1. IDENTIFICATION OF PRODUCT AND COMPANY Productname : Application : Company : Electrofuge 200 avec traceur Aerosol Anti Corrosion Products Touwslagerstraat 1 9240 ZELE Belgium Tel.: (+32)(0)52/456011 Fax: (+32)(0)52/450034 E-mail : hse@crcind.com In case of emergency : (+32) (0)52/45 60 11 Subsidiaries Tel Fax CRC Industries Finland Asemanrinne 13, 08500 Lohja AS (+358)(0)19/32921 (+358)(0)19/383676 CRC Industries France 12, Bld des Martyrs de Chateaubriant F-95102 Argenteuil Cédex (+33)(0)1/34112000 (+33)(0)1/34110996 CRC Industries Deutschland Südring 9, 76473 Iffezheim (+49)(0)7229/3030 (+49)(0)7229/303266 CRC Industries Iberia Gremio del cuero S/N, 40195 Segovia (+34)921/427546 (+34)921/436270 CRC Industries Sweden Kryptongatan 14, 43153 Mölndal (+46)(0)31/7068480 (+46)(0)31/273991 2. HAZARD IDENTIFICATION Health and Safety : Environment : Other hazards : Extremely Flammable (DME propellant) Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. 1 / 7
3. COMPOSITION AND INFORMATION ON COMPONENTS Hazardous ingredient CAS-nbr. EINECS w/w % symbol R-phrases* Notes 2-(2-butoxyethoxy)ethanol; diethylene glycol monobutyl 112-34-5 203-961-6 <0.1 Xi 36 A ether dimethyl ether 115-10-6 204-065-8 30-60 F+ 12 A xylene 1330-20-7 215-535-7 <12.5 Xn 10-20/21-38 A ethyl acetate 141-78-6 205-500-4 5-10 F,Xi 11-36-66-67 B 2-octyl-2H-isothiazol-3-one 26530-20-1 247-761-7 <0.05 T,N 22-23/24-34-43-50/53 2-Propanol, 1-ethoxy-, acetate 54839-24-6 259-370-9 1-5 10-67 Naphtha (petroleum), hydrotreated light (benzene<0.1%) 64742-49-0 265-151-9 5-10 F,Xn,N 11-38-51/53-65-67 B,P butanone; ethyl methyl ketone 78-93-3 201-159-0 5-10 F,Xi 11-36-66-67 A Explanation notes A : substance with Community workplace exposure limit B : substance with national established workplace exposure limit P : not classified as carcinogen, less than 0.1% w/w benzene (Einecs-nr. 200-753-7) Note H and P of Annex I (67/548/EEC) apply for the naphtha's in this product. (* Explanation risk-phrases : see chapter 16) 4. FIRST AID MEASURES General Advice : Contact with eyes : Contact with skin : Inhalation : Ingestion : 5. FIRE-FIGHTING MEASURES Flash point (without propellant): < 0 C Explosion limits : upper limit : lower limit : If symptoms persist always call a doctor If substance has got into eyes, immediately wash out with plenty of water for several minutes Wash with water and soap. Seek medical attention if irritation persists Fresh air, keep warm and at rest. Seek medical attention if ill effects occur If swallowed accidentally, do not induce vomiting and seek medical advice. 2 / 7
Extinguishing media : Fire-fighting procedures : Unusual exposure hazard : 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Environmental precautions : Cleaning methods : 7. HANDLING AND STORAGE Handling procedures : Storage procedures : foam, carbon dioxide or dry agent Keep container(s) exposed to fire cool, by spraying with water May form explosive vapour/air mixtures Aerosols may explode if heated above 50 C Shut off all ignition sources Ensure adequate ventilation Do not allow to enter public sewers and watercourses Absorb spillage in suitable inert material 8. EXPOSURE CONTROL AND PERSONAL PROTECTION Control procedures : Personal protection : inhalation : hands and skin : eyes : Exposure limits : Use only in well ventilated areas Keep away from heat and sources of ignition Do not spray on a naked flame or incandescent material. Do not pierce or burn aerosols, even after use. Avoid contact with skin and eyes. Do not breathe aerosols or vapours. Keep in a cool, dry, well ventilated place Keep out of reach of children. Ensure adequate ventilation Keep away from heat and sources of ignition Take precautionary measures against static discharges Ensure adequate ventilation It is advisable to take precautions to avoid contact with skin and eyes when handling the product. In case of insufficient ventilation, wear suitable respiratory equipment. (Filter type AX) Wear suitable protective gloves (butylrubber) Wear safety goggles. Hazardous ingredient CAS-nbr. method EU established exposure limits: 2-(2-butoxyethoxy)ethanol; diethylene glycol monobutyl ether 112-34-5 TWA 10 ppm STEL 15 ppm 3 / 7
Hazardous ingredient CAS-nbr. method dimethyl ether 115-10-6 TWA 1000 ppm xylene 1330-20-7 TWA 50 ppm STEL 100 ppm butanone; ethyl methyl ketone 78-93-3 TWA 200 ppm STEL 300 ppm 9. PHYSICAL AND CHEMICAL PROPERTIES (for aerosols without propellant) Apperance : physical state : Boiling point/range : Relative density : ph : Vapour pressure : colour : odour : Relative vapour density : Solubility in water : Flash point : < 0 C DME propelled liquid. Colourless to yellow. Characteristic odor. 0.88 g/cm3 (@ 20 C). Not applicable. Insoluble in water Auto-ignition : > 200 C Viscosity : Evaporation rate : 10. STABILITY AND REACTIVITY Conditions to be avoided : Materials to be avoided : Hazardous decomposition compounds : 11. TOXICOLOGICAL INFORMATION Inhalation : Ingestion : Skin contact : Eye contact : Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50 C. Strong oxidising agent CO,CO2 Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness Ingestion is unlikely to occur After vomiting of swallowed product aspiration into lungs is likely. Solvents may induce chemical pneumonia. Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some cases, dermatitis May cause irritation. 4 / 7
12. ECOLOGICAL INFORMATION Other adverse effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not allow to enter public sewers and watercourses component CAS-nr method value unit 13. WASTE DISPOSAL Product : 14. TRANSPORT UN-number : 1950 Do not discharge into drains or the environment, dispose to an authorised waste collection point. This material and its container must be disposed of in a safe way. Disposal should be in accordance with local, state or national legislation Road/Rail - ADR/RID : UN1950 Aerosols Class : 2.1, PG : NA, Class code : 5F, Label : 2.1, Tunnel-code : (D) Sea - IMDG : UN1950 Aerosols, flammable Class : 2.1, PG : NA, Label : 2.1 EmS F-D, S-U Air - IATA/ICAO : UN1950 Aerosols, flammable Class : 2.1, PG : NA, Label : RFG 15. REGULATORY INFORMATION Warning symbol(s) : Risk-phrase(s) : F+ : EXTREMELY FLAMMABLE R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. 5 / 7
Safety-phrase(s) : S2: Keep out of the reach of children. S16: Keep away from sources of ignition - No smoking. S23: Do not breathe vapours/spray. S24/25: Avoid contact with skin and eyes. S35: This material and its container must be disposed of in a safe way. S51: Use only in well-ventilated areas. Contains : Contains 2-octyl-2H-isothiazol-3-one May produce an allergic reaction. Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Without adequate ventilation formation of explosive mixtures may be possible. Classified according to Dir. 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. Classification according to EU-directive 99/45/EC 16. OTHER INFORMATION This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties. Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks, no part of these documents may be reproduced by any process without written permission from CRC. REVISIONS IN CHAPTRE : 2,3,8,11,13,14,15 6 / 7
*Explanation risk-phrases: R10: Flammable. R11: Highly flammable. R12: Extremely flammable. R20/21: Harmful by inhalation and in contact with skin. R22: Harmful if swallowed. R23/24: Toxic by inhalation and in contact with skin. R34: Causes burns. R36: Irritating to eyes. R38: Irritating to skin. R43: May cause sensitization by skin contact. R51/53: Toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. This Material Safety Data Sheet may already have been revised at this moment for reason such as legislation, availability of components and newly acquired experiences. The latest and only valid version of this Material Safety Data Sheet will be sent to you upon simple request or can be found on our website : www.crcind.com. We recommend you to register on this website for this product so you will be able to receive any future updated version automatically. 7 / 7