Safety Data Sheet Compressed Gas, N.O.S. (Nitrogen, Hydrogen)

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Transcription:

Safety Data Sheet Compressed Gas, N.O.S. (, ) www.arc3gases.com Section 1: Product and Company Identification Arc3 Gases Arc3 Gases - North 1700 Chamberlayne Ave. Richmond, VA 23222 phone: (804) 388-0302 fax: (804) 788-8904 Arc3 Gases - South 1660 US Highway 301 South P.O. Box 1708 Dunn, NC 28335 phone: (910) 892-4016 fax: (910) 892-3575 Emergency contact: INFOTRAC 1-800-535-5053 Product Code: Compressed Gas, N.O.S. (, ) Synonyms: Balance, 5% Recommended Use: known Usage Restrictions: known Section 2: Hazards Identification Hazard Classification: Gases Under Pressure Warning Hazard Statements: Contains gas under pressure; may explode if heated Precautionary Statements Storage: Protect from sunlight. Store in well-ventilated place. Arc3 Gases page 1 of 6

Section 3: Composition/Information on Ingredients CAS # Concentration 7727-37-9 Balance 1333-74-0 5% Chemical Substance Chemical Trade Names Family NITROGEN, COMPRESSED GAS inorganic, gas DIATOMIC NITROGEN; DINITROGEN; NITROGEN; NITROGEN-14; NITROGEN GAS; UN 1066; N2 HYDROGEN inorganic, gas HYDROGEN GAS; HYDROGEN COMPRESSED; HYDROGEN (H2); DIHYDROGEN; UN 1049; H2 Section 4: First Aid Measures Skin Contact Eye Contact Ingestion Inhalation e to Physicians Wash exposed skin with soap and water. Wash exposed skin with soap and water. Flush eyes with plenty of water. Flush eyes with plenty of water. If a large amount is swallowed, get medical attention. If a large amount is swallowed, get medical attention. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. For inhalation, consider oxygen. For inhalation, consider oxygen. Section 5: Fire Fighting Measures Suitable Extinguishing Media Non-flammable. Use suitable extinguishing media for surrounding fire. Cylinders may rupture or explode if exposed to heat. Carbon dioxide, regular dry chemical Large fires: Flood with fine water spray. Products of Protection of Firefighters Combustion Non-flammable Respiratory protection may be needed for frequent or heavy exposure. None known Any self-contained breathing apparatus with a full facepiece. Any self-contained breathing apparatus with a full facepiece. Section 6: Accidental Release Measures Personal Precautions Environmental Precautions Methods for Containment Keep unnecessary people away, isolate hazard area and deny No significant effects from Stop leak if possible without entry. Stay upwind and keep out of low areas. contamination expected. personal risk. Keep unnecessary people away, isolate hazard area and deny Avoid heat, flames, sparks and Reduce vapors with water spray. entry. Do not touch spilled material. Ventilate closed spaces other sources of ignition. Remove sources of ignition. before entering. Methods for Cleanup Other Information N/A N/A Stop leak if possible without personal risk. None Arc3 Gases page 2 of 6

Section 7: Handling and Storage Handling Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Store and handle in accordance with all current regulations and standards. Grounding and bonding required. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Storage Keep separated from incompatible substances. Keep separated from incompatible substances. Section 8: Exposure Controls/Personal Protection Exposure Guidelines NITROGEN, COMPRESSED GAS: NITROGEN: ACGIH (simple asphyxiant) HYDROGEN: ACGIH (simple asphyxiant) Engineering Controls Handle only in fully enclosed systems. Eye Protection Skin Protection Respiratory Protection Eye protection not required, but recommended. Eye protection not required, but recommended. Protective clothing is not required. Protective clothing is not required. General Hygiene considerations Avoid breathing vapor or mist Avoid contact with eyes and skin Wash thoroughly after handling and before eating or drinking Section 9: Physical and Chemical Properties Respiratory protection may be needed for frequent or heavy exposure. Any self-contained breathing apparatus with a full facepiece. Physical State Appearance Color Change in Appearance Physical Form Odor Taste Gas Clear Colorless N/A Gas Odorless Tasteless Gas Colorless Colorless N/A Gas Odorless Tasteless Flash Point Flammability Partition Coefficient Autoignition Temperature Upper Explosive Limits Lower Explosive Limits flammable Nonflammable Nonflammable Nonflammable Flammable gas (burns at all 752 F (400 C) 0.75 0.04 ambient temperatures) Boiling Point -321 F (-196 C) -423 F (-253 C) Freezing Point -346 F (- 210 C) -434 F (- 259 C) Vapor Pressure 760 mmhg @ -196 C 760 mmhg @ -253 C Vapor Density 0.967 (Air=1) 0.07 (Air=1) Specific Gravity Water Solubility 1.6% @ 20 C 1.82% @ 20 C ph Odor Threshold Evaporation Rate Viscosity 0.01787 cp @ 27 C 0.008957 cp @ 26.8 C Molecular Weight Molecular Formula Density Weight per Gallon Volatility by Volume Volatility Solvent Solubility 28.0134 N2 1.2506 g/l 100% 1 Soluble: Liquid ammonia 2 H2 0.08987 g/l @ 0 C Soluble: Arc3 Gases page 3 of 6

Section 10: Stability and Reactivity Stability Conditions to Avoid Incompatible Materials Stable at normal Stable at normal Metals, oxidizing materials temperatures and temperatures and Stable at normal temperatures and Stable at normal temperatures and Metals, oxidizing materials, metal oxides, combustible materials, halogens, metal salts, halo carbons, nitrogen triflouride, oxygen diflouride, magnesium and calcium carbonate, sodium, potassium Hazardous Decomposition Products Possibility of Hazardous Reactions Oxides of nitrogen Will not polymerize. Miscellaneous decomposition products Will not polymerize. Section 11: Toxicology Information Acute Effects Oral LD50 Dermal LD50 Inhalation Nausea, vomiting, difficulty breathing, headache, drowsiness, dizziness, tingling sensation, loss of coordination, convulsions, coma Nausea, vomiting, difficulty breathing, irregular heartbeat, headache, fatigue, dizziness, disorientation, mood swings, tingling sensation, loss of coordination, convulsions, unconsciousness, coma Eye Irritation Skin Irritation Sensitization Contact with rapidly expanding gas may cause burns or frostbite No information on significant adverse effects Difficulty breathing irritating irritating Difficulty breathing Chronic Effects Carcinogenicity Mutagenicity Reproductive Effects Developmental Effects hazardous No data No data Section 12: Ecological Information Fate and Transport Eco toxicity Persistence / Degradability Bioaccumulation / Accumulation Mobility in Environment Fish toxicity: Invertibrate toxicity: Algal toxicity: Phyto toxicity: Other toxicity: Fish toxicity: Invertibrate toxicity: Algal toxicity: Phyto toxicity: Other toxicity: Section 13: Disposal Considerations Dispose in accordance with all regulations. Dispose in accordance with all regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Arc3 Gases page 4 of 6

Section 14: Transportation Information U.S. DOT 49 CFR 172.101 DOT Information For This Mixture Shipping Name Compressed gas, n.o.s. (, ) UN Number UN1956 Hazard Class 2.2 Hazard Information Non-Flammable Gas Individual Component Information Proper Shipping Name, compressed, compressed ID Number Hazard Class or Division Packing Group UN1066 2.2 UN1049 2.1 Labeling Requirements Passenger Aircraft or Railcar Quantity Limitations Cargo Aircraft Only Quantity Limitations 2.2 75 kg or L 150 kg N/A 2.1 Forbidden 150 kg None Additional Shipping Description Canadian Transportation of Dangerous Goods Shipping Name UN Number Class Packing Group / Risk Group, compressed UN1066 2.2, compressed UN1049 2.1 Section 15: Regulatory Information U.S. Regulations CERCLA Sections SARA 355.30 SARA 355.40 regulated. regulated. regulated. regulated. regulated. regulated. SARA 370.21 Acute Chronic Fire Reactive Sudden Release Yes No No No Yes Yes No Yes No Yes SARA 372.65 regulated. regulated. OSHA Process Safety regulated. regulated. State Regulations CA Proposition 65 regulated. regulated. Canadian Regulations WHMIS Classification A A, B1. Arc3 Gases page 5 of 6

National Inventory Status US Inventory (TSCA) TSCA 12b Export ification Canada Inventory (DSL/NDSL) Listed on inventory. listed. Listed on inventory. Listed on inventory. listed. Listed on inventory. Section 16: Other Information NFPA Rating HEALTH=1 FIRE=0 REACTIVITY=0 HEALTH=0 FIRE=4 REACTIVITY=0 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Arc3 Gases page 6 of 6