Date of last revision: 11/01/2010 Page: 1 of 5 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ADETEC ND 22 MANUFACTURER NAME: EMERGENCY PHONE: (011) 4158-8400 ADDRESS: Rua Ifema, 291 ZIP Code: 06730-000 Vargem Grande Paulista / SP 2 COMPOSITION AND INFORMATION ON INGREDIENTS PRODUCT CLASS: ADHESIVE CHEMICAL PREPARATION: R-Phrases: 10 ; 36/ 37/ 38 ; 43 HAZARDOUS INGREDIENTS CAS Number % in weight Risk Symbol Risk Phrases Lower than Methyl Ethyl Ketone 78-93-3 50 Xi 36/37/38 Epoxy Resin Proprietary 25 Not established 36/38; 43 Propylene Glycol Monoethyl Ether 107-98-2 30 Xn 10 3 HAZARD IDENTIFICATION SUMMARY OF THE MOST SIGNIFICANT HAZARDS Flammable liquid and vapor. Hazardous if inhaled. May cause allergenic reaction in the skin. Causes irritation to skin and eyes. Hazardous vapor, may affect the brain and nervous system, causing dizziness, headache or nausea. EFFECTS OF OVER EXPOSURE: Acute (short term) CONTACT WITH EYES May cause irritation to the eyes. CONTACT WITH SKIN May cause irritation or sensitization of the skin. May cause dermatitis. INHALATION May cause irritation of the respiratory system, as well as symptoms such as throat dryness and difficulty to breathe. May cause depression of the central nervous system, causing headache, dizziness, confusion, unconsciousness or coma. INGESTION Hazardous if swallowed. Ingestion is not an entry route expected in industrial or commercial use. CHRONIC RISKS (Long term): Repeated or extended contact with solvent may lead to permanent damage to the central nervous system. Contact with the skin may cause dermatitis.
Date of last revision: 11/01/2010 Page: 2 of 5 4 FIRST-AID MEASURES EMERGENCY AND FIRST-AID PROCEDURES: INHALATION: Move the person to a ventilated place. Restore and keep breathing. If it is difficult to breathe, use oxygen. Provide immediate medical attention. CONTACT WITH EYES: Wash the eyes immediately with plenty of running water for at least 15 minutes. Provide immediate medical attention. CONTACT WITH SKIN: Wash the affected area with plenty of water and then with water and soap, remove contaminated clothing. Consult a physician if symptoms occur. INGESTION Do not induce vomit. Provide the victim with one or two glasses of water or milk. Call a physician. Never give anything by the mouth to an unconscious person. 5 FIRE-FIGHTING MEASURES FLAMMABILTIY CLASSIFICATION: Flammable Liquid Class 3 (NBR 7500/87) FLASH POINT: > -3 o C (Setaflash Sealed Container) TYPES OF EXTINGUISHERS: Foam, CO2, Chemical Powder and Mist MEASURES AGAINST FIRE AND EXPLOSION: Flammable liquid and vapor. Keep packaging well sealed. Sealed packaging may rupture when exposed to extreme heating. Isolate from heat, electrical equipment, flames, sparks and other ignition sources. Use water to keep packaging cooled. SPECIAL PROCEDURES WHEN FIGHTING FIRE: Use complete protection equipment, including breathing apparel with cylinder, water spray may not be effective, mist-type system is preferable. During fire, toxic or irritating gases may be generated by thermal decomposition or combustion. 6 MEASURES FOR CONTROLLING ACCIDENTAL SPILLING OR LEAKAGE STEPS TO BE FOLLOWED IF MATERIAL IS SPILLED: Keep non-essential people away from the leakage area. Remove all ignition sources (flames, hot surfaces, electrical sparks etc.). Avoid breathing vapors, use breathing equipment (cylinders). Notify the authorities as required. Contain and remove with inert material keeping in a container for further disposal. Avoid contact. Check information contained in other sections of this. 7 HANDLING AND STORAGE HANDLING Keep packaging well sealed to avoid leakage. Avoid contact with eyes and skin. Avoid breathing vapors. Only handle the product after reading and understanding safety precautions. Empty packaging cannot be reused. Use with appropriate ventilation. Empty containers may have flammable wastes; therefore, keep away from fire and spark. Do not smoke where the product is stored. STORAGE Store only in well ventilated areas. Do not store close to heat or spark. Keep packaging sealed when not in use.
Date of last revision: 11/01/2010 Page: 3 of 5 8 EXPOSURE CONTROL AND INDIVIDUAL PROTECTION ENGINEERING CONTROLS: Good ventilation of the area should be kept to keep contaminant level below the recommended limits. Solvent vapors are heavier than the air and are concentrated in the lower portions of the working area. Enough ventilation; (explosion-proof equipment) should be used to prevent accumulation of flammable vapor. RESPIRATORY PROTECTION: Use respiratory protection equipment with filters designed to remove particle and organic vapor combination, if the occupational limits are exceeded, as presented in the section below and in the NR6 and NR15 associated with Work Safety and Medicine. For emergency situations, usage in confined space, or other conditions where exposure limits may be exceeded, use breathing equipment with approved air supply. SKIN PROTECTION: Use nitrile rubber or neoprene gloves to avoid contact with skin. EYE PROTECTION: Use safety glasses with side protection where spills of the product may occur. OTHER PROTECTION EQUIPMENT: Use disposable or waterproof clothing if working clothing contamination is probable. Use long-sleeved shirts to reduce skin exposure. HYGIENE PRACTICES: Wash the hands previously to eating, smoking or using the bathroom. Food or drink should not be consumed in the area where this product is stored. Thoroughly wash the hands after handling. Chemical Name CAS Number % weight Lower than Exposure Guide OSHA- PEL-TWA ACGIH- TLV-TWA Methyl Ethyl Ketone 78-93-3 50.0 1 100 150 Ppm Epoxy Resin proprietary 25.0 N.E. N.E. - Propylene Glycol Monoethyl Ether 107-98-2 30.0 100 100 Ppm Units OSHA US Occupational Safety and Health Administration PEL Permissible Exposure Limit ACGIH American Conference of Gov. Industrial Hygienists N.E. Not Established TLV: Threshold Limit Value TWA Time Weighted Average STEL Short-Term Exposure Limit 9 PHYSICAL-CHEMICAL PROPERTIES ASPECT White to yellowish liquid. BOILING RANGE: 79 120 o C VAPOR DENSITY: Heavier than the air EVAPORATION RATE: slower than the ether SELF-IGNITION TEMPERATURE: Not available FLASH POINT: > - 3 ºC (Setaflash sealed container) DENSITY: 0.900 TO 0.940 g/cm 3 SOLUBILITY IN WATER - Insoluble VAPOR PRESSURE: Not determined ph: Not Applicable VOLATILES BY VOLUME: 81.9% VOLATILES BY WEIGHT: 78.5% 10 STABILITY AND REACTIVITY
Date of last revision: 11/01/2010 Page: 4 of 5 CONDITIONS TO AVOID: High Temperatures, Ignition Sources. INCOMPATIBILITY: (materials to avoid): Heavy oxidants, acids, base, water. HAZARDOUS PRODUCTS IN DECOMPOSITION: Carbon Dioxide, Carbon monoxide. POLYMERIZATION RISK: Shall not occur under normal conditions. STABILITY: Stable under normal storage conditions. 11 TOXICOLOGICAL INFORMATION HEALTH HAZARDS GENERAL Extended and repeated contact with solvents for a long period may lead to permanent health problems. EXPOSURE ROUTES: INHALATION: Harmful by inhalation. May cause irritation of the respiratory system. INGESTION: Harmful if ingested. SKIN: Harmful in contact with the skin. EYES: Irritating to the eyes. There is no toxicological information available for the product. For the product components, the following toxicological information is known: Methyl Ethyl Ketone DL50 - Dermal (rabbit) CL50 - Inhalation (rats) 6480-13000 mg/kg 2400-3400 mg/kg Propylene Glycol Monoether Oral LD 50 (rats) 6.6 ml 12 ECOLOGIC INFORMATION There is no information available on environmental impact of this product. For the product components, the following ecologic information is known: MEK: AIR: Product vapors reduce concentration of oxygen rendering the environment toxic and extremely explosive. MEK is photochemically degraded forming hydroxyl radicals. Water: The product and contaminated water resulting from fire-fighting are damaging to the flora and fauna. The product is slowly biodegradable. Ground: Causes pollution of the ground and underground.
Date of last revision: 11/01/2010 Page: 5 of 5 13 CONSIDERATIONS ON TREATMENT AND DISPOSAL DISPOSAL METHOD: Disposal should be made in accordance with federal and state regulation. If the waste is determined as hazardous, one should obtain the due license for disposal. 14 INFORMATION ON TRANSPORTATION LAND TRANSPORTATION National Regulations: This product is deemed hazardous for transportation as per Ordinance 204 dated 05/20/97 of the Transport Department. NAME: ADHESIVE, containing flammable liquid RISK CLASS: 3 Flammable liquid No. ONU: 1133 EMERGENCY GUIDE: 127 International Regulations Maritime Route (code IMDG): No. ONU: 1133 Risk Class: 3 Packing Group: II Air Route (IATA): No. ONU: 1133 Risk Class: 3 Packing Group: II 15 INFORMATION ON REGULATION OSHA: Hazardous by definition of the Hazard Communication Standard (29 CFR 1910.1200) Inventory Status The chemical substances of this product are listed in Section 8 Inventory of the TSCA US-Toxic Substance Control Act Classification and labeling in accordance with the European Parliament Directive Proposal Risk Phrases: R-10 Flammable R20/21 Harmful by inhalation and in contact with skin R 36/37/38 Irritating to the eyes, respiratory tract and skin R-43 May cause sensitization in contact with skin Safety Phrases: S16 Keep away from any flame or spark source Do not smoke S24/25 Avoid contact with the skin S36/37 Use appropriate protective clothing and gloves S45 In case of accident or illness, immediately consult the physician (if possible, show him the label). S51 Use only in well ventilated places. 16 OTHER INFORMATION CLASSIFICATION HMIS (Hazardous Materials Identification System) HEALTH 2* FLAMMABILITY: 3 REACTIVITY: 0 VOLATILE ORGANIC COMPOUNDS (calculated): 689 grams/ liter The information of this represents the current data and precisely reflects our best knowledge for appropriate handling of this product under normal conditions and in accordance with application in the literature. Any other use of the product, involving combined use with other product/ process is the user s liability.