SECTION 1: CHEMICAL PRODUCT & COMPANY INFORMATION APPLICABLE PART #: BA2, BA2NS IDENTITY: Unicer SUPPLIER: Universal Photonics, Inc. 85 Jetson Lane Central Islip, NY 11722 FOR INFORMATION CALL CUSTOMER SERVICE (516) 935-4000 DATEE PREPARED: July 26, 2016 EMERGENCY TELEPHONE NUMBER: 1.866.519.4752 3-E COMPANY - ACCT # 3665 SECTION 2: HAZARDS IDENTIFICATION GHS CLASSIFICATION: GHS LABEL ELEMENT: OTHER HAZARDS: Not a hazardous substance Not a hazardous substance None knownn SECTION 3: COMPOSITION INFORMATION CHEMICAL NAME Rare Earth Fluoride CAS-NO. 68188-85-2 CONCENTRATION (%) >=5 - <10 SECTION 4: FIRST AID MEASURES GENERAL ADVICE: EYE CONTACT: SKIN CONTACT: INHALATION: INGESTION: Consult a physician Rinse immediately with plentyy of water and seek medical advice. Wash off immediately with soap and plenty of water. If a person feels unwell or symptoms of skin irritation appear, consultt a physician. Remove to fresh air. If unconscious place in recovery position and seek medical advice. Never give anything byy mouth to an unconsciouss person. Do NOT induce vomiting. Rinse immediately with plenty of water and seek medical advice. SECTION 5: FIRE FIGHTING MEASURESS SUITABLE EXTINGUISHING MEDIA: UNSUITABLE EXTINGUISHING MEDIA: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Do not use a solid water stream as it may scatter and spread fire. SPECIFIC HAZARDS DURING FIREFIGHTING G: Exposure to decomposition products may be a hazard to health. Do not allow run- off from firefighting to enter drains or waterr courses. 1
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: In the event of fire, wear self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES: Ensure adequatee ventilation. Follow safe handling advice and personal protective equipment recommendations.. ENVIRONMENTAL PRECAUTIONS: METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Do not flush into surface water or sanitary sewer system. Prevent product from entering drains. Sweep up and shovel into suitable containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7: HANDLING & STORAGE HANDLING: STORAGE: Do not get in eyes or mouth or on skin. For r personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Do not use in areas without adequatee ventilation. Keep away from heat and sources of ignition. Keep in a dry, cool and well-ventilated place. SECTION 8: PERSONAL PROTECTION AND EXPOSURE CONTROLS COMPONENTS WITH WORKPLACE CONTROL PARAMETERS: COMPONENTS: CAS-NO. Rare Earth Fluoride 68188-85-2 VALUE TYPE (FORM OFF EXPOSURE) TWA TWA TWA CONTROL PARAMETERS/ PERMISSIBLE CONCENTRATION 2..5 mg/m3 (Fluorine) 2..5 mg/m3 (Fluorine) 2..5 mg/m3 (Fluorine) BASIS OSHA Z-1 ACGIH OSHA P0 BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS: COMPONENTS: Rare Earth Fluoride CAS-NO.: 68188-85-2 CONTROL PARAMETERS: Fluoride Fluoride BIOLOGICAL SPECIMEN: Urine Urine SAMPLING TIME: Prior to shift (16 hours after exposuree ceases) ) End of shiftt (As soon as possible after exposuree ceases) ) PERMISSIBLE CONCENTRATION: 2 mg/l 3 mg/l BASIS: ACGIH BEI ACGIH BEI 2
ENGINEERING MEASURES: Apply technical measures to comply with the occupational exposure limits. Provide adequate ventilation. PERSONAL PROTECTIVEE EQUIPMENT: RESPIRATORY PROTECTION: HAND PROTECTION MATERIAL: Protect PROTECTIVE MEASURES When workers are facing concentrations abovee the exposuree limit they must use appropriate certified respirators. ive gloves. S: Wear suitable protective equipment. When using do not eat, drink or smoke. HYGIENE MEASURES: Remove contaminated clothing and protective equipment before entering eating areas. Wash hands before breaks and immediately after handling the product. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Granular LOWER EXPLOSION LIMIT: COLOR: Colored VAPOR PRESSURE: ODOR: Characteristic RELATIVE VAPOR DENSITY: ODOR THRESHOLD: RELATIVE DENSITY: PH: BULK DENSITY: MELTING POINT/ RANGE BOILING POINT/ RANGE: FLASH POINT: EVAPORATION RATE: UPPER EXPLOSION LIMIT : T: SOLUBILITY(IES) WATER SOLUBILITY: PARTITION COEFFICIENT: N-OCTANOL/WATER AUTO-IGNITION TEMPERATURE: THERMAL DECOMPOSITION: VISCOSITY KINEMATIC: Not determined SECTION 10: STABILITY & REACTIVITY REACTIVITY: CHEMICAL STABILITY: POSSIBILITY OF HAZARDOUS REACTIONS 3
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS: Incompatible materials Incompatible with oxidizing agents. Incompatible with strong acids and bases. SECTION 11: TOXICOLOGICAL INFORMATION INFORMATION ON LIKELY ROUTES OF EXPOSURE: Inhalation (dust/mist/fume), inhalation (vapor), Skin/ Eye Contact, Ingestion ACUTE TOXICITY: SKIN CORROSION/IRRITATION: SERIOUS EYE DAMAGE/EYE IRRITATION: RESPIRATORY OR SKIN SENSITIZATION: SKIN SENSITIZATION: RESPIRATORY SENSITIZATION: : GERM CELL MUTAGENICITY: CARCINOGENICITY: IARC: ACGIH: OSHA: NTP: REPRODUCTIVE TOXICITY: STOTT - SINGLE EXPOSURE: STOTT - REPEATED EXPOSURE: ASPIRATION TOXICITY: identified ass probable, possible or confirmed human carcinogen by IARC. identified ass a carcinogen or potential carcinogen by ACGIH. identified ass a carcinogen or potential carcinogen by OSHA. identified ass a known or anticipated carcinogen by NTP. SECTION 12: ECOLOGICAL INFORMATIO ON ECO TOXICITY: PERSISTENCE AND DEGRADABILITY: BIO ACCUMULATIVE POTENTIAL: 4
MOBILITY IN SOIL: OTHER ADVERSE EFFECTS: SECTION 13: DISPOSAL INFORMATION WASTE FROM RESIDUES: Dispose of wastes in an approved waste disposal facility. SECTION 14: TRANSPORTATION INFORMATION INTERNATIONAL REGULATION: UNRTDG: Not regulated as a dangerous good IATA-DGR: Not regulated as a dangerous good IMDG-CODE: Not regulated as a dangerous good TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE: Not applicable for product as supplied. NATIONAL REGULATIONS: 49 CFR DOT T: Not regulated as a hazardous material SECTION 15: REGULATORY INFORMATION TSCA LIST: SARAA 311/312 HAZARDS: SARAA 302: SARAA 313: TSCA 5a - Not relevant TSCA_12b - Not relevant No SARA Hazards No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. This material does not containn any chemical components with known CAS numberss that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES: EINECS: inventory TSCA: CANADIAN DSL: PHILIPPINES (PICCS): JAPAN (ENCS): JAPAN (ISHL): On TSCA Inventory This product contains components that are on the Canadian DSL Not in compliance with the inventory. Not in compliance with the inventory. Not in compliance with the inventory. 5
KOREA (KECI): CHINA (IECSC): AUSTRALIA (AICS): NEW ZEALAND (NZLOC): inventory. inventory inventory. inventory. INVENTORIES: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA), CH INV (Switzerland), MY INV (Malaysia), TR INV (Turkey), TW INV (Taiwan) SECTION 16: OTHER INFORMATION HMIS RATING: NFPA 704: Health 1, Flammability 0, Reactivity 0, Personal Protection E Health 1, Flammability 0, Reactivity 0 DEFINITIONS: DOT Department of Transportation GHS The Globally Harmonized System of Classification and Labeling of Chemicals HMIS - Hazardous Materials Identification System NFPA - National Fire Protection Association NIOSH National Institute for Occupational Safety and Health NORM Natural Occurring Radioactive Materials IATA International Air Transportation Association IMO International Maritime Organization OSHA Occupational Safety & Health Administration TSCA Toxic Substance Control Act = Not applicable N/F = Not found DISCLAIMER WHILE UNIVERSAL PHOTONICS, INC. BELIEVES THAT THE DATA AND INFORMATION CONTAINED HEREIN ARE FACTUAL AND THE OPINIONS ARE THOSE OF QUALIFIED EXPERTS, THEY ARE NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATION FOR WHICH UNIVERSAL PHOTONICS, INC. ASSUMES ANY LEGAL RESPONSIBILITY. THEY ARE OFFERED SOLEY FOR THE CONSIDERATION, INVESTIGATION AND VERIFICATION BY THE USER. IT IS THE USER S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF THIS PRODUCT, DATA AND INFORMATION WITH APPLICABLE LAWS AND REGULATIONS.unicer.12.15.sds 6