SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Company : Eckart GmbH Guentersthal 4 91235 Hartenstein Telephone : +499152770 Telefax : +499152777008 E-mail address : msds.eckart@altana.com Responsible/issuing person 1.4 Emergency telephone number GBK Gefahrgut Büro GmbH, Ingelheim, Germany: From outside US: : (001) 352-323-3500 (First call in English, response in your language is possible) US & Canada (toll free) : 1-800-5355-053 SECTION 2: Hazards identification GHS Classification : Flammable liquids, Category 3, H226 Skin irritation, Category 2, H315 Eye irritation, Category 2A, H319 GHS-Labelling Page 1 / 14 102000021045
Symbol(s) : Signal word : Warning Hazard statements : H226: Flammable liquid and vapour. H315: Causes skin irritation. H319: Causes serious eye irritation. Precautionary statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Response: P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Hazardous components which must be listed on the label SECTION 3: Composition/information on ingredients Hazardous components Chemical Name CAS-No. EINECS-No. propane-1,2-diyl diacetate 623-84-7 210-817-6 Page 2 / 14 102000021045 Classification and Concentrati labelling on[%] Flam. Liq.;4;H227 10-30
3-methoxy-3-methylbutan-1-ol 56539-66-3 260-252-4 Flam. Liq.;4;H227 Acute Tox.;5;H303 Skin Irrit.;3;H316 Eye Irrit.;2A;H319 10-30 3-butoxypropan-2-ol 5131-66-8 225-878-4 Flam. Liq.;4;H227 ;2;H315 ;2;H319 10-30 3-methoxy-3-methylbutan-1-ol 56539-66-3 260-252-4 Flam. Liq.;4;H227 Acute Tox.;5;H303 Skin Irrit.;3;H316 Eye Irrit.;2A;H319 10-30 Dipropyleneglycoldimethylether 111109-77-4 Flam. Liq.;4;H227 5-10 ethyl acetoacetate 141-97-9 205-516-1 Flam. Liq.;4;H227 Acute Tox.;5;H303 1-5 aluminium 7429-90-5 231-072-3 Flam. Sol.;1;H228 1-5 ethanol 64-17-5 200-578-6 Flam. Liq.;2;H225 Eye Irrit.;2A;H319 1-5 For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: First aid measures 4.1 Description of first aid measures Page 3 / 14 102000021045
General advice If inhaled In case of eye contact If swallowed : No hazards which require special first aid measures. : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : Remove contact lenses. If eye irritation persists, consult a specialist. : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1 Extinguishing media 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Special protective equipment for firefighters : Wear self contained breathing apparatus for fire fighting if necessary. Further information : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Page 4 / 14 102000021045
SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions 6.3 Methods and materials for containment and cleaning up Methods for cleaning up 6.4 Reference to other sections : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Hygiene measures : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. : Normal measures for preventive fire protection. : General industrial hygiene practice. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Electrical installations / working materials must comply with the technological safety standards. Advice on common storage Other data : No materials to be especially mentioned. : No decomposition if stored and applied as directed. Page 5 / 14 102000021045
7.3 Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1 Control parameters 8.2 Exposure controls Personal protective equipment Eye protection : Safety glasses Skin and body protection : Protective suit Respiratory protection : No personal respiratory protective equipment normally required. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : silver Odour : characteristic ph : Freezing point : : 170 C Flash point : 54 C Page 6 / 14 102000021045
Bulk density : Flammability (solid, gas) : Auto-flammability : Upper explosion limit : Lower explosion limit : Vapour pressure : Density : Water solubility : Miscibility with water : immiscible Solubility in other solvents : Partition coefficient: n-octanol/water : Auto-ignition temperature : Thermal decomposition : Viscosity, dynamic : Viscosity, kinematic : Flow time : 9.2 Other information SECTION 10: Stability and reactivity 10.1 Reactivity No decomposition if stored and applied as directed. 10.2 Chemical stability No decomposition if stored and applied as directed. Page 7 / 14 102000021045
10.3 Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions. 10.4 Conditions to avoid Conditions to avoid : 10.5 Incompatible materials Materials to avoid : 10.6 Hazardous decomposition products Hazardous decomposition products Other information : : SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitisation Carcinogenicity Page 8 / 14 102000021045
Toxicity to reproduction/fertility Reprod.Tox./Development/Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Product SECTION 12: Ecological information 12.1 Toxicity Page 9 / 14 102000021045
12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Product: Additional ecological information : SECTION 13: Disposal considerations 13.1 Waste treatment methods Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. Page 10 / 14 102000021045
SECTION 14: Transport information 14.1 UN number ADR : 1210 CN_DG : 1210 TDG : 1210 CFR : 1210 IMDG : 1210 IATA : 1210 14.2 Proper shipping name ADR : PRINTING INK CN_DG : PRINTING INK TDG : PRINTING INK CFR : PRINTING INK IMDG : PRINTING INK IATA : PRINTING INK 14.3 Transport hazard class ADR : 3 CN_DG : 3 TDG : 3 CFR : 3 IMDG : 3 IATA : 3 14.4 Packing group ADR Packaging group : III Page 11 / 14 102000021045
Classification Code : F1 Hazard identification No : 30 Labels : 3 Tunnel restriction code CN_DG Packaging group : (D/E) : III Labels : 3 TDG Packaging group : III Labels : 3 CFR Packaging group : III Labels : 3 IMDG Packaging group : III Labels : 3 EmS Number IATA Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (LQ) Packaging group : F-E, S-D : 366 : 355 : Y344 : III Labels : 3 14.5 Environmental hazards Page 12 / 14 102000021045
14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment SECTION 16: Other information Full text of H-Statements H227 Combustible liquid H227 Combustible liquid H303 May be harmful if swallowed. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H227 Combustible liquid H315 Causes skin irritation. H319 Causes serious eye irritation. H227 Combustible liquid H303 May be harmful if swallowed. H316 Causes mild skin irritation. H319 Causes serious eye irritation. Page 13 / 14 102000021045
H227 H227 H303 H228 H225 H319 Combustible liquid Combustible liquid May be harmful if swallowed. Flammable solid. Highly flammable liquid and vapour. Causes serious eye irritation. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 14 / 14 102000021045