SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Material number : 000000000001038742 Manufacturer or supplier's details Company : Zep Inc. Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Telephone : 404-352-1680 Emergency telephone numbers For SDS Information : Compliance Services 1-877-428-9937 For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour liquid yellow-orange like fruit GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H315 Causes skin irritation. H319 Causes serious eye irritation. : Prevention: P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ 1 / 10
attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC ACGIH OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration [%] sodium dodecylbenzenesulfonate 25155-30-0 >= 7.9 - < 10 Sodium laureth (n=>3) sulfate 9004-82-4 >= 2.2 - < 2.9 Alcohols, C9-11, ethoxylated 68439-46-3 >= 1.5 - < 2.3 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. : If in eyes, rinse with water for 15 minutes. Remove contact lenses. Protect unharmed eye. 2 / 10
Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products Specific extinguishing methods Further information Special protective equipment for firefighters : Carbon dioxide (CO2) Carbon monoxide Smoke : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Standard procedure for chemical fires. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. For safety reasons in case of fire, cans should be stored separately in closed containments. : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. : Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Prevent spreading over a wide area (e.g. by containment or oil barriers). : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 3 / 10
SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage Materials to avoid : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. : No materials to be especially mentioned. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Ensure that eyewash stations and safety showers are close to the workstation location. Tightly fitting safety goggles : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour : liquid : yellow-orange : like fruit 4 / 10
Odour Threshold ph : 8-9.5 Melting point/freezing point Boiling point : : : Flash point : > 200 C Method: closed cup Evaporation rate Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density : 1.028 Density Solubility(ies) Water solubility Solubility in other solvents : : : : : : soluble : not determined Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition : : not determined : SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid : Stable No decomposition if stored and applied as directed. : Stable under normal conditions. No decomposition if stored and applied as directed. : No decomposition if stored and applied as directed. : Incompatible materials Hazardous decomposition products : None. : No decomposition if stored normally. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity 5 / 10
Acute oral toxicity : Acute toxicity estimate : 4,086 mg/kg Method: Calculation method Components: sodium dodecylbenzenesulfonate: Acute oral toxicity : LD50 Oral rat: 438 mg/kg Alcohols, C9-11, ethoxylated: Acute oral toxicity : LD50 Oral rat: 1,400 mg/kg Skin corrosion/irritation Remarks: Irritating to skin. Serious eye damage/eye irritation Remarks: Severe eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity sodium dodecylbenzenesulfonate: Sodium laureth (n=>3) sulfate: Alcohols, C9-11, ethoxylated: STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Remarks: 6 / 10
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Partition coefficient: n- octanol/water Mobility in soil Other adverse effects Regulation Remarks Additional ecological information : Remarks: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). : SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL 7 / 10
Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: IATA (Cargo Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 SARA 313 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA DSL AICS NZIoC PICCS IECSC On TSCA Inventory not determined not determined not determined not determined not determined Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) 8 / 10
Health Instability SAFETY DATA SHEET SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: 2 1 0 HEALTH FLAMMABILITY 3 1 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic OSHA GHS Label Information: Hazard pictograms : Signal w ord : Warning: Hazard statements : Causes skin irritation. Causes serious eye irritation. Precautionary statements : Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Wear protective gloves. Response: IF ON SKIN: Wash w ith plenty of soap and w ater. IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.0 Revision Date: 06/10/2015 Print Date: 01/25/2018 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep, Zep Commercial,Zep Professional, Enforcer, National Chemical, Selig, Mis ty, Next Dimension, Petro, i-chem, TimeMist, TimeWick, MicrobeMax, Country Vet, Konk, Original Bike Spirits, Blue Coral, Black Magic, Rain-X, Niagara National, FC Forward Chemicals,Rexodan, Mykal, and a number of private labeled brands. 9 / 10
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