SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number 7887/21595 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Detergent. 1.3. Details of the supplier of the safety data sheet Supplier Cole & Wilson Ltd Nabbs Lane Chemical Works Nabbs Lane Slaithwaite Huddersfield HD7 5AT 01484 842353 info@coleandwilson.com 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Environmental hazards Acute Tox. 4 - H302 Eye Dam. 1 - H318 Not Classified 2.2. Label elements Pictogram Signal word Hazard statements Precautionary statements Danger H302 Harmful if swallowed. H318 Causes serious eye damage. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P330 Rinse mouth. P501 Dispose of contents/container in accordance with national regulations. 1/6
Contains ISOTRIDECANOL, ETHOXYLATED (>5-20EO) 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures ISOTRIDECANOL, ETHOXYLATED (>5-20EO) 15-30% CAS number: 69011-36-5 Classification Eye Dam. 1 - H318 Classification (67/548/EEC or 1999/45/EC) Xn;R22. Xi;R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Unlikely route of exposure as the product does not contain volatile substances. Never give anything by mouth to an unconscious person. Do not induce vomiting. Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Give milk instead of water if readily available. Get medical attention immediately. Remove contaminated clothing. Rinse immediately with plenty of water. Get medical attention promptly if symptoms occur after washing. Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse. 4.2. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact Eye contact This is unlikely to occur but symptoms similar to those of ingestion may develop. Harmful if swallowed. May cause stomach pain or vomiting. Skin irritation. Severe irritation, burning and tearing. 4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. If in doubt, get medical attention promptly. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products Thermal decomposition or combustion products may include the following substances: Oxides of the following substances: Carbon. Thermal decomposition or combustion products may include the following substances: Oxides of the following substances: Carbon. 5.3. Advice for firefighters Protective actions during firefighting If risk of water pollution occurs, notify appropriate authorities. Control run-off water by containing and keeping it out of sewers and watercourses. 2/6
Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. 6.2. Environmental precautions Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the Environmental Agency or other appropriate regulatory body. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Flush contaminated area with plenty of water. 6.4. Reference to other sections Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. Collect and dispose of spillage as indicated in Section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Avoid spilling. Wear suitable protective equipment for prolonged exposure and/or high concentrations of vapours, spray or mist. Avoid contact with skin and eyes. 7.2. Conditions for safe storage, including any incompatibilities Storage precautions Storage class Avoid freezing. Keep container tightly closed. Chemical storage. 7.3. Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection No specific ventilation requirements. The following protection should be worn: Chemical splash goggles. Wear protective gloves made of the following material: Neoprene. Nitrile rubber. Polyethylene. Polyvinyl chloride (PVC). Wear appropriate clothing to prevent any possibility of skin contact. Do not eat, drink or smoke when using this product. Respiratory protection must be used if the airborne contamination exceeds the recommended occupational exposure limit. 3/6
SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Liquid. Yellow. Characteristic. ph ph (concentrated solution): 6.0-8.0 Solubility(ies) Soluble in water. 9.2. Other information Other information Not determined. SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity The following materials may react with the product: Acids. Oxidising agents. Reducing agents. 10.2. Chemical stability Stability No particular stability concerns. 10.3. Possibility of hazardous reactions Possibility of hazardous reactions No potentially hazardous reactions known. 10.4. Conditions to avoid Conditions to avoid Avoid freezing. 10.5. Incompatible materials Materials to avoid Oxidising agents. Reducing agents. Acids. 10.6. Hazardous decomposition products Hazardous decomposition products Thermal decomposition or combustion products may include the following substances: Oxides of the following substances: Carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity - oral ATE oral (mg/kg) 1,672.22 Inhalation Ingestion Skin contact Eye contact Acute and chronic health hazards This is unlikely to occur but symptoms similar to those of ingestion may develop. Harmful if swallowed. Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal tract. Irritating to skin. Irritating to eyes. Symptoms following overexposure may include the following: Redness. Pain. Repeated exposure may cause chronic eye irritation. Mild dermatitis, allergic skin rash. SECTION 12: Ecological Information 4/6
Ecotoxicity Low acute toxicity to aquatic organisms. 12.1. Toxicity Toxicity Not considered toxic to fish. 12.2. Persistence and degradability Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them at their direct request, or at the request of a detergent manufacturer. 12.3. Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. 12.4. Mobility in soil Mobility The product is non-volatile. 12.5. Results of PBT and vpvb assessment Results of PBT and vpvb assessment This product does not contain any substances classified as PBT or vpvb. 12.6. Other adverse effects Other adverse effects None known. SECTION 13: Disposal considerations 13.1. Waste treatment methods Disposal methods Dispose of in accordance with Local Authority Regulations SECTION 14: Transport information 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) Transport labels 14.4. Packing group 14.5. Environmental hazards Environmentally hazardous substance/marine pollutant No. 14.6. Special precautions for user 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 5/6
SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). 15.2. Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Revision comments Revision is in accordance with Commission Regulation (EC) No 1272/2008 Revision date 05/05/2015 Revision 0 SDS number 7887/21595 Hazard statements in full H302 Harmful if swallowed. H318 Causes serious eye damage. 6/6