Process Safety Management Of Highly Hazardous Chemicals OSHA 29 CFR

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Process Safety Management Of Highly Hazardous Chemicals OSHA 29 CFR 1910.119

PSM - Definition Not all refining hazards are caused by the same factors or involve ve the same degree of potential damage. Personal or occupational safety hazards give rise to incidents such as slips, falls, and vehicle accidents that primarily affect one individual worker for each occurrence. Process safety hazards can give rise to major accidents involving release of potentially dangerous materials, the release of energy (such as fires and explosions), or both.. Process safety incidents can have catastrophic effects and can result in multiple injuries and fatalities, as well as substantial economic, c, property, and environmental damage...the Texas City tragedy in March 2005 was a process safety incident The Report of The U.S. Refineries Independent Safety Review Panel, January 2007

PSM - Definition Process safety in a refinery involves the prevention of leaks, spills, equipment malfunctions, over pressures, excessive temperatures, corrosion, metal fatigue, and other similar conditions The Report of The U.S. Refineries Independent Safety Review Panel, January 2007

Accidents That Affected The PSM Regulation Development Year Company Location Deaths Injuries 1984 Union Carbide Bhopal 2000+? 1989 Phillips 66 Pasadena, TX 24 132 1990 Arco Channelview, TX 17 -- 1990 BSAF Cincinnati, OH 2 41 1991 IMC Sterlington, LA 8 128

Objective of OSHA PSM Prevent catastrophic releases of hazardous chemicals in areas where employees could be exposed to serious harm

Catastrophic Release A major uncontrolled emission, fire,, or explosion, involving highly hazardous chemicals

Highly Hazardous Chemical A Substance possessing : toxic reactive flammable explosive properties Specific list of chemicals specified by OSHA Hydrogen Sulfide Ammonia Chlorine

Flammable Liquid Any liquid having a flash point below 100 F LPG (Propane, Butane, Ethane, etc) Naphtha Cyclohexane Aromatic Compounds (Benzene, Toluene, etc)

Who Must Comply? OSHA List of Highly Hazardous Chemicals, Toxics and Reactive Any flammable liquid or gas on site in one location, in quantities of 10,000 lbs or more

PSM Elements -- Building Blocks for Reducing Risk Training Safe Work Practices Employee Participation Mechanical Integrity Operating Procedures Management of Change Process Safety Information Pre-startup Safety Review Process Hazard Analysis Contractor Program 14 ELEMENTS Incident Investigation Emergency Planning Compliance Audits Trade Secrets

Element 1 Employee Participation Pre-Startup Safety Review Mechanical Integrity Management Of Change Employee Participation Compliance Audits Procedures Training Incident Investigation Hot Work Permits Contractor Plan Process Hazard Analyses Emergency Planning Trade Secrets Process Safety Information

Element 2 Process Safety Information Chemical Hazards Information Process Technology Process Equipment Design Codes

Chemical Hazards Information Information typically found on MSDS Hazcom Information Exposure Guidelines Physical Data Chemical Stability Corrosivity Data Chemical Incompatibility Hazardous Effects of Inadvertent Mixing Thermal and Chemical Stability

Process Technology Information Block Flow Or Process Flow Diagrams Process Chemistry Maximum Intended Inventory Safe Upper and Lower Limits for Process Parameters Consequences of Deviation

Process Equipment Information Materials of Construction Piping and Instrumentation Diagrams (P&ID) Electrical Classification Relief System Design Ventilation system design Design Codes and Standards Material and Energy Balances (Processes built after 1992) Safety Systems Design Codes

Element 3 Process Hazard Analysis (PHA) Identify And Control Process Hazards

PHA Prioritization Extent of the Process Hazards Number of Potential Affected Employees Age of the Process Operating History of the Process

PHA Requirements Hazards of the process Identify previous incidents Engineering and administrative controls (Safeguards) Failure of safeguards Facility Siting Human Factors Evaluation of safety and health impacts

PHA Team One person knowledgeable in the process -- Operator One person knowledgeable in the analysis method Other members as necessary Engineering Maintenance Supervisors Operations

PHA Report Document recommendations to reduce hazards PHA results must be reviewed with employees Must be filed for life of the process Reviewed every 5 years

Element 4 Operating Procedures Objective Develop, implement, and maintain clearly written detailed procedures for safely operating and maintaining a process during all operating modes

Operating Procedures Modes of Operation Initial Startup Normal Operation Temporary Operations Emergency Shut-Down Normal Shut-Down Start-up following a turn around or after emergency shut-down

Operating Procedures -- Content Operating Limits Consequences of deviation Steps to correct or avoid deviations -- Trouble Shooting Safety and Health Measures Precautions to prevent over exposure Action to take if exposure occurs Hazards Safety Systems

Operating Procedures Safe Work Practices Lockout / tagout Confined space entry Opening process equipment Control over entrance into facility Annual Certification Current and accurate

Element 5 Training Initial Training Conducted for each current employee and each new employee before working in a newly assigned process Process Overview Operating Procedures Specific Safety and Health Hazards Safe Work Practices

Training Refresher Training Assures operators understand and follow current operating procedures Every 3 years -- More often if necessary

Training Documentation Verify each employee has received training Verify each employee has understood training Written Tests Observations Verbal Tests

Element 6 Contractor Plan Purpose Define responsibilities of facility employers and contract employers to ensure safe operation

Contractor Plan - FHR Responsibilities Evaluate safety performance and programs Inform contract employers of hazards Train contract employers on emergency action plan Control the entrance, presence and exit of contractors in covered process areas Periodically evaluate contract employers in meeting their obligations Maintain an injury and illness log

Contractor Plan - FHR Responsibilities Train employees on how to safely perform their job Instruct employees in the hazards Train employees in emergency action plan Document that each employee has received and understood the training Assure that employees follow FHR safety rules including safe work practices Advise FHR of unique hazards associated with their work

Element 7 Pre-Startup Safety Review (PSSR) Emergency Procedures Design Specifications Operating Procedures Process Hazard Analysis Don t Start That Machine! Training Safety Procedures

Element 8 Mechanical Integrity A strong mechanical integrity program and proper operations form the first line of defense against accidental releases from process equipment

Mechanical Integrity Covered Equipment Relief vent systems Controls Piping Systems Pumps Emergency Shutdown Systems Tanks Furnaces / heaters Vessels

Mechanical Integrity Quality Assurance Assure new or modified equipment is suitable Assure that equipment is correctly installed or modified Assure that maintenance materials, spare parts, and equipment are suitable

Mechanical Integrity Written procedures to maintain the on-going integrity of process equipment: Preventive maintenance Equipment Repair Inspection and Testing

Mechanical Integrity Maintenance Employee Training Process overview Hazards associated with the process Maintenance procedures

Element 9 Hot Work Permit Establish hot work permit system that complies with 29 CFR 1910.252 (a)

Element 10 Management Of Change (MOC) Objective Prevent changes in the process from introducing unacceptable hazards to workers

Management of Change Program Written Procedure for managing changes to: Process Chemicals Technology Facilities Equipment Procedures Process Safety Information

Management of Change Specific Items To Be Addressed For Each Change Technical Basis -- Why? Time Period for Change Safety and Health Impacts Authorization Requirements

Element 11 Incident Investigation Investigate each incident that resulted or could have resulted in a catastrophic release

Incident Investigation Incident investigation must be started as soon as possible, but no later than 48 hours after the incident Incident investigation team At least one person knowledgeable in the process including contract employees where applicable

Incident Investigation Report Incident Investigation Report Date of incident A description of the incident Factors contributing to the incident Recommendations Report must be reviewed with all affected employees including contract employees if necessary System to resolve report recommendations

Element 12 Emergency Planning And Response Institute an emergency response plan according to 29 CFR 1910.38(a) Plan must be reviewed with each employee

Emergency Planning And Response / Emergency Plan Emergency escape procedures and routes Accounting for all employees after evacuation Procedures for employees who remain to perform critical plant operations

Emergency Planning And Response / Emergency Plan Rescue and medical duties Preferred means of reporting fires and emergencies Emergency drills are not required, but are recommended

Element 13 Compliance Audits Evaluate compliance with the PSM standard every 3 years Audit team must include at least one person knowledgeable in the process Audit report documents findings

Compliance Audits Document responses to each of the findings listed in the audit report Document that all findings have been corrected Keep the two most recent compliance audits

Element 14 Trade Secrets Employer must make available all necessary information available to employees Process Safety Information PHAs Operating Procedures Incident Investigations Emergency Planning and Response Compliance Audits