SAFETY DATA SHEET Creation Date 16-Nov-2010 Revision Number 4 Product Name Cat No. : 1. Identification 3-Amino-9-ethylcarbazole AC147870000; AC147870050; AC147870250; AC147871000; AC147875000 CAS-No 132-32-1 Synonyms 3-Amino-N-Ethylcarbazole. Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acros Organics One Reagent Lane Fair Lawn, NJ 07410 Emergency Telephone Number For information US call: 001-800-ACROS-01 / Europe call: +32 14 57 52 11 Emergency Number US:001-201-796-7100 / Europe: +32 14 57 52 99 CHEMTREC Tel. No.US:001-800-424-9300 / Europe:001-703-527-3887 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute oral toxicity Category 3 Carcinogenicity Category 1B Label Elements Signal Word Danger Hazard Statements Toxic if swallowed May cause cancer Page 1 / 7
Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Response IF exposed or concerned: Get medical attention/advice Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth Storage Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % 3-Amino-9-ethylcarbazole 132-32-1 90 4. First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Autoignition Temperature Explosion Limits Upper Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wash off immediately with plenty of water for at least 15 minutes. Immediate medical attention is required. Move to fresh air. If not breathing, give artificial respiration. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Immediate medical attention is required. Do not induce vomiting. Call a physician or Poison Control Center immediately. None reasonably foreseeable. Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Page 2 / 7
Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. NFPA Health 2 Flammability 1 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Should not be released into the environment. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust Up formation. Handling Storage Exposure Guidelines 7. Handling and storage Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Avoid dust formation. Use only under a chemical fume hood. Do not breathe vapors/dust. Do not ingest. Keep container tightly closed in a dry and well-ventilated place. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Physical State Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Long sleeved clothing. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Powder Solid Page 3 / 7
Appearance Brown Odor Odorless Odor Threshold ph Melting Point/Range 98-100 C / 208.4-212 F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Insoluble in water Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula C14 H14 N2 Molecular Weight 210.28 10. Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under normal conditions. Incompatible products. Acids, Strong oxidizing agents Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Acute Toxicity. None under normal processing. 11. Toxicological information Product Information Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation 3-Amino-9-ethylcarbazole 144 mg/kg (rat) Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Page 4 / 7
3-Amino-9-ethylcarbaz ole Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity 132-32-1 Not listed Not listed Not listed Not listed Not listed... STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods None known None known The toxicological properties have not been fully investigated. 12. Ecological information Insoluble in water. Is not likely mobile in the environment due its low water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information DOT Proper Shipping Name Toxic solid, organic, n.o.s Proper technical name 3-Amino-9-ethylcarbazole TDG Proper Shipping Name TOXIC SOLID, ORGANIC, N.O.S. IATA Proper Shipping Name TOXIC SOLID, ORGANIC, N.O.S. IMDG/IMO Proper Shipping Name TOXIC SOLID, ORGANIC, N.O.S. Page 5 / 7
15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL 3-Amino-9-ethylcarbazole X - X 205-057-7 - X X - - X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By 16. Other information Regulatory Affairs Page 6 / 7
Thermo Fisher Scientific Email: EMSDS.RA@thermofisher.com Creation Date Revision Date Print Date Revision Summary 16-Nov-2010 18-Jan-2018 18-Jan-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7