of Pressure( ) SARA 313 Components - 40 CFR 372.65 International Regulations Inventory Status Not determined State and Local Regulations California Proposition 65 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Last Page