1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Other Names (if applicable) Product Code Barcode Number Recommended Use Company Name ABN Street Address Telephone Number Supplier Code Other Emergency Phone Number Atlas Enviroshield 2 in 1 Indoor & Outdoor Automatic Insect Control System Refill None 43410 26207735 Aerosol refill for metered spray device; for indoor and outdoor use ALDI STORES (A Limited Partnership) 90 196 565 019 1 Sargents Road, MINCHINBURY, NSW 2770 +61 2 9675 9000 1249 Australia - 13 11 26 (Poisons Information Centre) 2. HAZARDS IDENTIFICATION Classification of the substance or mixture ( According to the WHS Regulations and the ADG Code ) N, Dangerous to the environment. Not classified as hazardous according to the criteria of SWA. Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria Label elements GHS label elements Signal Word WARNING Hazard statement (s) H223: Flammable aerosol H280: Contains gas under pressure; may explode if heated. H402: Harmful to aquatic life Precautionary statement (s) P102: Keep out of reach of children. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P211: Do not spray on an open flame or other ignition source. P251: Pressurized container: Do not pierce or burn, even after use. P262: Do not get in eyes, on skin, or on clothing. P281: Use personal protective equipment as required Other hazards None identified This document becomes uncontrolled once printed. Page 1 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS Substances Mixtures Components CAS Number Proportion Liquid hydrocarbon 350g/kg Pyrethrins 8003-34-7 9g/kg Piperonyl butoxide 51-03-6 45g/kg Alkanes, C3-4 68475-59-2 to 100% This document becomes uncontrolled once printed. Page 2 of 6
4. FIRST AID MEASURES For advice, contact Poisons Information Centre (phone Australia 13 11 26) or a doctor (For each route of exposure provide indication of medical attention and special treatment needed including description of most important symptoms, acute and delayed) Inhalation Skin Contact Eye Contact Ingestion Note to Physician From the available evidence, this product would appear to offer no significant health hazard by any exposure route. Consequently, First Aid is not generally required. If frostbite has occurred, immerse affected area in water that is neither hot or cold, but near body temperature (35-42 C). Do not allow injured area to warm up too rapidly as further injury may result. If sprayed directly into eyes, wash eyes with warm water and seek medical advice. An unlikely exposure route. Treat symptomatically. 5. FIRE FIGHTING MEASURES Hazards from combustion products Precautions for firefighters and special protective equipment Suitable / Unsuitable extinguishing material The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is a moderate risk of an explosion from this product if commercial quantities are involved in a fire. Firefighters should take care and appropriate precautions. In case of fire, use carbon dioxide, dry chemical, foam, water fog. Water fog or fine spray is the preferred medium for large fires. 6. ACCIDENTAL RELEASE MEASURES Emergency procedures Methods and materials for containment and clean up Environmental precaution(s) This product is sold in small packages, and the accidental release from one of these is not usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Although no special protective clothing is normally necessary because of occasional minor contact with this product, it is good practice to wear impermeable gloves when handling chemical products. In the event of a major spill, prevent spillage from entering drains or water courses and call emergency services. 7. HANDLING AND STORAGE Precautions for safe handling Conditions for safe storage The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10 Store in a cool (below 30 C), well ventilated area. Protect from direct sunlight. Make sure that surrounding electrical devices and switches are suitable. Check containers and valves periodically for leaks. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION National Exposure Standards Liquid hydrocarbon TWA 790mg/m3 STELnot set Pyrethrins TWA 5mg/m3 STEL not set Biological Limit Values Engineering Controls Personal Protective Equipment The ADI for Pyrethrins is set at 0.04mg/kg/day. The ADI for Piperonyl butoxide is set at 0.1mg/kg/day. The corresponding NOEL is set at 16mg/kg/day. None required. None required in anticipated use. This document becomes uncontrolled once printed. Page 3 of 6
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour ph Specific Gravity or Density Vapour Pressure Vapour Density Percent Volatiles Boiling Point Range Freezing/ Melting Point Solubility Flash Point (include method detection) Flammability Limits Ignition Temperature Other Non viscous liquid Light yellow Mild sweet vegetable odour. Not applicable. About 0.76 <0.106kPa at 20 C About 5.4 No data >171 C at 100kPa No data. Liquid at normall ambient temperatures. Insoluble. No data. Liquid at normall ambient temperatures. No data No data. Liquid at normall ambient temperatures. None 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Conditions to avoid Incompatible Materials Hazardous Decomposition Products Hazardous Reactions This product is unlikely to react or decompose under normal storage conditions. This product is unlikely to react or decompose under normal storage conditions. Store below 30 C, protect from direct sunlight and do not expose to temperatures exceeding 50 C. Containers should be kept dry. Keep away from sources of sparks or ignition. strong oxidising agents Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. None known 11. TOXICOLOGICAL INFORMATION Health Effects Ingestion Eye Contact Skin Contact Inhalation Long term effects Acute Toxicity/ Chronic Toxicity: (ie LD 50 ) Significant oral exposure is considered to be unlikely. This product is unlikely to cause any irritation problems in the short or long term If sprayed directly in the eye, this product will irritate. If spraying is prolonged, it may cause damage through frostbite. Major health effect from this product is misuse of the aerosol function. If sprayed continuously on skin or in eyes, it can cause frostbite. Intentional misuse by deliberately concentrating and inhaling contents of aerosol containers can be harmful or fatal. None known Not known 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and Degradability Mobility Other Adverse Effects Bioaccumulation Potential This product is harmful to aquatic organisms. This document becomes uncontrolled once printed. Page 4 of 6
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13. DISPOSAL CONSIDERATIONS Disposal methods (including container disposal) Dispose of small quantities and empty containers by wrapping with paper and putting in garbage. For larger quantities, if recycling or reclaiming is not possible, use a commercial waste disposal service Special precautions for landfill or incineration 14. TRANSPORT INFORMATION Regulation UN Number Proper Shipping Name DG Class ADG 1950 Aerosols Class 2.1 IMDG 1950 Aerosols Class 2.1 IATA 1950 Aerosols Class 2.1 Label Additional Information 15. REGULATORY INFORMATION Poisons Schedule (Australia only) APVMA Status TGA Status AICS Status None allocated. Registered Not applicable. All of the significant ingredients in this formulation are compliant with NICNAS regulations. 16. OTHER INFORMATION SDS Version Number 1.0 SDS Version Date 3/06/2016 Reason for issue Key/Legend to Abbreviations and Acronyms used in the SDS: Abbreviation/Acronym ADG AICS APVMA AQIS AS ASCC DG ERG Code IATA IMDG LD 50 NOHSC SDS STEL TGA TLV TWA UN Number Meaning Australian Code for the Transport of Dangerous Goods by Road and Rail Australian Inventory of Chemical Substances Australian Pesticides and Veterinary Medicines Authority Australian Quarantine and Inspection Service Australian Standard (as issued by Standards Australia) Australian Safety and Compensation Council Dangerous Goods Emergency Response Guidebook Code. The Emergency Response Guidebook is used by first responders (eg firefighters, police officers and ambulance personnel) when responding to a transportation emergency involving hazardous materials. International Air Transport Association International Maritime Dangerous Goods The median lethal toxicological dose, LD 50 is an abbreviation for Lethal Dose, 50%. of a toxic substance. This is the dose required to kill half the members of a tested population. National Occupational Health and Safety Commission Safety Data Sheet Short Term Exposure Limit - A 15 minute TWA exposure which should not be exceeded at any time during a working day even if the eight-hour TWA average is within the TWA exposure standard. Exposures at the STEL should not be longer than 15 minutes and should not be repeated more than four times per day. There should be at least 60 minutes between successive exposures at the STEL. Therapeutic Goods Administration Threshold Limit Value - TLV is a proprietary name registered by the American Conference of Governmental Industrial Hygienists (ACGIH) and refers to airborne concentrations of substances or levels of physical agents to which it is believed that nearly all workers may be repeatedly exposed day after day without adverse effect. Time Weighted Average - The average airborne concentration of a particular substance when calculated over a normal eight-hour working day, for a five-day working week. UN numbers are four-digit numbers that identify hazardous substances, and articles (such as explosives, flammable liquids, toxic substances, etc.) in the framework of international transport. This SDS has been prepared by the ALDI Stores product supplier from current technical data and summarises at the date of issue their best knowledge of the health and safety information of the product, and in particular how to safely handle and use the product in the workplace. This SDS may only be reproduced in full. Summaries or excerpts from this SDS may not contain all the relevant information and thus are not permitted. ALDI Stores gives no warranty and makes no representation as to the accuracy, reliability or completeness of the information contained herein. The user should make their own determination in light of their own circumstances as to the suitability of this information and the safe conditions for the use of this product. To the extent permitted by law, ALDI Stores will not be liable for any loss, damage or expense arising from the use of this SDS, whether caused by the negligent act or omission of ALDI Stores or otherwise. End of SDS This document becomes uncontrolled once printed. Page 6 of 6