Metalaxyl-M -MATERIAL SAFETY DATA SHEET

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Metalaxyl-M -MATERIAL SAFETY DATA SHEET Manufacturer/information service: ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: info@rayfull.com sales@rayfull.com 1. Chemical Product Identification Product Name: Metalaxyl-M Molecular Formula: C 15 H 21 NO 4 Molecular Weight: 279.30 Structural Formula: Chemical Name: methyl N-(methoxyacetyl)-N-(2,6-xylyl)-Dalaninate; methyl (R)-2-{[(2,6-dimethylphenyl) methoxyacetyl] amino}propionate (IUPAC) Form: Liquid Color: Reddish-Brown Odor: Sweet Aromatic CAS No.: 70630-17-0 2. Composition / Information on Ingredients Composition CAS No. Content % Metalaxyl-M 70630-17-0 90.0 Other ingredients 10.0 1

3. Hazards Identification Symptoms of Acute Exposure: May cause eye irritation Hazardous Decomposition Products: Can decompose at high temperature forming toxic gases Unusual fire, Explosion and Reactivity Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. 4. First Aid Measures Have the product container, label or Material Safety Data Sheet with you when you calling a Poison control center or doctor, or going for treatment. Ingestion: If swallowed, call a Poison control center or a Doctor immediately for treatment advice. Have the person sip a glass of water if able to swallow. Do not induce vomiting unless to do so by a Poison Control center or Doctor. Do not give anything by mouth to an unconscious person. Eye: If in eyes, Hold eye open and rinse slowly and gently with water for 15 20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Skin: Wash affected area with plenty of soap and water for 15 20 minutes. Remove contaminated clothing. Launder contaminated clothing separately. Get medical attention. Inhalation: Move person to fresh air. If person is not breathing give artificial respiration, preferably mouth to mouth if possible. Call a Poison control center or doctor for further treatment advice. Note to Physician: There is no specific antidote if this product is ingested. Treat symptomatically. 5. Fire-Fighting Measures Fire and Explosion: Flash point : >40 C Flammable Limits (% in Air): Not Available Auto ignition Temperature: Not Available Flammability: Combustible Liquid Unusual Fire, Explosion and Reactivity Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion. In case of Fire: Use dry, chemical, foam or CO2 extinguishing media. Wear full protective clothing and self-contained breathing apparatus. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. 2

Prevent use of contaminated buildings, area and equipment until decontaminated. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff. 6. Accidental Release Measures Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions in protective equipment section. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition. 7. Handling And Storage Store the product in a well-ventilated, secure area out of reach of children and domestic animals. Do not use or store near heat or open flame. Do not store food, beverages, tobacco or feed in storage area. Prevent eating, drinking, smoking and cosmetic application in areas where there is a potential exposure to the product. Wash thoroughly with soap and water after handling. 8. Exposure Controls/Personal Protection Applicable control measures, including engineering controls: Please refer to the product label for personal protective clothing/equipment. Personal protective equipment for each exposure route: Ingestion: Do not eat, drink, smoke or apply cosmetics in areas where there is a potential for exposure to the material. Always wash thoroughly after handling. Eye Contact: To avoid eye contact, wear safety glasses with side shields or chemical goggles. Skin Contact: To avoid skin contact, wear rubber gloves, rubber boots, long-sleeved shirt, long pants and a head covering. Inhalation: To avoid breathing dust, wearr pesticide respirator with particulate prefilters. Select N or R or P type as appropriate for the oil characteristics of any other air contaminants present. Filter efficiency ranges from 95-99.7% as appropriate for the size distribution of dust present. Applicators: Please refer to product label for personal protective clothing and equipment 9. Physical and Chemical Properties 3

PH: 7 9 (1% solution in H2O @ 25 C) Vapour pressure and reference temperature- for Metalaxyl-M: 3.30E -03 Pa @ 25 C. Vapour density: Not available Specific gravity or density: 0.60g/cm3. Evaporation Rate: Not applicable Water/oil partition coefficient: Not available Viscosity: Not applicable. Product is a solid Solubility in water: 26.0 g/l @ 25 10. Stability and Reactivity Chemical stability: Stable under normal use and storage conditions. Conditions to avoid: None known Incompatibility with other materials: None known Hazardous decomposition products: Can decompose at high temperatures forming toxic gases. Hazardous polymerization: Will not occur 11. Toxicological Information Carcinogenicity Potential: None Observed Reproductive Hazard Potential: None Observed Mutagenic Potential: None observed Chronic exposure: Liver effects at high dose levels 12. Ecological and Ecotoxicological Information Practically non-toxic to birds in dietary exposure and slightly toxic in direct oral exposure. Non-toxic to bees. Non toxic to slightly toxic to aquatic invertebrates and fish. Slightly toxic to mammals 13. Disposal Considerations Do not reuse product containers. Dispose of product containers, waste containers, and residues according to local, provincial, and federal health and environmental guidelines. 14. Transport Information Not applicable. 4

15. Regulatory Information Not applicable. 16. Other Information All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS. 5