Identification of the substance/preparation and of the company/undertaking Product name: DOLIT 788 Solution Product no.: 94070025 Use of the substance/the preparation: Binding agent in furan resin mortar Manufacturer/supplier: CRS Chemieschutz GmbH Bachstrasse 38 D - 53639 Königswinter Germany Information can be obtained under: Phone: +49-2223-928400 Fax.: +49-2223-928461 E-mail: info@crs-chemicalcare.com Emergency phone number: (001) 3523233500 EMTEL-Customer ID: 99496 Revised on: 05.11.2008 2. Hazards identification: Classification: Xn harmful Information pertaining to special danger for human and environment: Harmful by inhalation, in contact with skin and if swallowed. 3. Composition/Information on ingredients Chemical properties Furan resin in solvent Hazardous ingredients: Chem. name: Furfuryl alcohol Phenol EG-no.: 202-626-1 203-632-7 REACH-no.: - - - - - - Index-no.: 603-018-00-2 605-001-00-5 CAS-no.: 98-00-0 108-95-2 Weight % ca. 45 < 0,4 Symbol Xn T R-phrases 20/21/22 23/24/25-48/20/21/22-34-68 The wording of the stated hazard information can be taken from chapter 16. Page 1 of 6
4. First aid measures General notes: Remove immediately all contaminated clothing. In case of irregular breathing or respiratory standstill apply artificial respiration. In case of inhaling: Remove immediately all contaminated clothing. In case of irregular breathing or respiratory standstill apply artificial respiration. In case of skin contact: Wash immediately with water and soap and rinse thoroughly. In case of eye contact Rinse eyes under running water at open lid for several minutes. Seek medical advice. In case of ingestion: Rinse mouth and drink plenty of water afterwards. Seek medical advice immediately. 5. Fire fighting measures Suitable extinguishing media: CO 2, Dry extinguishing media or water spray jet. Fight larger fire with water spray jet or alcohol resistant foam. Unsuitable extinguishing media because of safety reasons: Full jet water. Special exposures by the material or the product itself, its combustion products or developing gases: At combustion carbon monoxide (CO) may be released. Under certain combustion conditions traces of toxic substances cannot be excluded, such as formaldehyde. Special protective equipment for fire fighting: Wear full protective clothing. Use respiratory equipment. Additional notes: Collect contaminated water used for fire fighting separately, do not empty into drains. Combustion residues and contaminated water must be disposed according to regulations of the local authorities. 6. Accidental release measures Personal precautions: Wear protective equipment. Keep away unprotected persons. Environmental precautions: Avoid intrusion into drains, trenches and basements. In case of intrusion into waters or the public drainage system notify the local authorities Methods for cleaning up: Collect with suitable fluid binding agents (e.g. sand, mountain flour, sawdust, universal binding agent). Dispose contaminated material as waste according to point 13. Provide sufficient ventilation. Page 2 of 6
7.Handling and storage Advices on safe handling: Provide sufficient ventilation/exhaustion at work place. Store cool and dry in well closed containers. Open and handle containers with care. Precautions against fire and explosion: Keep away from ignition sources do not smoke. Take measures against electro static loads. Storage: Technical measures and storage conditions: Store containers in dry and well ventilated rooms. Additional information on storage conditions: Storage class: 6.1A (flammable, toxic material, VCI concept) 8. Exposure controls / personal protection Exposure limit values Type of limit value: Work material: Limit value: CAS-no.: Remarks: AGW TRGS 900 (D) Furfuryl alcohol 5 ppm (20 mg/m³) 98-00-0 skin resorbing AGW TRGS 900 (D) Phenol 10 ppm (41 mg/m³) 108-95-2 skin resorbing Personal protective equipment: (see also "Branchenregelung Säurebau" (Trade rules for acid protection construction)) General protection and hygiene measures: Do not breathe gases/vapours/aerosols. Avoid skin contact and eye contact. Take off contaminated and soaked cloths immediately. Wash your hands prior to breaks and at end of shift. Use skin protection ointment. Respiratory protection: Not required at sufficient room ventilation. Hand protection: Plastic gloves. (butyl rubber, nitrile rubber). The exact permeation time can be obtained from the manufacturer of the protective gloves and must be observed. Eye protection: Safety goggles Body protection: Occupational protective wear Page 3 of 6
9. Physical and chemical properties Appearance Colour Odour liquid dark brown after furfuryl alcohol Boiling point ( C): 100-200 DIN 53 171 Flash point ( C): ~ 80 ISO 2719 Ignition temperature ( C): > 390 DIN 51 794 Explosion limits (Vol%): lower: 1.8 upper: 16.3 Steam pressure (mbar) at 20 C: ~0.53 Density (g/cm³) at 20 C: ~ 1.1 Viscosity at 23 C: 400-800 DIN 53 018 Water solubility: mixable ph value (at 200 g/l H 2 O): 4.5 10. Stability and reactivity Conditions to avoid: No degrading if used as instructed. Materials to avoid: Violent exothermal reaction with acids. Hazardous degrading products: Inflammable gases/vapours. 11. Toxicological information Acute toxicity: Acute toxicity: Material Species Value Remarks: LD 50 (oral) furfuryl alcohol Rat 88 mg/kg - - - LD 50 (dermal) furfuryl alcohol Rabbit 400 mg/kg - - - LC 50 ( 4 h ) furfuryl alcohol Rat 233 mg/l - - - LD 50 (oral) phenol Rat 414 - - - LD 50 (dermal) phenol Rabbit 669 - - - LC 50 ( 4 h ) phenol Rat 0.3 mg/l - - - Irritating/burning effect: In case of skin contact: Longer skin contact may cause irritation. In case of eye contact: Irritating. Page 4 of 6
12. Ecological information: General notes: Do not drain into ground water, waters or into public sewage system. 13. Disposal considerations: Disposal/waste (product): Dispose under observation of regulations from local authorities, e.g. transport to a suitable combustion plant. EAK/AVV waste codes: Allocation of the waste code has to be made according to regulations as specially required for processes and types in the industry. Appropriate packaging: Contaminated packages have to be emptied completely, following they can be recycled after appropriate cleaning. Containers with residues and which are not cleaned and contain residual substances according to GefstoffV or EU guideline, respectively, are not subject to the packaging regulations, but are classified as hazardous waste. Disposal according to regulations of the responsible authorities. 14. Transport information Land transport ADR/RID and GGVSE Class: 6.1 UN no.: 2810 Packing group: III Label:: 6.1 Substance designation: UN 2810 TOXIC LIQUID, ORGANIC MATERIAL, N.O.S. (Furfuryl alcohol) Sea ship transport IMDG/GGVSee Class: 6.1 UN no.: 2810 Packing group: III Label:: 6.1 EMS no.: F-A, S-A Marine pollutant: nein Proper technical name: TOXIC LIQUID, ORGANIC, N.O.S. Cause of hazards: (Furfuryl alcohol) Air transport ICAO-TI and IATA-DGR Class: 6.1 UN/ID-no: 2810 Packing group: III Proper shipping name: TOXIC LIQUID, ORGANIC, N.O.S., Cause of hazards: (Furfuryl alcohol) Page 5 of 6
15. Regulatory information EU regulations The product is classified and labeled according to EU guideline/gefstoffv. Hazard symbols and hazard designation: Xn harmful Hazard components for labeling: Furfuryl alcohol R phrases: R 20/21/22 Harmful by inhalation, when swallowing and at contact with skin S phrases: 26-28-36/37/39-60 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of contact with skin, wash immediately with plenty of water and soap. Wear suitable protective clothing, gloves and eye/face protection at work. This material and its container must be disposed of as hazardous waste. National regulations (Germany): Classification according to Betriebssicherheitsverordnung (Operational reliability) (BetrSichV): not applicable Water hazard class: WGK 2 (risk of water hazards) (according to appendix 4 VwVwS of 17.05.1999) Other regulations, restrictions and prohibition regulations. BG leaflet: BGI 621 "Solvents" (M 017) (ZH 1/319) Real protection measures and first aid measures for handling furan resins are documented in the "Branchenregelung Säureschutzbau" (Trade rules for acid protection construction)! 16. Other information: Relevant R phrases under section 3: R 20/21/22 R 23/24/25 R 34 R 48/20/21/22 R 68 Harmful by inhalation, when swallowing and at contact with skin Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin. Danger of non-reversible damages Editing division: Phone: 02223/928400 E-Mail.: info@crs-chemicalcare.com Page 6 of 6