Revised edition: 13.03.2013 1. 1. 1. Version: 5.01 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Iron Oxide Black, brownish black 1. 2. Article No.: 48442 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent (pigment and dyes), inorganic. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2
2. 3. 3. 3. 1. 3. 2. Composition/Information on Ingredients Substance Mixture Page 2 Dust may be produced when working with this material, which can cause a mechanical irritation of eyes, nose and respiratory tract. Chemical Characterization: Pigment Black 11. 77499, Fe2O3 (CAS No. 1317-61-9); REACH Reg. No. 01-2119457646-28-0000 Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: No special measures required. Supply fresh air. If required give artificial respiration. In case of complaints or unconsiousness consult a physician. In case of unconsciousness place patient stable in side position for transportation. In case of unconsciousness place patient stable in side position for transportation. Keep the airways open. Unfasten tight garments (collar, tie, belt). No special measures required. Remove contact lens. Rinse open eyes with plenty of water (10-15 min). Should irritation continue, seek medical advice. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed No special measures required. Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Foam, carbon dioxide (CO2), extinguishing powder, water spray. Unsuitable extinguishing media: 3
None known. 5. 2. Special Hazards arising from the Substance or Mixture Page 3 5. 3. Special hazards: Advice for Firefighters Protective equipment: No special hazards. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Ensure adequate ventilation. Floor may be slippery; use care to avoid falling. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. Contact local authorities if product pollutes soil or vegetation. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Clean up mechanically. Transfer liquids and solid diking material to separate suitable containers for recovery or disposal. In case of emergency, see Section 1. Protective clothing, see Section 8. See Section 13 for information on disposal. No special measures necessary if properly handled. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store dry and in the original tightly sealed containers. No special measures necessary. No special measures necessary. 4
Storage class (VCI): 13; Non combustible solids Page 4 7. 3. Further Information: Specific End Use(s) 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): DNEL/DMEL: 10 mg/m3 (worker, inhalation, long-term exposition - systemic effects) 10 mg/m3 (worker, inhalation, long-term exposition - local effects) 8. 2. Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Environmental precautions: Workplace Exposure Limit (WEL): The user must take precautions to ensure that the environmental controls employed are adequate to maintain the exposure level below the WEL. Ensure adequate ventilation, especially in confined areas. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Wash contaminated clothes before reuse. Dust mask. Protective gloves (EN 374) Safety glasses with protective shields (EN 166). Protective clothing. Emissions from ventilation or work process equipment should be 5
9. 9. 1. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Form: powder Color: black Odor: odorless Odor threshold: ph-value: 4-8 (5 % w/w) Melting temperature: > 1000 C (> 1832 F) Boiling temperature: not available Flash point: not available Evaporation rate: Flammability (solid, gas): not available Upper explosion limit: not determined Lower explosion limit: not determined Vapor pressure: Vapor density: Density: 4.6 kg/l (20 C) Solubility in water: insoluble Coefficient of variation (n- Octanol/Water): no information available Auto-ignition temperature: Decomposition temperature: No data available. Viscosity, dynamic: 6
Explosive properties: Page 6 9. 2. 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: 300-1000 kg/m3 No further information. The product is stable. This material is considered to be stable. Avoid temperatures above 80 C: product can become i nstable and oxidize. Under unfavourable condtions, the additionally caused heat can lead to ignition of combustible materials nearby. Therefore, do not store the product near sources of heat. Avoid heat. None if stored and handled according to specifications. > 5000 mg/kg (rat) LD50, dermal: not determined 7
LC50, inhalation: Page 7 Primary effects 12. 12. 1. Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Non irritating Non-irritating to eyes Exposure to high ambient dust levels can cause irritation of the eyes. No information available No sensitizing effect (guinea pig). Not mutagenic (Ames Test) No data available. No data available. No data available. Chronic effects: Inhalation: Repeated or prolonged inhalation of dust can cause a chronic irritation of the respiratory tract. Fe3O4 LC0: > 10000 mg/l (96h, Brachydanio rerio) EC0: > 10000 mg/l (48h, Daphnia magna) no information available Algae toxicity: 12. 2. Persistency and Degradability 8
12. 3. Bioaccumulation 12. 4. Mobility 12. 5. Results of PBT- und vpvp Assessment Not applicable. 12. 6. Other Adverse Effects Page 8 Water hazard class: Not hazardous. Behaviour in sewage systems: Further ecological effects: No special effects or hazards known. 13. 13. 1. AOX Value: Disposal Considerations Waste Treatment Methods Product: If possible reuse product. Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Hazard no.: 9
Page 9 EmS No.: IATA Class: Hazard no.: 14. 4. Packaging Group ADR/RID: 14. 5. 14. 6. IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations. 14. 7. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code 14. 8. 15. Further Information Regulatory Information Not classified as a dangerous good under transport regulations. Do not store together with foodstuffs. 15. 1. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Not applicable. EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: 15. 2. 15. 3. 16. Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.