A MATERIAL SAFETY DATA SHEET 2-IODOXYBENZOIC ACID. 1.2 Relevant identified uses of the substance or mixture and uses advised against

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Transcription:

A MATERIAL SAFETY DATA SHEET 2-IODOXYBENZOIC ACID 1.1 Product Identifiers: Product Name : 2-Iodoxybenzoic acid CAS No : 61717-82-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Supplier: Infinium Pharmachem Pvt. Ltd. (AN ISO 9001:2008 CERTIFIEDCO.) 38, G.I.D.C, Sojitra Dist: ANAND Gujarat, India Tel : 0091-2697-234987 Fax : 0091-2697-234987 Email : info@infiniumpharmachem.com Synonyms : Stabilized IBX CAS No. : 61717-82-6 Molecular Weight : 280.02 g/mol Chemical Formula : C 7 H 5 IO 2 3.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Skin corrosion(category 1A), H314 Specific target organ toxicity -single exposure(category 3), Respiratory system,h335 Classification according to EU Directives 67/548/EEC or 1999/45/EC C Corrosive R35 Xi Irritant R37 R 1 3.2 Label elements Labeling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H314 H335 Causes severe skin burns and eye damage. May cause respiratory irritation. Precautionary statement(s) P280 P261 P305 + P351 + P338 P310 Wear protective gloves/ eye protection/ face protection Avoid breathing dust. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician Supplemental Hazard Statements None According to European Directive 67/548/EEC as amended.

Hazard symbol(s) Corrosive R-phrase(s) R1 Explosive when dry. R35 Causes severe burns. R37 Irritating to respiratory system. S-phrase(s) S26 S35 S36/37/39 S45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of in a safe way. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately.(show the label wherever possible) 3.3 Other hazards None 4.1 Description of first aid measures General Advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most Important symptoms & efforts, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 3.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed 5.1 Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Hydrogen Iodide, Carbon oxides. 5.3 Advice for firefighters Wear self contained breathing apparatus for fighting if necessary. 5.4 Further Information 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13

7.1 Precautions for safe Handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed..normal measures for preventive fire protection. 7.2 Conditions for safe Storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. 7.3 Specific end uses. 8.1 Control parameters Components with workplace control Parameters. 8.2 Exposure Controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection

Complete suit protecting against chemicals, the type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). 9.1 Information on Basic physical & chemical properties a) Appearance Form: crystalline b) Odor c) Odor Threshold d) ph 1.8 e) Melting point/freezing Melting point/range: 250 C Decomposes on heating Point f) Initial boiling point and Boiling range g) Flash point h) Evaporation rate i) Flammability (solid, gas) j) Upper/lower Flammability or explosive limits k) Vapor pressure l) Vapor density m) Relative density n) Water solubility no data avaialble o) Partition coefficient: n-octanol /water p) Auto ignition Temperature q) Decomposition Temperature r) Viscosity s) Explosive properties t) Oxidizing properties 9.2 Other safety Information

10.1 Reactivity 10.2 Chemical stability Stable under recommended storage conditions 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials Oxidizing agents, Strong bases, Strong oxidizing agents, Strong reducing agents 10.6 Hazardous decomposition products Other decomposition products - In the event of fire : see section 5 11.1 Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: No component of this product presents at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure

Aspiration hazard Additional Information RTECS: Not available spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache. 12.1 Persistence and degradability 12.2 Bioaccumulative potential 12.3 Mobility in soil 12.4 Results of PBT and vpvb assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.5 Toxicity 12.6 Other adverse effects 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an after burner and scrubber. Contaminated packaging Dispose of as unused product.

14. TRANSPORT INFORMATION 14.1 UN number ADR/RID: -1759 IMDG: -1759 IATA: -1759 14.2 UN proper shipping name ADR/RID : CORROSIVE SOLID, N.O.S.(Isophthalic acid, o-iodoxybenzoic acid) IMDG : CORROSIVE SOLID, N.O.S.(Isophthalic acid, o-iodoxybenzoic acid) IATA : corrosive solid, n.o.s.(isophthalic acid, o-iodoxybenzoic acid). 14.3 Transport hazard class (es) ADR/RID: - 8 IMDG: - 8 IATA: - 8 14.4 Packaging group ADR/RID: - II IMDG: -II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment MSDS Creation Date: 01-01-2015 Revision #1 Date: 31-12-2017 Disclaimer: The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Infinium Pharmachem Pvt Ltd be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Infinium Pharmachem Pvt Ltd has been advised of the possibility of such damages.