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Available online at www.sciencedirect.com ScienceDirect Procedia Engineering 84 (014 ) 97 93 014 ISSST, 014 International Symposium on Safety Science and Technology Research of emergency venting time in natural gas pipeline accidents with SPS XIONG Yi*, Zhang Liping, ZHU Tingting Mechanical and Storage and Transportation Engineering Institute, China University of Petroleum (Beijing), Beijing 1049, China Abstract Gas venting is an important step in the emergency repair of natural gas pipeline accidents. Accurately estimating the gas venting time is of great significance for arranging gas pipeline emergency repair process. Therefore, the venting model is built with Stoner Pipeline Simulator (SPS), and the influencing factors of venting time are studied by SPS dynamic simulation. The results show that pipe length, pipe pressure, pipe diameter and diameter of gas venting pipe can affect the gas venting time. And then a empirical law of natural gas venting time and pipe parameters is summed up, which can provide theoretical support for the organization of emergency repair. 014 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/). Peer-review under responsibility of scientific committee of Beijing Institute of Technology. Peer-review under responsibility of scientific committee of Beijing Institute of Technology Keywords: accident of natural gas pipeline; emergency repair; gas venting time; SPS dynamic simulation 1. Introduction As one of the primary means of natural gas transportation, gas pipeline is put forward higher requirements for safety, environmental protection, efficiency[1]. Therefore, the accident of gas pipeline will pose a serious threat to downstream users security and even national energy security[]. During the emergency repair process, one of the most important things is making sure the time of emergency repair, which can affect the program of emergency repair and gas supply of downstream users. On the other hand, the time of emergency venting is the main composition of emergency repair time. Therefore, accurately estimating emergency venting time is of great significance for arranging emergency repair[3]. * Corresponding author. Tel.: 010-89731533. E-mail address: xiongyi@cup.edu.cn 1877-7058 014 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/). Peer-review under responsibility of scientific committee of Beijing Institute of Technology doi:10.1016/j.proeng.014.10.517

98 Xiong Yi et al. / Procedia Engineering 84 ( 014 ) 97 93 Emergency venting refers to the operation of emptying the natural gas through valve chamber till the pipe pressure within the safe range during the accident emergency process. At present, the rule of emergency venting time has been investigated by some researchers, which shows that the length and diameter of pipeline, the diameter of venting line and the difference of pressure before and after venting will affect the emergency venting time. However, there are still some problems in their study. Kong jimin[1] deduced theoretic formula of emergency venting time with the gas equation of state and the conservation of mass, but the formula is put forward with the steady-state estimation methods without considering the influences of the friction of pipe or the compression coefficient and viscosity changing with the pipeline pressure. Ref.[4] suggests the semi-empirical formula of emergency venting time by USA, however it still a steady-state formula without considering these dynamic parameters. Liu wei[5] and Ye xueli [4] pointed out the deficiencies of these formulas and obtain the dynamic calculation method with Fano equation and numerical integration method. However, they do not put forward empirical formula, which limits the using of this method in emergency, and the dynamic effect of the transmission pipeline is not considered yet. Therefore, dynamic analysing, employed to improve accuracy of estimating, and empirical formula of the dynamic analysing result are needed. SPS is regard as a credible software on long-distance pipeline hydraulic dynamic simulation, which has been successfully applied in West to East Gas Line, Sichuan to East Gas Transmission Line, etc[6,7]. Therefore, the model of gas venting is built with SPS, and the rule of venting time is studyed. With the dynamic simulation by SPS, a empirical formula has been put forward, which reflects the relation of pipeline parameters and emergency venting time. With this empirical formula, emergency venting time can be fastly estimated and used to direct emergency repair of pipeline accidents. Furthermore, the empirical formula has been compared with the theoretic formula and semi-empirical formula adopted in Ref.[4].. Venting process model of emergency in natural gas pipeline.1. SPS modelof venting process in emergency The venting process of emergency repair is generally taken in the valve chambers at both ends of accident point, which is shown in Fig. 1. Among them, T_JDF1_JDF is the gas transmission pipeline, H_GG1 and H_GG are venting pipelines, B_JDF1 and B_JDF are block valves in main line, B_QF1 and B_QF are venting ball valves. Firstly, put the main pipeline in normal transmission state. And then close the block valves in main line (B_JDF1 and B_JDF) and open the venting ball valves (B_QF1 and B_QF) to simulate venting. E_FK1 ND_QF1_OUT H_GG1 ND_QF1_IN ND_QF_IN H_GG ND_QF_OUT E_FK B_QF1 B_QF E_GX_IN ND_JDF1_IN B_JDF1 ND_JDF1_OUT T_JDF1_JDF ND_JDF_IN B_JDF ND_JDF_OUT E_GX_OUT Fig. 1. SPS model of emergent venting process in natural gas pipeline... Control equation Model In the venting process, the gas flow in the pipeline fulfills the control equations in SPS, which includes continuity equation, energy equation, momentum equation and BWRS equation of state. Considering these dynamic parameters, viscosity is calculated with formula (1) and friction coefficient is obtained with Colebrook method. exp(vpmi P VTMI T ) (1) 0

Xiong Yi et al. / Procedia Engineering 84 ( 014 ) 97 93 99 where, is the viscosity under specified pressure and temperature, Pa s; is the viscosity under standard 0 conditions, Pa s; P is the difference between pressure in pipeline and in standard state, Pa; T is the difference between temperature in pipeline and in standard state, K; VPMI is the pressure coefficient of viscosity, 1/Pa; VIMI is the temperature coefficient of viscosity, 1/K. At the outlet of the venting pipe, it s considered to be in a supercritical state because of the high pressure difference between the venting pipe and the environmental. For the sound barrier function, outlet mass flow should meet the formula ()[8]. G=AP KMg ( ) ZRT K 1 K 1 K 1 () where, G is the mass flow, kg/s; A is the cross-sectional area of venting valve, m ; P is the absolute pressure of venting pipe, Pa; M is the relative molecular mass of natural gas; Z is the natural gas compression factor; T is the pipe temperature, K; K is the adiabatic coefficient, for natural gas K 1.3 ; R 8.31J mol -1 K -1 is a constant; g= 9.8m/s is the gravitational acceleration..3. Venting system verification Select the actual data of a emergency venting process to verify the accuracy and reliability of the established venting model. The outside diameter of main pipeline is 711mm with 10mm wall thickness, the length is 31.7km, and the operating pressure is 9MPa. And the venting pipline outside diameter is 73mm with 10mm wall thickness. It takes 17 hours to reduce the pipe pressure to atmospheric pressure with venting at one end of the pipe. And then, simulating with SPS is taken, which shows that it will take 16 hours and 38 minutes for this venting process. The relative error is.15%, which verifies the applicability of this model. 3. Dynamic analysis of emergency venting rule According to previous work of steady-state analysis, the venting time is related to varied parameters of pipes, such as pipe length and diameter of venting main pipeline, diameter of venting process pipe, pressure difference of accident pipeline before and after venting, etc. Therefore, the influence of these parameters has been research with dynamic simulation. 3.1. Influence of venting main pipeline length With other dynamic parameters remaining unchanged, the influence of venting main pipe length on venting time is considered with the venting model established by SPS. During this analysis, the diameter of main pipe is Φ1016 18mm and the diameter of venting process pipe is Φ33.9 6.5mm; the pressure of main pipe is 10MPa and atmospheric pressure after venting. Venting mode is venting in a single-ended valve chamber. The simulation results are shown in Fig.. And the relation of venting time and main pipe length can be fitted by formula (3), which is linear correlation. t al (3) where, t is the venting time and L is the length of venting main pipeline, a is the coefficient of association. Fitting curve shown in Fig. indicates that a is 35.68min/km. 3.. Influence of venting main pipeline diameter With other dynamic parameters remaining unchanged, the influence of venting main pipe diameter on venting time is considered with the venting model established by SPS. During this analysis, the length of main pipe is 0km

930 Xiong Yi et al. / Procedia Engineering 84 ( 014 ) 97 93 and the diameter of venting process pipe is Φ33.9 6.5mm; the pressure of main pipe is 10MPa and atmospheric pressure after venting. Venting mode is venting in a single-ended valve chamber. The simulation results are shown in Fig. 3. And the relation of venting time and square of main pipe inside diameter can be fitted by formula (4), which is linear correlation. t bd (4) where, t is the venting time and D is the square of inside diameter of venting main pipeline, b is the coefficient of association. Fitting curve shown in Fig. 3 indicates that b is 794.6min/m. Fig.. Contrast of simulation data points and fitting curves of venting mainpipeline length influence. Fig. 3. Contrast of simulation data points and fitting curves of venting main pipeline diameter influence. 3.3. Influence of venting process pipe diameter With other dynamic parameters remaining unchanged, the influence of venting process pipe diameter on venting time is considered with the venting model established by SPS. During this analysis, the length of main pipe is 0km and the diameter of venting main pipe is Φ1016 18mm; the pressure of main pipe is 10MPa and atmospheric pressure after venting. Venting mode is venting in a single-ended valve chamber. The simulation results are shown in Fig.4. And the relation of venting time and reciprocal of square of venting process pipe inside diameter can be fitted by formula (5), which is linear correlation. t c d (1 / ) (5)

Xiong Yi et al. / Procedia Engineering 84 ( 014 ) 97 93 931 where, t is the venting time and 1/d is the reciprocal of square of venting process pipe inside diameter, c is the coefficient of association. Fitting curve shown in Fig. 4 indicates that c is 70.0min m. Fig. 4. Contrast of simulation data points and fitting curves of venting process pipe diameter influence. 3.4. Influence of pressure difference before and after venting With other dynamic parameters remaining unchanged, the influence of pressure difference before and after venting on venting time is considered with the venting model established by SPS. During this analysis, the length of main pipe is 0km and the diameter of venting main pipe is Φ1016 18mm; the diameter of venting process pipe is Φ33.9 6.5mm. Venting mode is venting in a single-ended valve chamber. The simulation results are shown in Fig. 5. And the relation of venting time and pressure difference before and after venting can be fitted by formula (6), which is linear correlation. t e P (6) where, t is the venting time and P is the pressure difference before and after venting, e is the coefficient of association. Fitting curve shown in Fig. 5 indicates that e is 76.39min/MPa. Fig. 5. Contrast of simulation data points and fitting curves of influence of pressure difference before and after venting. 4. Empirical formula of emergency venting time With the dynamic analysis by SPS, it is indicated that the venting time is linear positive correlation with the length of venting main pipe, the square of inside diameter of venting main pipe, the inverse square of inside

93 Xiong Yi et al. / Procedia Engineering 84 ( 014 ) 97 93 diameter of venting process pipe, and the pressure difference before and after venting. This rule can be expressed by empirical formula (7) D (7) t f L P d where, t is the venting time, min; D is the inside diameter of venting main pipeline, m; d is the venting process pipe inside diameter, m; L is the length of venting main pipeline, km; P is the pressure difference before and after venting, MPa. Base on the analysis of the influence of these parameters, the numerical relationship of coefficient f and abcdcan,,, be obtained by simultaneous formula (3) (7), which is shown in equation (8) (11). a 99.3 f 35.68 (8) b 067.8 f 794.6 (9) c 19.1 f 70.0 (10) e 198.6 f 76.39 (11) And then, it can be calculated that f is 0.38 min/(mpa km) with least square method. Comparing this empirical formula with steady-state formula in Ref.[4], the maked difference is that the relationship of venting time and pressure difference before and after venting. And another difference is that the coefficient f in empirical formula is different from in theoretic formula and semi-empirical formula. With the empirical formula, emergency venting time can be fastly estimated and used to direct emergency repair of pipeline accidents. 5. Conclusions (1) The dynamic analysis shows that the emergency venting time is related to the length and diameter of venting main pipe, the diameter of venting process pipe and pressure difference before and afer venting, which is similar with steady-state analysis result. () Empirical formula indicates the difference of relationship with the dynamic and steady-state analysis, which may be more precise. (3) With the empirical formula, emergency venting time can be fastly estimated and used to direct emergency repair of pipeline accidents. Acknowledgements We gratefully acknowledge the financial support by China Postdoctoral Science Foundation (013M530846) and Science Foundation of China University of Petroleum, Beijing (No.YJRC-011-10). References [1] Kong Jimin, The discussing on gas venting time and gas venting amount in natural gas pipeline, Petrochemical industry application, 4(005) 18 0. [] Du Yan, Xie Ying, Wang Zihao, etc, Accident Analysis of Gas Pipeline, Pipeline Technique and Equipment, (009)16-18. [3] Niu Jianzhuang, Application of In-line Stopping Technology in Gas Transmission Pipeline, OGST, 7(009)63-66. [4] Ye Xueli, Hydraulic calculation of natural gas vent line, Natur. GAS Ind. 3(1999)77-81. [5] Liu wei, Calculation of gas pressure relief headers, China Offshore Oil and Gas (Engineering), 6(1991)7-13. [6] Liu Jun, Zhang Lei, Cheng Xiaojiao, Based on dynamic simulation of natural gas pipeline emergency blow-down SPS, Petrochemical industry application, 11(013) 80 83. [7] Zheng Yunping, Xiao Jie, Sun Xiao, etc, Application and underdtanding of Stoner Pipeling Simulator (SPS), Natur. GAS Ind. 11(013)1-6. [8] L. Prandtl, Introduction to fluid Mechanics, Science Press, Beijing, 1984.