Regulation 1907/2006/EC, Article 31 Publication: Sep 96 BIO-CLEAN #360 Liquid disinfectant for aircraft toilets AR0000270 AR0000271 AR0000272 AR0004444 AR0004550 Revision: Feb 2012 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name Type of product BIO-CLEAN liquid disinfectant Perfumed, coloured disinfectant for aircraft toilets Use 1.2. Relevant identified uses of the substance or mixture and uses advised against Industrial. See the data sheet for detailed information. 1.3. Details of the supplier of the safety data sheet Supplier P.S.A. 19, rue Georges Bidault 77183 Croissy Beaubourg, France Tel: 0033 (0) 1.64.11.33.22. Fax: 0033 (0) 1.64.11.30.64 e-mail: psa@psa-paris.com 1.4. Emergency telephone number INRS 00 33 1 45 42 59 59 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or the mixture Classification EC 67/548 or EC 1999/45 Not regulated. Risk class and category of the Regulatory Code 1272/2008/EC CLP) Not regulated. 2.2. Label elements Labelling EC 67/548 or EC 1999/45 Symbol(s): Labelling Regulation 1272/2008/EC (CLP) Hazard pictogram code: / Safety phrases: / 2.3. Other hazards None under normal conditions. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Substance/Preparation: Preparation. This product is not considered hazardous but contains hazardous ingredients. (PSA-FDS01-05) Bioclean 360 1/5
Name of the substance Value(s) CAS No. EINECS EC Index REACH Classification No. Isopropyl alcohol < 5% 67-63-0 200-661-7 603-117-00-0 01-2119457558-25 F; R11 R67 Xi; R36 Flam. Liq. 2; H222a Eye Irrit 2 STOT RE 3 Compounds of the quaternary ammonium ion, alkyl in C8- C18 benzyl dimethyl, chlorides <= 1% 63449-41-2 264-151-6 612-140-00-5 / Xn; R21/22 C; R34 N; R50 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures First aid - Inhalation: None - Contact with skin: Rinse with water - Contact with eyes: Rinse with water. Seek medical advice if pain, blinking, lacrimation or redness persist. - Ingestion: Rinse mouth. Seek medical attention if the patient becomes unwell. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Emergency medical treatment: Symptomatic treatment. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Adequate: Dry chemicals. Carbon dioxide. Alcohol-based foam. 5.2. Specific hazards arising from the substance or mixture 5.3. Advice for firefighters Flammability class Non-flammable. Special procedures Do not allow run-off water from fire fighting to contaminate the environment. Be careful when tackling any chemical fire. Neighbouring fires Cool exposed containers by spraying or a water mist. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Individual precautions In case of repeated or prolonged contact, wear gloves. 6.2. Precautions for the environment Precautions for the environment Do not allow product to enter drains or fresh water supplies. Notify the authorities if the liquid enters drains or public water supplies. 6.3. Methods and material for containment and cleaning up Measures after leak/spread Clean any spillage as soon as possible, by collecting it with an absorbent product. Contain and recover large spillages by mixing with inert granular solids. Use an appropriate container to avoid any contamination of the immediate environment. Do not allow product to enter drains or fresh water supplies. (PSA-FDS01-05) Bioclean 360 2/5
6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling General The handling and storage of this product do not require any special precautions. Handling In case of contact with eyes, rinse immediately. Handle the product according to good industrial hygiene and safety procedures. If contact with eyes or skin is possible, wear suitable protection. Wash hands and any other exposed areas with mild soap and water before eating, drinking, smoking, and before leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage Do not store in a metal that is likely to corrode. Protect from frost. 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Individual protection - Respiratory protection: Not required. - Skin protection: If repeated contact with the skin is possible, wear protective clothing. - Eye protection: Eye protection is not necessary unless there is a risk of splashing or spraying with the liquid. - Hand protection: In case of repeated or prolonged contact, wear gloves - Ingestion: Do not eat, drink or smoke during use. 8.2. Occupational exposure limits SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on the basic physical and chemical properties Appearance liquid Colour blue Odour perfumed ph about 7 Initial boiling point approximately 100 Flash point Not applicable Density 1.00 +/- 0.03 Solubility in water complete Spontaneous ignition temperature not applicable 9.2. Other information SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions Hazardous reactions: None under normal conditions. Hazardous properties: None under normal conditions. (PSA-FDS01-05) Bioclean 360 3/5
10.4. Conditions to avoid Conditions to avoid: Storage in a metal likely to corrode (risk of attack by rust). Frost. 10.5. Incompatible materials Incompatible materials: Strong acids, bases 10.6. Hazardous decomposition products Hazardous decomposition products: None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Acute toxicity - Inhalation: Not considered harmful by inhalation in normal conditions of use. - Skin: Not considered particularly harmful in contact with skin in normal conditions of use. - Eyes: May cause minor eye irritation on contact. - Ingestion: Not considered particular hazardous if ingested in normal conditions of use. Sensitisation In the framework of the regulation (EC) 648/2004 concerning detergents, this product contains small quantities of allergenic fragrances known to cause skin sensitisation in humans. D-limonene, Cinnamyl alcohol, Citral 0.01% or more but less than 0.1%. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity For the product No hazards for water treatment plants in normal conditions of use. Avoid release into the environment (except when the product is used normally). 12.2 Persistence and degradability Biodegradation (%): 12.3. Bio-accumulation potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment The product does not contain any PBT or vpvb substance known to date. 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste residues Avoid release into the environment. Dispose of the product according to local regulations. SECTION 14: TRANSPORT INFORMATION 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) (PSA-FDS01-05) Bioclean 360 4/5
14.4. Packing group 14.5. Environmental hazards 14.6. Special precautions for user Stop the engine. No naked flames. Do not smoke. Signal the hazard and warn other road users. 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Ensure adherence to all national or local regulations. Symbol(s) R Phrase(s) S Phrase(s) Labelling of biocides in accordance with 98/8/EC Quaternary ammonium compounds, benzyl C8-18-alkyldimethyl, chlorides: 10g/Kg TP2 Labelling of detergents sold to the general public - Cationic surfactant. Less than 5%. - In the framework of the regulation (EC) 648/2004 concerning detergents, this product contains small quantities of allergenic fragrances known to cause skin sensitisation in humans.d-limonene, Cinnamyl alcohol, Citral 0.01% or more but less than 0.1%. 15.2. Chemical safety assessment SECTION 16: OTHER INFORMATION Other data: The risk phrases quoted in this document are the following: R11: Highly flammable R21/22: Harmful by contact with skin and if swallowed. R34: Causes burns. R36: Irritating to eyes. R50: Very toxic to aquatic organisms. R67: Vapours may cause drowsiness and dizziness. This sheet completes the technical instructions for use, but does not replace them. The information it contains is based on the state of our knowledge relating to the product concerned, on the date this sheet was published. It is given in all good faith. Under no circumstances does it relieve the user of his obligation to understand and apply all the regulations governing his activity. He will take sole responsibility for the precautions linked to use, of which he is aware. Moreover, the attention of users is drawn to the possible risks run if the product is used for purposes other than those for which it was designed. (PSA-FDS01-05) Bioclean 360 5/5