AUTOL Hydrauliköl BIO HVI 46 Page 1 of 5 Section 1. Identification of the substance/mixture and of the company/undertaking. 1.1 Product identifier: Trade name: AUTOL Hydrauliköl BIO HVI 46 1.2 Relevant identified uses of the substance or mixture and uses advised against: Application of the substance/ the preparation: Lubricant for industrial use, hydraulic oil 1.3 Details of the supplier of the Eni Schmiertechnik GmbH Safety Data Sheet, Paradiesstr. 14, 97080 Würzburg Manufacturer/supplier: TEL. (+ 49) 931-900 98-0 FAX (+ 49) 931-98442 Advising/Support: Technical Department, Tel. (+49) 931 900 98-145 technik.wuerzburg@agip.de www.enischmiertechnik-datenblaetter.de Section 2. Hazards identification. 2.1 Classification of the substance or mixture: Classification according to Regulation (EC) No. 1272/2008: Classification according to Directive 67/548/EEC or Directive 1999/45/EC: The substance is not classified according to the CLP regulation. Information concerning particular The product does not have to be labelled due to the calculation procedure of the hazards for human and environment: General Classification Guideline for preparations of the EU in the latest version. Classification system: 2.2 Label elements: Labelling according to Regulation (EC) No. 1272/2008: Hazard pictograms: Signal word: Hazard statements: 2.3 Other hazards: Results of PBT and vpvb assessment: PBT: vpvb: The classification is according to the latest editions of the EU lists, and extended by company and literature data. Section 3. Composition/information on ingredients. 3.1 Chemical characterization: Substances CAS No. Description: 3.2 Chemical characterization: Mixtures Description: Dangerous components: Esters of fatty acids Mixture of substances listed below with non-hazardous additions. Additional information: For the wording of the listed risk phrases refer to section 16. Section 4. First aid measures. 4.1 Description of first aid measures: After inhalation: After skin contact: After eye contact: After swallowing: Supply fresh air; consult doctor in case of complaints. Immediately wash with water and soap and rinse thoroughly. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for medical help immediately.
AUTOL Hydrauliköl BIO HVI 46 Page 2 of 5 4.2 Most important symptoms and effects, both acute and delayed: 4.3 Indication of any immediate medical attention and special treatment needed: Gastric or intestinal disorders Section 5. Fire fighting measures. 5.1 Extinguishing media: Suitable extinguishing agents: For safety reasons unsuitable extinguishing agents: 5.2 Special hazards arising from the substance or mixture: 5.3 Advice for fire fighters: Protective equipment: Additional information: Section 6. Accidental release measures. CO 2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Water with full jet. Wear self-contained respiratory protective device. 6.1 Personal precautions, protective equipment and emergency procedures: Wear protective clothing. Cool endangered receptacles with water spray. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6.2 Environmental precautions: Do not allow to enter sewers/surface or ground water. 6.3 Methods and material for Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, containment and cleaning up: sawdust). Dispose of the material collected according to regulations. 6.4 Reference to other sections: See section 7 for information on safe handling. See section 8 for information on personal protection equipment. See section 13 for disposal information. Section 7. Handling and storage. 7.1 Precautions for safe handling: Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air). No special measures required. Store in cool, dry place in tightly closed receptacles. Information about fire and explosion protection: Protect against electrostatic charges. 7.2 Conditions for safe storage, including any incompatibilities: Storage: Requirements to be met by storerooms and receptacles: Information about storage in one common storage facility: Further information about storage conditions: Provide solvent resistant, sealed floor. Section 8. Exposure controls/personal protection. Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters: Ingredients with limit values that require monitoring at the workplace: Additional information: Store away from foodstuff. Store away from oxidizing agents. Protect from frost. Store in cool, dry conditions in well-sealed receptacles. The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. The lists valid during the making were used as basis.
8.2 Exposure controls: Personal protective equipment: General protective and hygienic measures: Respiratory protection: AUTOL Hydrauliköl BIO HVI 46 Page 3 of 5 The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Not necessary if room is well-ventilated. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: Recommendation: Chemical resistant protective gloves (EN 374) Material of gloves: Penetration time of glove material: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. The exact breakthrough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses. Use safety glasses according to EN 166 : 2001. Section 9. Physical and chemical properties. 9.1 Information on basic physical and chemical properties: General information: Appearance: Form: Fluid Colour: Clear Odour: Characteristic Odour threshold: ph value: Change in condition: Melting point/range: < 0 C Boiling point/range: Undetermined Flashpoint: 270 C Flammability (solid, gaseous): Ignition temperature: Decomposition temperature: Self-igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower/upper: Vapour pressure at 20 C: < 1 hpa Density at 20 C: 0,918 g/cm³ Relative density: Vapour density: Evaporation rate: Solubility in/miscibility with water: Not miscible or difficult to mix Partition coefficient (n-octanol/water): Viscosity: Dynamic: Kinematic: 43 mm/s Solvent content: Organic solvents: 0,0 % 9.2 Other information: No further relevant information available
Section 10. Stability and reactivity. AUTOL Hydrauliköl BIO HVI 46 Page 4 of 5 10.1 Reactivity: Reacts with strong oxidants and strong reducing agents under severe heat. 10.2 Chemical stability: Thermal decomposition/ conditions to be avoided: No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions: Reacts with strong oxidizing agents. 10.4 Conditions to avoid: Temperatures above 60 C can lead to reduced shelf life of the product. 10.5 Incompatible materials: 10.6 Hazardous decomposition Emergence of flammable gases/vapours on contact with strong oxidizing agents products: possible. Section 11. Toxicological information. 11.1 Information on toxicological effects: Acute toxicity: Primary irritant effect: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitization: Additional toxicological information: May cause skin irritation after repeated contact. May cause slight irritation to the eyes. No sensitizing effects known. the product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. Section 12. Ecological information. 12.1 Toxicity: Aquatic toxicity: The product meets the requirements of the European Ecolabel and the German ecolabel Blauer Engel. 12.2 Persistence and degradability: The product meets the requirements of the European Ecolabel and the German ecolabel Blauer Engel. 12.3 Bioaccumulative potential: 12.4 Mobility in soil: Additional ecological information: General notes: 12.5 Results of PBT and vpvb assessment: PBT: vpvb: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 12.6 Other adverse effects: Section 13. Disposal considerations. 13.1 Waste treatment methods: Recommendation: Uncleaned packaging: Recommendation: Must be specially treated adhering to official regulations. Disposal must be made according to official regulations. Section 14. Transport information. 14.1 UN-Number:
AUTOL Hydrauliköl BIO HVI 46 Page 5 of 5 14.2 UN proper shipping name: 14.3 Transport hazard class(es): Class: 14.4 Packaging group: ADR, IMDG, IATA: 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user: 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: UN Model Regulation : -- Section 15. Regulatory information. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture: Labelling according to Regulation (EC) No. 1272/2008: Hazard pictograms: Signal word: Hazard statements: 15.2 Chemical safety assessment: A chemical Safety Assessment has not been carried out. Section 16. Other information. The information contained in this safety data sheet is based on our current information level. It does not give assurance for certain product properties and does not establish a contractual relationship. This information relates only to the specific material and may not be valid if the material is used in combination with any other material or in any process. Revised: 3, 6, 7, 9, 11, 12, 15