Revised edition: 24.09.2015 1. 1. 1. Version: 1.3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Cobalt Blue Medium 1. 2. Article No.: 45710 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: To dye plastics, varnishes and cement. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2
2. 3. 3. Composition/Information on Ingredients 3. 1. Substance 3. 2. Mixture Page 2 Chemical Characterization: Inorganic pigment. Pigment Blue 28, C.I. No. 77346. Information on Components / Hazardous Ingredients: Cobalt aluminate spinel; REACH Reg. No. 01-2119963940-31-xxxx 100 % CAS-Nr: 1345-16-0 EINECS-Nr: 310-193-6 EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Do not leave affected persons unattended. Supply fresh air and keep patient calm. No special measures required. In case of unconsciousness place patient stable in side position for transportation. Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eyes with plenty of water for at least 15 minutes. Remove contact lens. Seek medical attention if irritation persists. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Do not give milk or alcohol to drink. Never give anything by mouth to an unconscious person. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. Treatment: Fire-Fighting Measures First-aid measures must be specified together with the responsible physician for industrial medicine. 3
5. 1. Extinguishing Media Page 3 Suitable extinguishing media: Use extinguishing media for surrounding fire. Product itself does not burn. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. 5. 3. Special hazards: Advice for Firefighters Protective equipment: Product is not flammable. Wear self-contained respiratory protective device. Usual measures for chemical fires. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water. 6. 2. Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Ensure adequate ventilation. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Protective clothing, see Section 8. No special measures necessary if properly handled. Avoid formation of dust. Do not inhale dust. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Store in tightly sealed containers in a well ventilated location. Requirements for storage areas and 4
containers: No special measures necessary. Page 4 7. 3. Information on fire and explosion protection: Storage class (VCI): Further Information: Specific End Use(s) Electrical installations / working materials must comply with the technological safety standards. 13; Non combustible solids No decomposition if used and stored according to specifications. 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): No exposure limits for this product. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Technical protective measures have priority to personal protective measures. Personal Protection General protective measures: Respiratory protection: Hand protection: Wash hands before breaks and after work. Wash hands and face at the end of work. Carry out work under a fume hood. Do inhale product. None required under normal operating conditions. Protective gloves recommended in case of prolonged or repeated contact. Protective glove material: Eye protection: Safety glasses with protective shields (EN 166). Body protection: Safety shoes. 5
Environmental precautions: 9. Physical and Chemical Properties 9. 1. Information on Basic Physical and Chemical Properties Page 5 Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: powder blue odorless no information available no information available 4.30 g/cm3 No data available No data available. Explosive properties: 6
Page 6 9. 2. 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: not determined No data available. Stable if used according to specifications. No decomposition if used according to specifications. None if handled and stored according to specifications. No data available. None if stored and handled according to specifications. LC50, inhalation: 7
Primary effects Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Non irritating Non-irritating to eyes No information available Not sensitizing. Not mutagenic. No relevant data found. No relevant data found. Methods for the evaluation of the biological degradability are not applicable for inorganic substances. On the basis of available data, the product does not contain and PBT or vpvb in percentage greater than 0.1 %. Water hazard class: 8
Not hazardous. Page 8 Behaviour in sewage systems: Further ecological effects: There are no data available on the product itself. 13. 13. 1. AOX Value: Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: 9
Page 9 14. 5. 14. 6. Environmental Hazards Special Precautions for User Not classified as environmentally hazardous. 14. 7. 14. 8. 15. 15. 1. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 0, not hazardous (German Regulation) Seveso III Directive: under Directive 2012/18/EC. Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: 15. 2. 15. 3. 16. Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Classification II: 100 % inorganic dust A Chemical Safety Assessment has been carried out for this product. EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern (REACH Regulation (EC) 1907/2006, Article 57) Listed in: REACH (EU), TSCA (US), AICS (AUS), DSL (CA), KECI (KR), ENCS (JP), PICCS (PH), NZIoC (NZ), IECSC (CN), INV (CH), INV (MY), INV (TR), INV (TW) Regulation (EC) 2037/2000 - Substances that Deplete the Ozone Layer: not regulated / Regulation (EC) 689/2008 concerning the export and import of dangerous chemicals: not regulated / EC. REACH, Annex XIV, Candidate List of Substances of very High Concern (SVHC): not regulated / Regulation (EC) 850/2004 - Persistent organic pollutants and amending Directive 79/117/EEC: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.