SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : Material number : 000000000000903402 Manufacturer or supplier's details Company : Zep Inc. Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Telephone : 404-352-1680 Emergency telephone numbers For SDS Information : Compliance Services 1-877-428-9937 For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded For a Transportation Emergency : CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour solid white odourless GHS Classification Acute toxicity (Inhalation) : Category 4 Eye irritation : Category 2A Specific target organ toxicity - : Category 3 (Respiratory system) single exposure GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear eye protection/ face protection. 1 / 10
P281 Use personal protective equipment as required. Response: P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: Dispose of contents/container in accordance with local regulation. Potential Health Effects Carcinogenicity: IARC ACGIH OSHA NTP Group 1: Carcinogenic to humans quartz (SiO2) 14808-60-7 No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration [%] Fuller's earth 8031-18-3 >= 70 - < 90 quartz (SiO2) 14808-60-7 >= 20 - < 30 SECTION 4. FIRST AID MEASURES General advice If inhaled : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. 2 / 10
In case of skin contact In case of eye contact If swallowed : If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Immediately flush eyes for at least 15 minutes. Get medical attention. : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Hazardous combustion products Specific extinguishing methods Further information Special protective equipment for firefighters : Water spray jet : High volume water jet : No hazardous combustion products are known : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. : Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE 3 / 10
Advice on safe handling Conditions for safe storage Materials to avoid : Avoid formation of respirable particles. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. : Observe label precautions. Keep in a dry, cool place. Electrical installations / working materials must comply with the technological safety standards. : Do not store near acids. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) TWA (total dust) TWA (respirable) TWA (respirable) TWA (Respirable dust) Control Basis parameters / Permissible concentration 30 mg/m3 / OSHA Z-3 %SiO2+2 10 mg/m3 / OSHA Z-3 %SiO2+2 250 mppcf / OSHA Z-3 %SiO2+5 0.05 mg/m3 NIOSH REL Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks Eye protection Skin and body protection Hygiene measures : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Not applicable : No special protection is required. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 4 / 10
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : solid Colour Odour Odour Threshold ph Melting point/freezing point Boiling point Flash point : Evaporation rate Upper explosion limit Lower explosion limit Vapour pressure Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Viscosity : white : odourless Viscosity, kinematic SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials : Stable : Stable under normal conditions. : No decomposition if stored and applied as directed. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute inhalation toxicity : Acute toxicity estimate : 2 mg/l Exposure time: 4 h 5 / 10
Test atmosphere: dust/mist Method: Calculation method Skin corrosion/irritation Remarks: May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Remarks: May cause irreversible eye damage. Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Fuller's earth: quartz (SiO2): STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Remarks SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential 6 / 10
Partition coefficient: n- octanol/water Mobility in soil Other adverse effects Regulation Remarks Additional ecological information : Remarks 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: IATA (Cargo Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL 7 / 10
Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard SARA 302 SARA 313 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. quartz (SiO2) 14808-60-7 The components of this product are reported in the following inventories: TSCA DSL AICS NZIoC PICCS IECSC On TSCA Inventory All components of this product are on the Canadian DSL On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory On the inventory, or in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION 8 / 10
Health Instability SAFETY DATA SHEET Further information NFPA: Flammability HMIS III: 2 1 0 HEALTH FLAMMABILITY 2* 0 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic OSHA GHS Label Information: Hazard pictograms : Signal w ord : Warning: Hazard statements : Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Precautionary statements : Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash skin thoroughly after handling. Use only outdoors or in a w ell-ventilated area. Wear eye protection/ face protection. Use personal protective equipment as required. Response: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unw ell. IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Storage: Store in a w ell-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with local regulation. Version: 1.0 Revision Date: 11/11/2015 Print Date: 11/17/2015 We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Zep Inc. markets products under well recognized and established brand names such as Zep, Zep Commercial,Zep Professional, Enforcer, National Chemical, Selig, Mis ty, Next Dimension, Petro, i-chem, TimeMist, TimeWick, MicrobeMax, Country Vet, Konk, Original Bike Spirits, Blue Coral, Black Magic, Rain-X, Niagara National, FC Forward Chemicals,Rexodan, Mykal, and a number of private labeled brands. 9 / 10
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