SAFETY DATA SHEET SYSCO FOAM HAND SANITIZER Section. Chemical product and company identification Product name Recommended use and restrictions SYSCO FOAM HAND SANITIZER Hand disinfectant Use only for the purpose on the product label. Product dilution information Not applicable Supplier's information Code Date of issue Section 2. Hazards identification Sysco Corporation 390 Enclave Parkway Houston, Texas 77077 To request MSDS, call 877-822-50 www.sysco.com 924680-2 09 Dec 203 EMERGENCY HEALTH INFORMATION -800-328-0026 Outside United States and Canada CALL -65-222-5352 (in USA) GHS Classification GHS label elements Signal word Symbol FLAMMABLE LIQUIDS - Category 3 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B Warning Hazard statements Flammable liquid and vapor. Causes eye irritation. Precautionary statements Prevention Response Storage Disposal Other hazards Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Keep container tightly closed. No special protection is required. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical attention. Store in a well-ventilated place. Keep cool. See section 3 for waste disposal information. None known. Page /6
Section 3. Composition/information on ingredients Substance/mixture Hazardous ingredients Mixture Concentration Range (%) CAS number ISOPROPYL ALCOHOL 5-20 67-63-0 BENZALKONIUM CHLORIDE 0. 68424-85- Hazardous ingredients Concentration Range (%) CAS number Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse with water for a few minutes. Get medical attention if symptoms appear. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Protection of firstaiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. See toxicological information (section ) Section 5. Fire-fighting measures Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Specific fire-fighting methods Special protective equipment for fire-fighters Use dry chemical, CO₂, water spray (fog) or foam. Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard. Decomposition products may include the following materials carbon dioxide carbon monoxide Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page 2/6
Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Handling Storage Avoid contact with eyes. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Absorb with an inert material. Use a water rinse for final clean-up. Section 7. Handling and storage Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources. Wash hands after handling. Keep out of reach of children. Keep container tightly closed. Keep container tightly closed and sealed until ready for use. Keep container in a cool, well-ventilated area. Avoid all possible sources of ignition (spark or flame). Store in a segregated and approved area. Store between the following temperatures 0 and 45 C Section 8. Exposure controls/personal protection Control parameters Ingredient name Exposure limits ISOPROPYL ALCOHOL ACGIH TLV (United States, 3/202). STEL 400 ppm 5 minutes. TWA 200 ppm 8 hours. OSHA PEL (United States, 6/200). TWA 980 mg/m³ 8 hours. TWA 400 ppm 8 hours. NIOSH REL (United States, 6/2009). TWA 400 ppm 0 hours. TWA 980 mg/m³ 0 hours. STEL 500 ppm 5 minutes. STEL 225 mg/m³ 5 minutes. Appropriate engineering controls Personal protection Eye protection No special protection is required. Hand protection No special protection is required. Skin protection No special protection is required. Respiratory No special protection is required. protection Hygiene measures No special ventilation requirements. No special measures required. Page 3/6
Section 9. Physical and chemical properties Physical state Color Odor ph Flash point Explosion limits Flammability (solid, gas) Melting point Boiling point Evaporation rate (butyl acetate = ) Vapor pressure Vapor density Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Odor threshold Viscosity Stability Possibility of hazardous reactions Hazardous decomposition products Liquid. Red [Light] Alcohol-like 5 to 9 (00%) 42 C (Closed cup) >00 C (>22 F) 0.988 (Water = ) Easily soluble in the following materials cold water and hot water. Kinematic (room temperature) 0 cm 2 /s (0 cst) Section 0. Stability and reactivity Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Materials to avoid Section. Toxicological information Route of exposure The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin contact, Eye contact, Inhalation, Ingestion Symptoms Eye contact Adverse symptoms may include the following irritation watering redness Skin contact Inhalation No specific data. No specific data. Ingestion No specific data. Page 4/6
Section. Toxicological information Acute toxicity Eye contact Skin contact Inhalation Ingestion Toxicity data Product/ingredient name propan-2-ol Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Other adverse effects Causes eye irritation. LC50 Inhalation Rat 30 mg/l Vapor LD50 Dermal Rabbit 2870 mg/kg LD50 Oral Rat 470 mg/kg Section 2. Ecological information Ecotoxicity Aquatic and terrestrial toxicity Product/ingredient name Result Species Disposal methods Section 3. Disposal considerations RCRA classification Avoid disposal. Attempt to use product completely in accordance with intended use. Disposal should be in accordance with applicable regional, national and local laws and regulations. Unused product is D00 (Ignitable) Section 4. Transport information Not intended for transport. Exposure Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Page 5/6
Section 5. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 302/304/3/32 extremely hazardous substances No listed substance SARA 302/304 emergency planning and notification No listed substance SARA 33 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 No listed substance No listed substance Section 6. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards 0 National Fire Protection Association (U.S.A.) Health 0 Flammability Instability/Reactivity Special Date of issue Prepared by 09 Dec 203 Regulatory Affairs -800-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 6/6