Revised edition: 29.01.2014 1. 1. 1. Version: 9 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Cobalt Blue, Sapporo 1. 2. Article No.: 45702 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Synthetic pigment for dying industrial products. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 1. 4. Internet: EMail: Emergency No. www.kremer-pigmente.de info@kremer-pigmente.de 2. 2. 1. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. 2. 2. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Hazard designation: Safety designation: EUH210 Safety data sheet availabe upon request. Hazardous components for labelling: Other Hazards 2
2. 3. 3. 3. 1. 3. 2. Composition/Information on Ingredients Substance Mixture Chemical Characterization: Pigment Blue 74, C.I. 77346 Page 2 After eye contact: can cause irritation. Prolonged skin contact can irritate skin. Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Hazardous Ingredients: Phenacite Co-Zn-Silicate (blue) 90-100 % CAS-Nr: 68412-74-8 EINECS-Nr: 270-208-6 EC-Nr: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Take affected persons out into the fresh air. Supply fresh air and keep patient calm. In case of complaints consult a physician. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water. In case of discomfort seek medical help. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Do not induce vomiting. Consult physician immediately. Symptoms: Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Skin contact: prolonged contact may cause irritations. Eye contact: can cause mechanical irritation. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media No special first-aid measures necessary. Suitable extinguishing media: 3
Use extinguishing media for surrounding fire. Page 3 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture 5. 3. Special hazards: Advice for Firefighters Protective equipment: No special hazards. Wear suitable protective clothing. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Ensure adequate ventilation. Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Protective clothing, see Section 8. The usual precautionary measures are to be adhered to when handling chemicals. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Wash hands at the end of work. Preventive skin protection recommended. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in a cool and dry place. No special measures necessary. Take measures to prevent static electricity discharge. Storage class (VCI): 4
Further Information: 7. 3. Specific End Use(s) Page 4 8. 8. 1. Further information: See Section 1.2.; no other uses provided Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TLV: 0.10 mg/m3 (inhalable dust fraction) based on cobalt. Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Ensure adequate ventilation, especially in confined areas. Personal Protection General protective measures: Respiratory protection: Hand protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Dust mask recommended when very dusty (with particle filter P1 or FFP1). Protective gloves (EN 374) Protective glove material: Eye protection: Safety glasses (EN 166) Body protection: 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: powder blue odorless not available 5
Melting temperature: not determined Page 5 9. 2. Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: not available 3-5 g/cm3 insoluble No data available. not determined Solvent content: 6
Solid content: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: No further information. Stable if used according to specifications. The product is stable. Stable at room temperature. Hazardous polymerisation will not occur. > 5000 mg/kg (rat) Prolonged skin contact can cause irritations, redness and dry skin. Dust may cause irritation. Can cause irritation of the respiratory system. Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Not classified as harmful. Sensitization: 7
Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations No data available. No data available. No data available. No negative effects. Avoid inhalation of dust. Even inert dusts can impair the function of the respiratory system. No negative effects. Not readily biodegradable. No bioaccumulation expected. Weak solubility and mobility. Not applicable. Not hazardous. The product is not soluble in water. No negative effects expected. 8
13. 1. Waste Treatment Methods Page 8 Product: Product can be taken to a waste disposal site according to local regulations. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. 14. 5. 14. 6. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. None Not classified as a dangerous good under transport regulations. 9
Page 9 14. 7. 14. 8. 15. 15. 1. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (self-assessment) 15. 2. 15. 3. 16. Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.